Search results for "layered"
showing 10 items of 142 documents
Ni/Zn Layered Double Hydroxide (LDH) Micro/Nanosystems and Their Azorubine Adsorption Performance
2021
A membranous shaped Ni/Zn layered double hydroxide based nanohybrid was obtained using a low-cost template-free hydrothermal process at optimized growth conditions of 180 °C for 6 h. The synthesized nanohybrid was structurally, texturally and morphologically characterized using different techniques such as X-ray diffraction, FTIR, XPS spectroscopy, BET analysis and FESEM microscopy. The adsorption performance of our product was estimated through the Azorubine dye removal from synthetic wastewater. We therefore studied the synergic effects of Ni/Zn adsorbent dosage, contact time, pH, adsorbate concentration, stirring speed and temperature on the Azorubine adsorption efficiency. In this inves…
Appropriazione e (ri)semantizzazione dello spazio urbano: lo sport in una piazza palermitana
2019
Il contributo, attraverso uno studio di campo, con un approccio geografico culturale esplora le modalità attraverso cui uno spazio urbano, piazza Vittorio Emanuele Orlando a Palermo, può essere oggetto di complessi processi di (ri)semantizzazione. La piazza diviene infatti luogo per sport giovanili improvvisati, al centro di dialettiche opposte (ufficialità/improvisazione) e di forme multistratificate di socialità e aggregazione.
Alkoxide-intercalated NiFe-layered double hydroxides magnetic nanosheets as efficient water oxidation electrocatalysts
2016
Alkoxide-intercalated NiFe-layered double hydroxides were synthesized via the nonaqueous methanolic route. These nanoplatelets exhibit high crystalline quality as demonstrated by atomic resolution scanning transmission electron microscopy combined with electron energy-loss spectroscopy. Moreover, the presence of the alkoxide moieties has been unambiguously demonstrated by means of thermogravimetric analysis coupled to a mass spectrometer. These NiFe-LDHs can be exfoliated in water or organic solvents and processed into homogeneous ultra-thin films (< 3nm thick) with the assistance of O2-plasma. The study of their behaviour as water oxidation electrocatalysts has shown an outstanding perf…
Fundamental Insights into the Covalent Silane Functionalization of NiFe Layered Double Hydroxides
2020
Layered double hydroxides (LDHs) are a class of 2D anionic materials exhibiting wide chemical versatility and promising applications in different fields, ranging from catalysis to energy storage and conversion. However, the covalent chemistry of this kind of 2D materials is still barely explored. Herein, the covalent functionalization with silanes of a magnetic NiFe-LDH is reported. The synthetic route consists of a topochemical approach followed by anion exchange reaction with surfactant molecules prior to covalent functionalization with the (3-aminopropyl)triethoxysilane (APTES) molecules. The functionalized NiFe-APTES was fully characterized by X-ray diffraction, infrared spectroscopy, e…
Palladium supported on Halloysite-triazolium salts as catalyst for ligand free Suzuki cross-coupling in water under microwave irradiation
2015
Abstract Environmental friendly halloysite-dicationic triazolium salts (second generation) obtained by subsequent click reactions of a diyne derivative in the presence of 2-azidopropyl-modified halloysite nanotubes, were used as supports for palladium catalyst. Thanks to the high triazolium loading (25%) these materials were able to support higher amount of the metal than that on the monocationic derivative (first generation). Such materials were characterized by thermogravimetric analysis, FT-IR spectroscopy and SEM investigations. The new catalytic system was employed in the ligand free Suzuki cross-coupling under microwave irradiation. A set of solvent, time and% loading of palladium was…
Structural Characterisation of Complex Layered Double Hydroxides and TGA-GC-MS Study on Thermal Response and Carbonate Contamination in Nitrate- and …
2015
Layered double hydroxides (LDHs) are versatile materials used for intercalating bioactive molecules in the fields of pharmaceuticals, nutraceuticals and cosmetics, with the purpose of protecting them from degradation, enhancing their water solubility to increase bioavailability and improving their pharmacokinetic properties and formulation stability. Moreover, LDHs are used in various technological applications to improve stability and processability. The crystal chemistry of hydrotalcite-like compounds was investigated by X-ray powder diffraction (XRPD), automated electron diffraction tomography (ADT) and thermogravimetric analysis (TGA)-GC-MS to shed light on the mechanisms involved in io…
An analytical solution for multilayered beams subjected to ends loads
2014
An alternative model for multilayered beams undergoing axial, shear and bending loads applied at the beam's ends is developed. It is based on a layer-wise kinematics, which inherently fulfills the equilibrium equations at layer level and the interface continuity conditions. This kinematics is suitably expressed by introducing a set of generalized variables representative of the beam midline displacement field, which become the primary variables of the problem governing equations. As a consequence, the proposed beam model exhibits the computational characteristics of an equivalent single layer model and possesses the accuracy of layer-wise beam theories, as well. Closed form solutions for di…
Two-Dimensional Crystals and van der Waals Heterostructures based on Inorganic and Molecular Strongly Correlated Layered Materials
2021
“En resumen, toda obra grande es el fruto de la paciencia y de la perseverancia, combinadas con una atención orientada tenazmente durante meses y aun años hacia un objeto particular”. “In summary, all great work is the fruit of patience and perseverance, combined with tenacious concentration on a subject over a period of months or years”. Santiago Ramón y Cajal (Reglas y consejos sobre investigación científica. Madrid: Academia de Ciencias Exactas, Físicas y Naturales, 1897). The present Thesis constitutes a journey –a romance of many dimensions, quoting Edwin Abbot Abbot– from 3D to 2D and, hopefully (we let the curious Reader judge), “Through Flatland to Thoughtland” (citing, again, Abbot…
Magnetic materials based on layered double hydroxides: chemical design, processing and electrochemical applications
2018
Tras el descubrimiento del grafeno en 2004, los materiales bidimensionales han generado un interés creciente por parte de la comunidad científica que se prolonga hasta nuestros días. Junto a este material constituido por delgadas láminas de carbono, también existen materiales bidimensionales de naturaleza inorgánica entre los que predominan aquellos basados en fuerzas de van der Waals. Dicalcogenuros metálicos, fósforo negro o antimoneno son algunos de estos ejemplos. Sin embargo, también existen materiales 2D formados por láminas iónicas, donde son las fuerzas electrostáticas las que ejercen un papel fundamental en cuanto a la organización y estructura de dichos sistemas. Este es el caso d…
A discontinuous Galerkin formulation for variable angle tow composite plates higher-order theories
2020
A discontinuous Galerkin formulation for the mechanical behaviour of Variable Angle Tow multi-layered composite plates is presented. The starting point of the formulation is the strong form of the governing equations, which are obtained by means of the Principle of Virtual Displacement, the Generalized Unified Formulation and the Equivalent Single Layer assumption for the mechanical behaviour of the whole assembly. To obtain the corresponding discontinuous Galerkin formulation, an auxiliary flux variable is introduced and the governing equations are rewritten as a first-order system of partial differential equations. To link neighbouring mesh elements, suitably defined numerical fluxes are …