Search results for "lies"
showing 10 items of 1093 documents
Magnetic field driven micro-convection in the Hele-Shaw cell
2013
AbstractMicro-convection caused by ponderomotive forces of the self-magnetic field of a magnetic fluid in the Hele-Shaw cell under the action of a vertical homogeneous magnetic field is studied both experimentally and numerically. It is shown that a non-potential magnetic force at magnetic Rayleigh numbers greater than the critical value causes fingering at the interface between the miscible magnetic and non-magnetic fluids. The threshold value of the magnetic Rayleigh number depends on the smearing of the interface between fluids. Fingering with its subsequent decay due to diffusion of particles significantly increases the mixing at the interface. Velocity and vorticity fields at fingering…
Thermal-, pressure- and light-induced spin-crossover behviour in the two-dimensional Hofman-like coordination polymer [Fe(3-Clpy)2Pd(CN)4]
2013
The thermal spin-crossover behaviour, photoexcitation and subsequent relaxation, as well as the pressure-induced spincrossover behaviour at 298 K are discussed for the non-porous two-dimensional Hofmann-like coordination polymer [Fe(3-Clpy)(2)Pd(CN)(4)] (1). The title compound undergoes a two-step, cooperative thermal-induced SCO with critical temperatures T-c1(down arrow) = 159.6 K and T-c1(up arrow) = 164.5 K for the first step and T-c2(down arrow) = 141.4 K and T-c2(up arrow) = 148.4 K for the second step. Irradiation of the low-spin state with green light (514 nm) at 10 K induced the photoexcitation of around 60% of the iron(II) centres to the high-spin state (LIESST effect). The subseq…
Cyanocarbanion-based spin-crossover materials: photocrystallographic and photomagnetic studies of a new iron(II) neutral chain
2010
International audience; A new iron(II) chain of formula [Fe(abpt)(2)(tcpd)] [1; (tcpd)(2-) = [C(10)N(6)](2-) = (C[C(CN)(2)](3))(2-) = 2-dicyanomethylene-1,1,3,3-tetracyanopropanediide anion, abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole] has been synthesized and characterized by IR spectroscopy, detailed variable-temperature single-crystal X-ray diffraction, magnetic and photomagnetic measurements. The crystal structure determination of 1 reveals a one-dimensional structural architecture in which the (tcpd)(2-) cyanocarbanion acts as a μ(2)-bridging ligand and the two abpt molecules act as chelating ligands. Detailed X-ray diffraction studies as a function of the temperature (293-10 K…
Photomagnetic properties of an Iron(II) low-spin complex with an unusually long-lived metastable LIESST state
2007
A comprehensive study of the photomagnetic behavior of the [Fe(L222N5)(CN)2].H2O complex has been carried out. This complex is characterized by a low-spin (LS) iron(II)-metal center up to 400 K and exhibits at 10 K the well-known Light-Induced Excited Spin State Trapping (LIESST) effect. The critical LIESST temperature (T(LIESST)) has been measured to be 105 K. The kinetics of the transition from the metastable high-spin (HS) state to the low-spin state have been determined and used for reproducing the experimental T(LIESST) curve. This study represents a second example of a fully low-spin iron(II)-metal complex up to 400 K, which can be photoexcited at low temperature with an atypical long…
Prevalence of anatomical variants and coronary anomalies in 543 consecutive patients studied with 64-slice CT coronary angiography
2008
The aim of our study was to assess the prevalence of variants and anomalies of the coronary artery tree in patients who underwent 64-slice computed tomography coronary angiography (CT-CA) for suspected or known coronary artery disease. A total of 543 patients (389 male, mean age 60.5 +/- 10.9) were reviewed for coronary artery variants and anomalies including post-processing tools. The majority of segments were identified according to the American Heart Association scheme. The coronary dominance pattern results were: right, 86.6%; left, 9.2%; balanced, 4.2%. The left main coronary artery had a mean length of 112 +/- 55 mm. The intermediate branch was present in the 21.9%. A variable number …
Right coronary artery arising from pulmonary trunk: assessment with conventional coronary angiography and multislice computed tomography coronary ang…
2009
We present a case of a 59-year-old man who was admitted to the hospital because of atypical chest pain and dyspnea. Conventional coronary angiography showed an anomalous origin of the right coronary artery from the pulmonary trunk. The patient underwent multislice computed tomography in order to clarify the origin and course of the anomalous vessel. The aim of this report is to emphasize the role of multislice computed tomography as an accurate noninvasive imaging tool in the evaluation of coronary artery anomalies.
Anatomical variants and anomalies of the coronary tree studied with MDCT coronary angiography
2010
Le anomalie delle arterie coronariche sono presenti alla nascita nella maggior parte dei casi asintomatiche ma possono manifestarsi con sintomatologia severa quale angina pectoris o addirittura l’arresto cardiaco. L’angiografia coronarica mediante tomografia computerizzata multistrato (TCMS) permette, tramite ricostruzioni multiplanari secondo piani curvilinei e riformattazioni 3D, la visualizzazione dell’albero coronarico e delle sue varianti ed anomalie in maniera non invasiva, fornendo migliore e più accurata alternativa alla angiografia coronarica (AC). Lo scopo di questo pictorial consiste nella descrizione mediante immagini TCMS con ricostruzioni multiplanari e 3D delle principali var…
New discoveries in New World Atissini as revealed in revision of Pelignellus Sturtevant & Wheeler (Diptera: Ephydridae)
2019
Pelignellus is resurrected from synonymy with Atissa and is revised. The genus and both included species—P. subnudus Sturtevant & Wheeler from the USA (California) and P. freidbergi n. sp. from Central America (Costa Rica, El Salvador, Panama)—are described with an emphasis on structures of the male terminalia, which are fully illustrated. The species are keyed and their distribution data are provided. For perspective and to facilitate recognition of genera and species, the tribe Atissini is diagnosed and a key to genera is provided.
Frequency conversion of propagating surface plasmon polaritons by organic molecules
2008
We demonstrate frequency conversion of surface plasmon polaritons (SPP) by utilizing the coupling between organic dye molecules and SPP. Launching of SPPs into a plasmonic waveguide is done in two ways: by optically excited molecules and by quantum dots (QDs). QDs are demonstrated to overcome the major problem of bleaching occurring with molecules. The SPP propagates tens of micrometers and clear frequency conversion is observed in the SPP spectrum after passing an area of converter molecules. The use of molecules and QDs as elements of all-plasmonic devices has the potential for high integration and use of self-assembly in fabrication. Peer reviewed
Sekcija “Dezinformācijas un sazvērestību radītie riski demokrātijai: Latvijas pieredzes pārlūkošana”: Kopsavilkumi : 2021. gada 25. un 26. februāris
2021
Latvijas Zinātnes padomes fundamentālo un lietišķo projektu programmas projekts “Dezinformācijas un sazvērestību radītie riski demokrātijai: Latvijas pieredzes pārlūkošana” (lzp-2019/1-0278)