Search results for "libration"
showing 10 items of 901 documents
Size-Exclusion Chromatographic Determination of Polymer Molar Mass Averages Using a Fractal Calibration
2005
The characterization of polymers by size-exclusion chromatography basically consists of the determination of the weight-average molar mass (Mw), number-average molar mass (Mn), and polydispersity index (I). An accurate estimation of these magnitudes requires the use of a reliable and trusted calibration curve. Three procedures for building up a calibration curve are analyzed in this work. The first is the classical universal calibration (UC), based on the elution of tetrahydrofuran-polystyrene in a system as reference. The second is based on the proper calibration curve made with standards of the sample under study. However, two main drawbacks arise when using these methodologies: the nonfu…
Exploring the effect of absence selection on landslide susceptibility models: A case study in Sicily, Italy
2016
Abstract A statistical approach was employed to model the spatial distribution of rainfall-triggered landslides in two areas in Sicily (Italy) that occurred during the winter of 2004–2005. The investigated areas are located within the Belice River basin and extend for 38.5 and 10.3 km 2 , respectively. A landslide inventory was established for both areas using two Google Earth images taken on October 25th 2004 and on March 18th 2005, to map slope failures activated or reactivated during this interval. Geographic Information Systems (GIS) were used to prepare 5 m grids of the dependent variables (absence/presence of landslide) and independent variables (lithology and 13 DEM-derivatives). Mul…
New cut-off criterion for uninformative variable elimination in multivariate calibration of near-infrared spectra for the determination of heroin in …
2008
A new cut-off criterion has been proposed for the selection of uninformative variables prior to chemometric partial least squares (PLS) modelling. After variable elimination, PLS regressions were made and assessed comparing the results with those obtained by PLS models based on the full spectral range. To assess the prediction capabilities, uninformative variable elimination (UVE)-PLS and PLS were applied to diffuse reflectance near-infrared spectra of heroin samples. The application of the proposed new cut-off criterion, based on the t-Students distribution, provided similar predictive capabilities of the PLS models than those obtained using the original criteria based on quantile value. H…
Multivariate regression analysis applied to the calibration of equipment used in pig meat classification in Romania.
2016
This paper highlights the statistical methodology used in a dissection experiment carried out in Romania to calibrate and standardize two classification devices, OptiGrade PRO (OGP) and Fat-o-Meat'er (FOM). One hundred forty-five carcasses were measured using the two probes and dissected according to the European reference method. To derive prediction formulas for each device, multiple linear regression analysis was performed on the relationship between the reference lean meat percentage and the back fat and muscle thicknesses, using the ordinary least squares technique. The root mean squared error of prediction calculated using the leave-one-out cross validation met European Commission (EC…
Determination of vinegar acidity by attenuated total reflectance infrared measurements through the use of second-order absorbance-pH matrices and par…
2007
Univariate (zero-order), multivariate (first-order) and multiway (second-order) calibrations were assayed for the determination of vinegar acidity using a mechanized procedure based upon vibrational spectroscopy and the emerging multicommutation methodology. The second-order methodology relies on the use of a flow system based on multicommutation and binary sampling. The flow network comprises a set of three-way solenoid valves, computer-controlled to provide facilities to handle the sample and to generate a time-dependent pH gradient using two carrier solutions. The procedure is based on the volumetric fraction variation approach that maintains the same volume of sample solution and dynami…
Combination of mid- and near-infrared spectroscopy for the determination of the quality properties of beers
2006
Abstract The combination of infrared (MIR) and near-infrared (NIR) spectroscopy has been employed for the determination of important quality parameters of beers, such as original and real extract and alcohol content. A population of 43 samples obtained from the Spanish market and including different types of beer, was evaluated. For each technique, spectra were obtained in triplicate. In the case of NIR a 1 mm pathlength quartz flow cell was used, whereas attenuated total reflectance measurements were used in MIR. Cluster hierarchical analysis was employed to select calibration and validation data sets. The calibration set was composed of 15 samples, thus leaving 28 for validation. A critic…
A green method for the determination of cocaine in illicit samples
2013
Abstract Direct determination of cocaine in untreated seized samples has been made based on diffuse reflectance measurements of the near infrared (NIR) radiation through samples contained inside standard glass vials. The method used a series of previously analyzed samples, by the reference gas chromatography method, to build a partial least squares calibration model which was validated using an independent set of samples. The use of a general model for samples containing from 11.38% till 86.44% (w/w) cocaine was based on the use of spectral ranges from 12500.7 to 10128.6, 9339.8 to 6967.7 and 5388.3 to 4597.6 cm−1 with previous first derivative and vector normalization data pre-processing a…
Retro-nasal aroma release is correlated with variations in the in-mouth air cavity volume after empty deglutition.
2012
International audience; We hypothesized that interindividual differences in motor activities during chewing and/or swallowing were determining factors for the transfer of volatile aroma from the in-mouth air cavity (IMAC) toward the olfactory mucosa. In our first experiment, we looked for changes in IMAC volume after saliva deglutition in 12 healthy subjects. The mean IMAC volume was measured after empty deglutition using an acoustic pharyngometer device. Based on the time course of the IMAC volume after swallowing, we discerned two groups of subjects. The first group displayed a small, constant IMAC volume (2.26 mL ±0.62) that corresponded to a high tongue position. The second group displa…
The SMAP and Copernicus Sentinel 1A/B microwave active-passive high resolution surface soil moisture product
2019
Abstract Soil Moisture Active Passive (SMAP) mission of NASA was launched in January 2015. Currently, SMAP has an L-band radiometer and a defunct L-band radar with a rotating 6-m mesh reflector antenna. On July 7th, 2015, the SMAP radar malfunctioned and became inoperable. Consequently, the production of high-resolution active-passive soil moisture product got hampered, and only ~2.5 months (April 15th, 2015 to July 7th, 2015) of data remain available. Therefore, during the SMAP post-radar phase, many ways were examined to restart the high-resolution soil moisture product generation of the SMAP mission. One of the feasible approaches was to substitute the SMAP radar with other available SAR…
Land surface temperature derived from airborne hyperspectral scanner thermal infrared data
2006
Abstract The AHS (airborne hyperspectral scanner) instrument has 80 spectral bands covering the visible and near infrared (VNIR), short wave infrared (SWIR), mid-infrared (MIR), and thermal infrared (TIR) spectral range. The instrument is operated by Instituto Nacional de Tecnica Aerospacial (INTA) and it has been involved in several field campaigns since 2004. The main goal of this paper is to analyze the feasibility of retrieving land surface temperature from the 10 AHS thermal infrared bands, from 71 to 80, located in the region between 8 and 13 μm. For this purpose, three different methods have been considered: (i) the single-channel method, which uses only one thermal band; (ii) the sp…