Search results for "least squares"
showing 10 items of 268 documents
Combination of mid- and near-infrared spectroscopy for the determination of the quality properties of beers
2006
Abstract The combination of infrared (MIR) and near-infrared (NIR) spectroscopy has been employed for the determination of important quality parameters of beers, such as original and real extract and alcohol content. A population of 43 samples obtained from the Spanish market and including different types of beer, was evaluated. For each technique, spectra were obtained in triplicate. In the case of NIR a 1 mm pathlength quartz flow cell was used, whereas attenuated total reflectance measurements were used in MIR. Cluster hierarchical analysis was employed to select calibration and validation data sets. The calibration set was composed of 15 samples, thus leaving 28 for validation. A critic…
Partial least squares X-ray fluorescence determination of trace elements in sediments from the estuary of Nerbioi-Ibaizabal River.
2010
The feasibility of partial least squares (PLS) regression modeling of X-ray fluorescence (XRF) spectra of estuarine sediments has been evaluated as a tool for rapid trace element content monitoring. Multivariate PLS calibration models were developed to predict the concentration of Al, As, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sn, V and Zn in sediments collected from different locations across the estuary of the Nerbioi-Ibaizabal River (Metropolitan Bilbao, Bay of Biscay, Basque Country). The study was carried out on a set of 116 sediment samples, previously lyophilized and sieved with a particle size lower than 63 microm. Sample reference data were obtained by inductively coupled plasma mass …
A green method for the determination of cocaine in illicit samples
2013
Abstract Direct determination of cocaine in untreated seized samples has been made based on diffuse reflectance measurements of the near infrared (NIR) radiation through samples contained inside standard glass vials. The method used a series of previously analyzed samples, by the reference gas chromatography method, to build a partial least squares calibration model which was validated using an independent set of samples. The use of a general model for samples containing from 11.38% till 86.44% (w/w) cocaine was based on the use of spectral ranges from 12500.7 to 10128.6, 9339.8 to 6967.7 and 5388.3 to 4597.6 cm−1 with previous first derivative and vector normalization data pre-processing a…
Model-Based Transfer Entropy Analysis of Brain-Body Interactions with Penalized regression techniques
2020
The human body can be seen as a functional network depicting the dynamical interactions between different organ systems. This exchange of information is often evaluated with information-theoretic approaches which comprise the use of vector autoregressive (VAR) and state space (SS) models, normally identified with the Ordinary Least Squares (OLS). However, the number of time series to be included in the model is strictly related to the length of data recorded thus limiting the use of the classical approach. In this work, a new method based on penalized regressions, the so-called LASSO, was compared with OLS on physiological time-series extracted from 18 subjects during different stress condi…
Sensorless induction machine drive for fly-wheel generation unit based on a TLS-based non-linear observer
2016
This paper proposes a sensorless technique for an induction machine Flywheel Energy Storage System (FESS) based on a non-linear observer integrated with a total least-squares speed estimator taking into consideration the IM (Induction Machine) saturation effects. The nonlinear observer is based on an original formulation of the dynamic model of the IM including the magnetic saturation, rearranged in a space-state form, after assuming as state variables the stator current and the rotor magnetizing current space-vectors in the stator reference frame. The choice of the observer gain has been made by the use of Lyapunov's method. The speed signal needed by the non-linear observer for the flux e…
Signal Denoising with Harten’s Multiresolution Using Interpolation and Least Squares Fitting
2014
Harten’s multiresolution has been successfully applied to the signal compression using interpolatory reconstructions with nonlinear techniques. Here we study the applicability of these techniques to remove noise to piecewise smooth signals. We use two reconstruction types: interpolatory and least squares, and we introduce ENO and SR nonlinear techniques. The standard methods adaptation to noisy signals and the comparative of the different schemes are the subject of this paper.
Non-parametric spectrum cartography using adaptive radial basis functions
2017
This paper presents a framework for spectrum cartography based on the use of adaptive Gaussian radial basis functions (RBF) centered around a specific number of centroid locations, which are determined, jointly with the other RBF parameters, by the available measurement values at given sensor locations in a specific geographical area. The spectrum map is constructed non-parametrically as no prior knowledge about the transmitters is assumed. The received signal power at each location (over a given bandwidth and time period) is estimated as a weighted contribution from different RBF, in such a way that the both RBF parameters and the weights are jointly optimized using an alternating minimiza…
MUSIC-LS Modal Channel Estimation for an OFDM-OQAM System
2008
Orthogonal frequency division multiplexing based on offset quadrature amplitude modulation (OFDM-OQAM) signaling over frequency selective multipath channels shows inter-symbol interference (ISI) and Inter-Channel Interference (ICI) that degrade its performance. Channel equalization and channel estimation are needed to combat these intrinsic interferences. In this paper a novel modal channel estimator based on the MUltiple signal classification (MUSIC) and least squares (LS) algorithms for a wideband passband OFDM-OQAM signaling over static multipath channels is presented. The effects of the frequency selective channel on the received signal are described considering a wideband OFDM-OQAM sys…
Direct determination of polymerised triacylglycerides in deep-frying vegetable oil by near infrared spectroscopy using Partial Least Squares regressi…
2012
Abstract A green method for the determination of polymerised triacylglyceride (PTG) in deep-frying vegetable oils of different botanic origin has been developed employing near infrared (NIR) spectroscopy and Partial Least Squares (PLS) regression. Four different types of oil were heated during several hours, with and without the addition of foodstuff. NIR transmission spectra were obtained directly from sample aliquots stored in glass vials, thus avoiding the consumption of solvents and minimising waste generation. Variables employed for building the PLS models were selected applying interval PLS (iPLS) as well as Uninformative Variable Elimination-PLS (UVE-PLS). A global PLS model using sp…
Individual Performance in Turbulent Environments: The Role of Organizational Learning Capability and Employee Flexibility
2015
Organizational learning capability (OLC) and employee flexibility help firms navigate the challenges faced by organizations operating in turbulent environments. OLC includes dimensions such as experimentation, risk taking, openness, dialogue, and participative decision making. Employee flexibility is considered a crucial tool for strategic human resource management in tackling environmental turbulence. Accordingly, we pose the following research question: how, and to what extent, is individual performance enhanced by OLC and employee flexibility in turbulent environments? The major impact that environmental turbulence has on change and flexibility requirements suggests that employee flexibi…