Search results for "lignin"

Anodic Degradation of Lignin at Active Transition Metal-based Alloys and Performance-enhanced Anodes

2018

Warm season precipitation signal in δ 2 H values of wood lignin methoxyl groups from high elevation larch trees in Switzerland

2017

RATIONALE In this study, we tested stable hydrogen isotope ratios of wood lignin methoxyl groups (δ 2Hmethoxyl values) as a palaeoclimate proxy in dendrochronology. This is a quite new method in the field of dendrochronology and the sample preparation is much simpler than the methods used before to measure δ2H values from wood. METHODS We measured δ 2Hmethoxyl values in high elevation larch trees (Larix decidua Mill.) from Simplon Valley (southern Switzerland). Thirty-seven larch trees were sampled and five individuals analysed for their δ 2Hmethoxyl values at annual (1971-2009) and pentadal resolution (1746-2009). The δ 2Hmethoxyl values were measured as CH3I released upon treatment of the…

Annually resolved δ<sup>2</sup>H tree-ring chronology of the lignin methoxyl groups from Germany reflects averaged Wester…

2019

Abstract. Stable hydrogen isotopes ratios of lignin methoxyl groups (expressed as δ2HLM) of wood have been shown to reflect the climate-sensitive δ2H values of precipitation (expressed as δ2Hprecip) modulated by a large uniform negative isotope fractionation. However, a detailed calibration study among temporal variabilities of δ2HLM in tree-ring series, site-specific δ2Hprecip and climate parameters has not been performed yet. Here, we present annually resolved δ2HLM values from nine tree-ring series (derived from four Fagus sylvatica L. trees) collected near stations of the Global Isotope Network of Isotopes in Precipitation (GNIP) and the Deutsche Wetterdienst (DWD) meteorological observ…

Tree-ring δ2H values from lignin methoxyl groups indicate sensitivity to European-scale temperature changes

2020

Abstract Stable hydrogen isotope ratios of lignin methoxyl groups (δ2HLM) of wood have been shown to reflect climate-sensitive δ2H values of precipitation (δ2Hprecip). However, a detailed calibration study between high-resolution δ2HLM and δ2Hprecip data has not been performed yet. Here, we present annually resolved δ2HLM values from nine tree-ring series (derived from four Fagus sylvatica L. trees) collected near a station of the Global Isotope Network of Isotopes in Precipitation (GNIP) and the meteorological observatory at Hohenpeisenberg (Germany; ~48°N, 11°E). The nine δ2HLM tree-ring series show highly significant inter-series correlations (Rbar = 0.52) over the common period of overl…

Lignin oxidation products as a vegetation proxy in stalagmite and drip water samples from the Herbstlabyrinth, Germany

2019

Here we present the first quantitative record of lignin oxidation products (LOPs) in a Holocene stalagmite from the Herbstlabyrinth Cave in central Germany, as well as LOP results from 16 months of drip water monitoring. Lignin is only produced by vascular plants and is therefore an unambiguous vegetation proxy, which can help to better interpret other vegetation and climate proxies in speleothems. We compared our results with stable isotope and trace element data from the same samples. The drip water monitoring reveals a seasonal pattern of LOPs in a fast drip site with low LOP concentrations in winter and higher LOP concentrations in summer, which is opposite to the behaviour of the drip …

Imidazolium Based Ionic Liquids: A Promising Green Solvent for Water Hyacinth Biomass Deconstruction.

2018

Water hyacinth (WH) is a troublesome aquatic weed of natural and artificial water bodies of India and other tropical countries and causing severe ecological problems. The WH biomass is low in lignin content and contains high amount of cellulose and hemicellulose, making it suitable material for conversion into liquid fuels for energy production. This study highlighted that, how different imidazolium based ionic liquids (ILs) [1-alkyl-3-methylimidazolium bromide, [Cnmim]Br (n = 2, 4, 6, 8, and 10)] with tunable properties can be employed for the degradation of WH biomass. Different characterizations techniques, such as XRD, FT-IR, SEM, and DSC are used to unravel the interplay between ILs an…

The Altered Expression of microRNA408 Influences the Arabidopsis Response to Iron Deficiency

2019

MicroRNAs contribute to the adaptation of plants to varying environmental conditions by affecting systemic mineral nutrient homeostasis. Copper and iron deficiencies antagonistically control the expression of Arabidopsis thaliana microRNA408 (miR408), which post-transcriptionally regulates laccase-like multicopper oxidase family members LAC3, LAC12, and LAC13. In this work, we used miR408 T-DNA insertion mutants (408-KO1 and 408-KO2) and a previously characterized transgenic line overexpressing miR408 (35S:408-14) to explore how miR408 influences copper- and iron-dependent metabolism. We observed that the altered expression of miR408 diminished plant performance and the activation of the ir…

Bioethanol and lipid production from the enzymatic hydrolysate of wheat straw after furfural extraction

2018

This study investigates biofuel production from wheat straw hydrolysate, from which furfural was extracted using a patented method developed at the Latvian State Institute of Wood Chemistry. The solid remainder after furfural extraction, corresponding to 67.6% of the wheat straw dry matter, contained 69.9% cellulose of which 4% was decomposed during the furfural extraction and 26.3% lignin. Enzymatic hydrolysis released 44% of the glucose monomers in the cellulose. The resulting hydrolysate contained mainly glucose and very little amount of acetic acid. Xylose was not detectable. Consequently, the undiluted hydrolysate did not inhibit growth of yeast strains belonging to Saccharomyces cerev…

Combustion Properties of Birch (Betula pendula) Black Liquors From Sulfur-Free Pulping

2016

Sulfur-free pulping has an environmental advantage over the traditional kraft process. This article describes the combustion properties of the black liquors produced from silver birch (Betula pendula) sawdust using three different cooking processes: two sulfur-free cooks (soda-anthraquinone and oxygen-alkali), and one reference kraft cook. It also considers the corresponding black liquors from an integrated forest biorefinery, in which a hot-water pretreatment of feedstock was performed prior to pulping. With the same cooking time, the total burning times for the sulfur-free black liquors were higher (15–55%) than those for the conventional kraft black liquors. However, no significant diffe…

Highly-Efficient Release of Ferulic Acid from Agro-Industrial By-Products via Enzymatic Hydrolysis with Cellulose-Degrading Enzymes: Part I–The Super…

2021

Historically Triticum aestívum L. and Secale cereále L. are widely used in the production of bakery products. From the total volume of grain cultivated, roughly 85% is used for the manufacturing of flour, while the remaining part is discarded or utilized rather inefficiently. The limited value attached to bran is associated with their structural complexity, i.e., the presence of cellulose, hemicellulose, and lignin, which makes this material suitable mostly as a feed supplement, while in food production its use presents a challenge. To valorize these materials to food and pharmaceutical applications, additional pre-treatment is required. In the present study, an effective, sustainable, and …