Search results for "liquid"
showing 10 items of 4351 documents
Fermi Liquid with Fermion Condensate
2014
Here we discuss the general properties of FCQPT leading to the emergence of FC. We present a microscopic derivation of the main equations of FC, and show that Fermi systems with FC form an entirely new class of Fermi liquids with its own topological structure, protecting the FC state. We construct the phase diagram, and explore the order parameter of these systems. We show that the fermion condensate has a strong impact on the observable physical properties of systems, where it is realized, up to relatively high temperatures of a few tens kelvin. Two different scenarios of the quantum critical point (QCP), a zero-temperature instability of the Landau state, related to the divergence of the …
Metals with a Strongly Correlated Electron Liquid
2014
In this chapter, we consider the main properties of strongly correlated Fermi systems, which are formed by the fermion condensate leading to the emergence of flat bands. Namely, we consider the residual entropy \(S_0\) related to the flat bands that leads to the violation of the quasiparticle—hole symmetry. The presence of \(S_0\) has a profound impact on the universality of second order phase transitions. In that case under the application of magnetic field the curve of the second order AF phase transitions passes into a curve of the first order ones at the tricritical point, thus leading to a violation of the critical universality of the fluctuation theory. We demonstrate that a jump in t…
Transition to ballistic regime for heat transport in helium II
2014
The size-dependent and flux-dependent effective thermal conductivity of narrow capillaries filled with superfluid helium is analyzed from a thermodynamic continuum perspective. The classical Landau evaluation of the effective thermal conductivity of quiescent superfluid, or the Gorter-Mellinck regime of turbulent superfluids, are extended to describe the transition to ballistic regime in narrow channels wherein the radius $R$ is comparable to (or smaller than) the phonon mean-free path $\ell$ in superfluid helium. To do so we start from an extended equation for the heat flux incorporating non-local terms, and take into consideration a heat slip flow along the walls of the tube. This leads f…
Photochemistry of 3,6-bis(styryl)pyridazines in solution and in neat liquid crystalline phase—optical switching and imaging techniques
2008
Abstract 3,6-Bis(styryl)pyridazines 1a – f with 2–6 alkoxy groups show on irradiation in solution a stereoisomerization which leads to a photostationary state of ( E , E )- and ( E , Z )-isomer. Sensitizing and quenching experiments reveal that the ( E , E )→( E , Z ) route is a pure triplet process, whereas the ( E , Z )→( E , E ) route can have a minor singlet by-reaction. Hexyloxy or dodecyloxy chains on the terminal benzene rings convey the ( E , E )-isomers of compounds 1a , b , d – f thermotropic liquid crystalline properties. In particular S A , S C , and S F/I phases were studied with regard to their photochemical behavior. Depending on the system, photodegradation of the smectic ph…
Influence of crystal defects on the electromigration of the hydrogen in palladium
2001
Abstract Electromigration and diffusion of hydrogen in palladium defected through quenching to liquid nitrogen temperature were investigated. It was found that the obtained experimental results cannot be described by means of a single flux of hydrogen which diffuses in a gradient of electric field. In order to effectively explain the obtained results, a theoretical model was elaborated. It assumed the existence of the following two fluxes of hydrogen in the quenched metal: • Ji—of migration, according to the interstitial mechanism, and • Ji–d—of migration, according to the interstitial-defective mechanism. Dependence of effective valences and diffusion coefficients for both mechanisms of tr…
On the operation of silicon photomultipliers at temperatures of 1–4 kelvin
2016
Abstract SiPM operation at cryogenic temperatures fails for many common devices. A particular type from Zecotek with deep channels in the silicon substrate instead of quenching resistors was tested at liquid helium temperature. Two similar types were thoroughly characterized from room temperature down to liquid nitrogen temperature by illuminating them with low light levels. At cryogenic temperatures the SiPMs show an unchanged rise-time and a fast recovery time, practically no after-pulses, and exhibit no increased cross-talk probability. Charge collection spectra were measured to extract the pixel gain and its variation, both comparable to room temperature at the same over-voltage. The qu…
Transintestinal secretion of ciprofloxacin, grepafloxacin and sparfloxacin: in vitro and in situ inhibition studies.
2003
The influence of the secretion process on the absorption of ciprofloxacin, grepafloxacin and sparfloxacin has been evaluated by means of inhibition studies. Two well known P-glycoprotein inhibitors (cyclosporine, verapamil), a mixed inhibitor of P-glycoprotein and the organic cation transporter OCT1 (quinidine) and a well established MRP substrate (p-aminohipuric acid) have been selected in order to distinguish the possible carriers implicated. An in situ rat gut perfusion model and CACO-2 permeability studies are used. Both methods suggest the involvement of several types of efflux transporters for every fluoroquinolone. The relevance of the secretory pathway depends on the intrinsic perme…
Supramolecular hierarchy among halogen and hydrogen bond donors in light-induced surface patterning
2015
Halogen bonding, a noncovalent interaction possessing several unique features compared to the more familiar hydrogen bonding, is emerging as a powerful tool in functional materials design. Herein, we unambiguously show that one of these characteristic features, namely high directionality, renders halogen bonding the interaction of choice when developing azobenzene-containing supramolecular polymers for light-induced surface patterning. The study is conducted by using an extensive library of azobenzene molecules that differ only in terms of the bond-donor unit. We introduce a new tetrafluorophenol-containing azobenzene photoswitch capable of forming strong hydrogen bonds, and show that an io…
Rilassometria 1H-NMR per la caratterizzazione di legni integri e degradati
2006
La caratterizzazione del legno riveste un particolare ruolo negli studi volti alla conservazione di manufatti lignei di interesse storico-artistico-archeologico. Le proprietà meccaniche del legno dipendono dalla specie, dal contenuto d’acqua, dalla direzione delle fibre, dalla porosità, dalla distribuzione dei pori e, in generale, da un insieme di condizioni che non sempre sono facilmente misurabili e controllabili. Di particolare interesse sono i metodi di indagine non invasivi e non distruttivi; tra questi si sta affermando la Risonanza Magnetica Nucleare (NMR) [1,2]. In questo lavoro metodi di Rilassometria 1H-NMR, messi a punto per il tessuto osseo [3], sono stati applicati allo studio …
Age-dependent regulation of antioxidant genes by p38α MAPK in the liver
2018
p38α is a redox sensitive MAPK activated by pro-inflammatory cytokines and environmental, genotoxic and endoplasmic reticulum stresses. The aim of this work was to assess whether p38α controls the antioxidant defense in the liver, and if so, to elucidate the mechanism(s) involved and the age-related changes. For this purpose, we used liver-specific p38α-deficient mice at two different ages: young-mice (4 months-old) and old-mice (24 months-old). The liver of young p38α knock-out mice exhibited a decrease in GSH levels and an increase in GSSG/GSH ratio and malondialdehyde levels. However, old mice deficient in p38α had higher hepatic GSH levels and lower GSSG/GSH ratio than young p38α knock-…