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Historia Domu Rekolekcyjnego Konferencji Episkopatu Polski "Księżówka" w Zakopanem w latach 1945-1990
2017
Artykuł jest kontynuacją historii „Księżówki” - Domu Rekolekcyjnego Konferencji Episkopatu Polski w Zakopanem. Autor ukazuje w nim funkcjonowanie domu w peerelowskim okresie zmagań z władzami administracyjno-politycznymi o byt w warunkach narzucanych przez totalitarny ustrój.
Damming an electronic energy reservoir: ion-regulated electronic energy shuttling in a [2]rotaxane
2021
We demonstrate the first example of bidirectional reversible electronic energy transfer (REET) between the mechanically bonded components of a rotaxane. Our prototypical system was designed such that photoexcitation of a chromophore in the axle results in temporary storage of electronic energy in a quasi-isoenergetic “reservoir” chromophore in the macrocycle. Over time, the emissive state of the axle is repopulated from this reservoir, resulting in long-lived, delayed luminescence. Importantly, we show that cation binding in the cavity formed by the mechanical bond perturbs the axle chromophore energy levels, modulating the REET process, and ultimately providing a luminescence read-out of c…
Cation binding resorcinarene bis-crowns: the effect of lower rim alkyl chain length on crystal packing and solid lipid nanoparticles
2012
A group of seven resorcinarene bis-crown ethers (CNBC5) with two polyether bridges at the upper rim and either propyl, butyl, pentyl, heptyl, nonyl, decyl or undecyl groups at the lower rim were synthesized and their binding properties with Cs+ were investigated by NMR titration. The bis-crowns form 1:2 complexes with Cs+ with binding constants of logK 4–5. Crystal structures of bis-crowns and their Cs+ and K+ complexes were studied and different packing motifs were found depending on the alkyl chain length. Short ethyl, propyl and butyl alkyl chains gave a layer or pillar packing where the polar and non-polar regions cannot be distinguished, whereas longer pentyl and decyl chains formed bi…
Anion-driven encapsulation of cationic guests inside pyridine[4]arene dimers
2019
Pyridine[4]arenes have previously been considered as anion binding hosts due to the electron-poor nature of the pyridine ring. Herein, we demonstrate the encapsulation of Me4N+ cations inside a dimeric hydrogen-bonded pyridine[4]arene capsule, which contradicts with earlier assumptions. The complexation of a cationic guest inside the pyridine[4]arene dimer has been detected and studied by multiple gas-phase techniques, ESI-QTOF-MS, IRMPD, and DT-IMMS experiments, as well as DFT calculations. The comparison of classical resorcinarenes with pyridinearenes by MS and NMR experiments reveals clear differences in their host–guest chemistry and implies that cation encapsulation in pyridine[4]arene…
Suomi toisena kielenä -oppijoiden sanaston kehittyminen taitotasolta toiselle siirryttäessä
2012
Tutkimuksen tavoitteena on selvittää, kuinka sanaston käyttö kehittyy suomi toisena kielenä -oppijoiden teksteissä. Tarkastelun kohteena on sanavaraston rikkaus eli leksikaalinen diversiteetti. Aineistona on 1197 aikuisten ja koululaisten eri tekstilajeja edustavaa kirjoitusta, jotka on arvioitu valmiiksi Eurooppalaisen viitekehyksen mukaisille taitotasoille. Työ on osa Suomen Akatemian ja Jyväskylän yliopiston vuosina 2007-2009 rahoittamaa Cefling hanketta, jonka tehtävänä on selvittää, millaista kielitaito on kullakin Eurooppalaisessa viitekehyksessä kuvatulla kuudella taitotasolla. Tavoitteena on myös selvittää, onko aikuisten ja koululaisten kielenoppimisessa eroja. Keskeisimmät teoreet…
The emergence of Vibrio pathogens in Europe : ecology, evolution, and pathogenesis (Paris, 11-12th March 2015)
2015
Global change has caused a worldwide increase in reports of Vibrio-associated diseases with ecosystem-wide impacts on humans and marine animals. In Europe, higher prevalence of human infections followed regional climatic trends with outbreaks occurring during episodes of unusually warm weather. Similar patterns were also observed in Vibrio-associated diseases affecting marine organisms such as fish, bivalves and corals. Basic knowledge is still lacking on the ecology and evolutionary biology of these bacteria as well as on their virulence mechanisms. Current limitations in experimental systems to study infection and the lack of diagnostic tools still prevent a better understanding of Vibrio…
Production of Cultural Policy in Russia: Authority and Intellectual Leadership
2020
The paper discusses different frameworks of knowledge production within the discourses and practices of Russian cultural policy. Russian cultural policy as an administrative sector has been developed in line with two distinctive governmental regimes, more precisely during the period of liberal decentralisation of the 1990s and the conservative centralisation from 2011 up until today. The study focuses on the main changes that have occurred in the framework of policy design and participation in policy-making. An attempt is made to combine Foucauldian analytical frameworks of power and discourse with a Gramscian hegemonic approach to political studies that was mainly advocated by the Essex sc…
Inclusion complexes of Cethyl-2-methylresorcinarene and pyridine N-oxides: breaking the C–I⋯−O–N+ halogen bond by host–guest complexation
2016
C ethyl-2-Methylresorcinarene forms host–guest complexes with aromatic N-oxides through multiple intra- and intermolecular hydrogen bonds and C–H⋯π interactions. The host shows conformational flexibility to accommodate 3-methylpyridine N-oxide, while retaining a crown conformation for 2-methyl- and 4-methoxypyridine N-oxides highlighting the substituent effect of the guest. N-Methylmorpholine N-oxide, a 6-membered ring aliphatic N-oxide with a methyl at the N-oxide nitrogen, is bound by the equatorial −N–CH3 group located deep in the cavity. 2-Iodopyridine N-oxide is the only guest that manifests intermolecular N–O⋯I–C halogen bond interactions, which are broken down by the host resulting i…
Projekts: Uzņēmuma SIA"Riga electric scooter tour" izveidošana
2020
Maģistra darba ietvaros autors izvēlējās veidot jaunu uzņēmumu SIA “Riga electric scooter tour”, kas tūristiem un citiem interesentiem piedāvās nelielās grupās gida pavadībā, pārvietojoties ar elektriskajiem skrejriteņiem, iepazīt Rīgas populārākās un kultūrvēsturiski nozīmīgākās vietas un apskates objektus. Lai sekmīgi varētu sniegt ekskursijas līdz 7 cilvēkiem lielās grupās gida pavadībā, būs nepieciešams iegādāties 8 elektriskos skrejriteņus “KICKSCOOTER ES1”, kurus ražo uzņēmums Ninebot by Segway, kas būs vienīgie uzņēmuma pamatlīdzekļi. Konkrētā modeļa braucamrīki tika izvēlētie, jo ar vienu uzlādi ar tiem var nobraukt vismaz tāda garuma distanci, kā plānots ekskursijas maršruta garums…
Strong Emission Enhancement in pH-Responsive 2:2 Cucurbit[8]uril Complexes
2019
Organic fluorophores, particularly stimuli-responsive molecules, are very interesting for biological and material sciences applications, but frequently limited by aggregation- and rotation-caused photoluminescence quenching. A series of easily accessible bipyridinium fluorophores, whose emission is quenched by a twisted intramolecular charge-transfer (TICT) mechanism, is reported. Encapsulation in a cucurbit[7]uril host gave a 1:1 complex exhibiting a moderate emission increase due to destabilization of the TICT state inside the apolar cucurbituril cavity. A much stronger fluorescence enhancement is observed in 2:2 complexes with the larger cucurbit[8]uril, which is caused by additional con…