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showing 10 items of 1967 documents
Do too many choices have negative consequences? An empirical review
2013
Various experiments demonstrated that having too much choice has negative consequences on the motivation to choose and on the satisfaction with the chosen option. However, the literature reports conflicting results showing that choosing from large assortments has advantages. This paper reviews the main empirical results in favor and against the negative effect of too much choice and identifies possible directions for further research. Copyright © 2013 by Società editrice il Mulino.
Pauson-Khand reaction of internal dissymmetric trifluoromethyl alkynes. Influence of the alkene on the regioselectivity.
2014
Abstract: The scope of the Pauson-Khand reaction (PKR) of internal trifluoromethyl alkynes, previously described with norbornadiene, is expanded to norbornene and ethylene. A thorough structural analysis of the resulting PK adducts has been carried out to unveil that α-trifluoromethylcyclopentenones are preferred in all cases, independently of the electronic properties of the alkyne. The regioselectivity observed with norbornadiene and ethylene is higher than in the case of norbornene.
Total Synthesis of (-)-Hymenosetin.
2015
The 3-decalinoyltetramic acid (−)-hymenosetin and its N-methyl analogue were prepared in 11 and 8 steps, respectively, from (+)-citronellal using an intramolecular Diels–Alder reaction as the key step. This method represents the first example for the synthesis of a 3-decalinoyltetramic acid with a free NH moiety. The stereochemistry of the title compound, an unnatural diastereomer, and of a decalin building block was studied in detail using circular dichroism spectroscopy in the IR and UV/VIS freqeuncy range. This allowed to determine the absolute configuration of the natural product and to plan the synthetic route.
Combining workload balance and patient priority maximisation in operating room planning through hierarchical multi-objective optimisation
2022
Abstract Previous analysis suggested the opportunity to consider the preferences of different stakeholders (hospital, patients, doctors and nurses) through the adoption of both patient priority maximisation and workload balance as performance criteria. The aim of this paper is to develop an effective and efficient solution approach for the operating room planning and scheduling capable to take into account the patient priority maximisation and workload balance criteria at the same time. This work is inspired by the need of a deeper understanding of the quality of the solutions obtained when a combination of the two criteria leads the OR planning decisions. Starting from a hierarchical multi…
Distributing Storage in Cloud Environments
2013
Cloud computing has a major impact on today's IT strategies. Outsourcing applications from IT departments to the cloud relieves users from building big infrastructures as well as from building the corresponding expertise, and allows them to focus on their main competences and businesses. One of the main hurdles of cloud computing is that not only the application, but also the data has to be moved to the cloud. Networking speed severely limits the amount of data that can travel between the cloud and the user, between different sites of the same cloud provider, or indeed between different cloud providers. It is therefore important to keep applications near the data itself. This paper investig…
Prevalence and determinants of secondary posttraumatic growth following trauma work among medical personnel: a cross sectional study
2021
Background: People helping trauma victims as a part of their work may experience positive results, known as Secondary Posttraumatic Growth (SPTG). Aim: The present study aimed to determine the prevalence and determinants of SPTG among medical personnel, considering occupational load, job satisfaction, social support, and cognitive processing of trauma, understood as cognitive coping strategies. Methods: Subjects comprised 419 representatives of the medical profession, including paramedics and nurses. The age of the subjects varied from 19 to 65 (M = 39.60; SD = 11.03). Four standard measurement tools were utilized: the Secondary Posttraumatic Growth Inventory, the Job Satisfaction Scale, th…
Software for simulating dichromatic perception of video streams
2013
We have designed a configurable stand-alone Matlab-based software to simulate dichromatic perception of video streams. The algorithm used is an extension for video streams of the “corresponding pair algorithm” by Capilla and coworkers for simulation of dichromatic perception of images. The software allows the user to upload a video sequence and to process it using different dichromatic color vision models and viewing conditions. The output video may be generated in different spatial and temporal resolutions and file formats. The functions for Matlab environment and a stand-alone application may be downloaded from the Repository of the University of Alicante. © 2013 Wiley Periodicals, Inc. C…
Selection in captive populations
1986
We have briefly reviewed types of genetic variation and selection in the wild as contrasted with selection in captive populations, along with the objectives of captive breeding programs, before recommending selection procedures for the genetic management of captive populations. Although some inadvertent selection for tameness and adaptation to captive environments is inevitable in captive populations, any selection that is actively applied to captive populations should have clearly defined objectives. Much of the apparent disagreement about genetic management of captive populations probably stems from the varying objectives of different captive breeding programs. Objectives differ depending…
A Fiber Optic Strain Gage Sensor for Measuring Preload in Thick Composite Bolted Joints
2019
Mechanical fastening is a popular choice in joining composites because of the ability to transfer high loads and the ease of assembly and disassembly. In this study, the failure behavior of composite–aluminum single lap bolted joint is investigated. In particular, the effects of varying the preload on the bolt are examined. In order to accurately measure the preload, a specialized sensor that uses a fiber Bragg grating sensor embedded in the bolt is proposed and created. This sensor is realized for the current tests but can be expanded to other applications. An experimental study of bolted single-lap joints varying the tightening torque value has been carried out and, in order to validate t…
The tandem Diels-Alder reaction between acetylenedicarboxyaldehyde and N,N'-dipyrrolylmethane. An ab initio study of the molecular mechanisms
1998
Abstract An extensive exploration at RHF/3-21G and RHF/6-31G ∗ levels of the potential energy surface for the tandem cycloaddition of acetylenedicarboxyaldehyde to N,N'-dipyrrolylmethane allows us to characterize the reaction pathways and the associated stationary points. The formation of the pincer and/or domino adducts can be described as a stepwise mechanism. The first step, associated with an intermolecular [4 + 2] cycloaddition, is the rate determining step and an azanorbornadiene intermediate is obtained. The second step is an intramolecular [4 + 2] cycloaddition. The formation of the pincer adduct is the step which kinetically controls the global process, due to the low barrier heigh…