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showing 10 items of 233 documents

Synthesis of substituted piperidines by enantioselective desymmetrizing intramolecular aza-Michael reactions.

2018

An organocatalytic enantioselective intramolecular aza-Michael reaction has been described for the first time in a desymmetrization process employing substrates different from cyclohexadienones. By using 9-amino-9-deoxy-epi-hydroquinine as the catalyst and trifluoroacetic acid as a co-catalyst, a series of enantiomerically enriched 2,5-and 2,6-disubstituted piperidines have been obtained in good yields and with moderate diastereoselectivity. Depending on the catalyst/co-catalyst loading ratio, either the major or the minor diastereoisomer of the final piperidine products was achieved with high levels of enantioselectivity. Finally, some mechanistic insights have been considered by means of …

010405 organic chemistryChemistryOrganic ChemistryEnantioselective synthesisDiastereomer010402 general chemistry01 natural sciencesBiochemistryDesymmetrization0104 chemical sciencesCatalysischemistry.chemical_compoundLoading ratioIntramolecular forceTrifluoroacetic acidOrganic chemistryPiperidinePhysical and Theoretical ChemistryOrganicbiomolecular chemistry
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Shallow system rejuvenation and magma discharge trends at Piton de la Fournaise volcano (La Réunion Island)

2017

International audience; Basaltic magma chambers are often characterized by emptying and refilling cycles that influence their evolution in space and time, and the associated eruptive activity. During April 2007, the largest historical eruption of Piton de la Fournaise (Île de La Réunion, France) drained the shallow plumbing system (>240×106 m3>240×106 m3) and resulted in collapse of the 1-km-wide summit crater. Following these major events, Piton de la Fournaise entered a seven-year long period of near-continuous deflation interrupted, in June 2014, by a new phase of significant inflation. By integrating multiple datasets (lava discharge rates, deformation, seismicity, gas flux, gas composi…

010504 meteorology & atmospheric sciencesLavaeffusive paroxysmMagma chamber010502 geochemistry & geophysicseffusive trend01 natural sciencesEffusive eruptionImpact crater[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistryeffusive paroxysm; effusive trends; Piton de la Fournaise; shallow plumbing system; unloading; Geophysics; Geochemistry and Petrology; Earth and Planetary Sciences (miscellaneous); Space and Planetary ScienceGeochemistry and Petrologyunloading[SDU.STU.VO]Sciences of the Universe [physics]/Earth Sciences/VolcanologyEarth and Planetary Sciences (miscellaneous)Petrology0105 earth and related environmental sciencesBasaltgeographygeography.geographical_feature_categoryeffusive trendsFumarolePiton de la FournaiseGeophysicsVolcanoshallow plumbing systemSpace and Planetary ScienceMagmaGeologySeismology
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Positive effect of platelet rich fibrin on osseointegration

2016

Background Leukocyte-platelet rich fibrin (L-PRF) is a second generation platelet concentrate clinically used to accelerate tissue healing and bone regeneration. Achieving reduced implant osseointegration time could provide immediate or early loading of implants. The aim of this study was to evaluate the L-PRF-induced osseointegration and bone-implant contact (BIC) in an experimental animal model. Material and Methods Twelve 4-month-old New Zealand white rabbits were used. Following general anesthesia, 3-5 mL of blood was obtained from the central artery in rabbit ear and L-PRF was prepared. Two implant cavities (5 mm long and 3 mm in diameter) were created in each tibia with a total of fou…

0106 biological sciencesBone RegenerationDentistry01 natural sciencesOsseointegrationFibrin03 medical and health sciences0302 clinical medicineOsseointegrationPlatelet-Rich Fibrin010608 biotechnologyEarly loadingAnimalsMedicinePlatelet concentrateBone regenerationMatrix for growth factorsGeneral DentistryDental ImplantsFibrinbiologybusiness.industryResearch030206 dentistry:CIENCIAS MÉDICAS [UNESCO]digestive system diseasesPlatelet-rich fibrinExperimental animalOtorhinolaryngologyUNESCO::CIENCIAS MÉDICASbiology.proteinSurgeryRabbitsImplantOral SurgerybusinessPlatelet rich fibrinMedicina Oral Patología Oral y Cirugia Bucal
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Food load manipulation ability shapes flight morphology in females of central-place foraging Hymenoptera

2013

Received: 19 March 2013.- Accepted: 20 June 2013.- Published: 28 June 2013

0106 biological sciencesForagingWaspsBiodiversityHymenopteraBiologyDevelopment010603 evolutionary biology01 natural sciencesPredation03 medical and health sciencesWing loadingForagingCoevolutionEcology Evolution Behavior and Systematics030304 developmental biology0303 health sciencesNatural selectionEcologyResearchFlight Muscle RatioBeesbiology.organism_classificationLower wingWing LoadingAnimal Science and ZoologyFrontiers in Zoology
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Impact loading history modulates hip fracture load and location : A finite element simulation study of the proximal femur in female athletes

2018

Sideways falls impose high stress on the thin superolateral cortical bone of the femoral neck, the region regarded as a fracture-prone region of the hip. Exercise training is a natural mode of mechanical loading to make bone more robust. Exercise-induced adaptation of cortical bone along the femoral neck has been previously demonstrated. However, it is unknown whether this adaption modulates hip fracture behavior. The purpose of this study was to investigate the influence of specific exercise loading history on fall-induced hip fracture behavior by estimating fracture load and location with proximal femur finite element (FE) models created from magnetic resonance images (MRI) of 111 women w…

02 engineering and technologyFinite element simulationWeight-Bearing0302 clinical medicinemurtumatreisiluuOrthopedics and Sports MedicineFemurOrthodonticsHip fractureluustomedicine.diagnostic_testbiologyProximal femurexerciseRehabilitationfallingfemoral neckta3142lonkkamurtumatBiomechanical Phenomenamedicine.anatomical_structureFemalevahvistaminenAdultFinite Element Analysis0206 medical engineeringBiomedical EngineeringBiophysics030209 endocrinology & metabolismbone strengthYoung Adult03 medical and health sciencesmedicineHumansFemoral neckHip Fracturesbusiness.industryAthletesMagnetic resonance imagingfinite element modelingmedicine.diseasebiology.organism_classification020601 biomedical engineeringAthletesImpact loadingAccidental FallsCortical bonebusinesshuman activitiesJournal of Biomechanics
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Loading and release of the complex [Pt(DTBTA)(DMSO)Cl]Cl·CHCl3 with the 2,2′-dithiobis(benzothiazole) ligand into mesoporous silica and studies of an…

2018

Abstract Synthetic delivery systems have great potential for overcoming problems associated with systemic toxicity that accompanies chemotherapy with the use of cisplatin and family of platinum anticancer drugs. Mesoporous silicates have been studied in context of drug delivery and drug targeting. In this paper we report the studies of loading and release of a platinum complex, [Pt(DTBTA)(DMSO)Cl]Cl∙CHCl3 (1) where DTBTA = 2,2′-dithiobis(benzothiazole), that was recently synthesized and structurally characterized. Evaluation in vitro of antitumor activity against a human breast cancer cell line (MCF-7) showed a very potent activity of complex(1). Therefore, we thought to incorporate this co…

02 engineering and technologyMesoporous silica010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesControlled release0104 chemical sciencesInorganic ChemistryAntiproliferative activityControlled releaseLoadingMCM41Platinum(II) complexchemistry.chemical_compoundTargeted drug deliveryBenzothiazolechemistrySettore CHIM/03 - Chimica Generale E InorganicaDrug deliveryMaterials ChemistryPhysical and Theoretical Chemistry0210 nano-technologyCytotoxicityMesoporous materialConjugateNuclear chemistrySettore CHIM/02 - Chimica Fisica
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Energy Efficient Optimization for Computation Offloading in Fog Computing System

2017

In this paper, we investigate the energy efficient computation offloading scheme in a multi-user fog computing system. We consider the users need to make the decision on whether to offload the tasks to the fog node nearby, based on the energy consumption and delay constraint. In particular, we utilize queuing theory to bring a thorough study on the energy consumption and execution delay of the offloading process. Two queuing models are applied respectively to model the execution processes at the mobile device (MD) and fog node. Based on the theoretical analysis, an energy efficient optimization problem is formulated with the objective to minimize the energy consumption subjects to execution…

020203 distributed computingOptimization problemComputer sciencebusiness.industryNode (networking)Distributed computing020206 networking & telecommunicationsCloud computing02 engineering and technologyEnergy consumptionDistributed algorithm0202 electrical engineering electronic engineering information engineeringComputation offloadingbusinessMobile deviceEdge computingEfficient energy useGLOBECOM 2017 - 2017 IEEE Global Communications Conference
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A Sequential Game Approach for Computation-Offloading in an UAV Network

2017

International audience; Small drones are currently emerging as versatile nascent technology that can be used in exploration and surveillance missions. However, most of the underlying applications require very often complex and time-consuming calculations. Although, the limited resources available onboard the small drones, their mobility, the computation delays and energy consumption make the operation of these applications very challenging. Nevertheless, computation-offloading solutions provide feasible resolves to mitigate the issues facing these constrained devices. In this context, we address in this paper the problem of offloading highly intensive computation tasks, performed by a fleet…

020203 distributed computingSequential gameComputer scienceDistributed computingBase stations020206 networking & telecommunicationsContext (language use)Computational modelingServers02 engineering and technologyEnergy consumptionBase stationsymbols.namesake[SPI]Engineering Sciences [physics]Nash equilibriumServer0202 electrical engineering electronic engineering information engineeringsymbolsOverhead (computing)Computation offloadingDelaysGamesDrones
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On the estimation of the fatigue cycle distribution from spectral density data

1999

This paper deals with the fatigue life prediction of components and structures subjected to random fatigue, i.e. to cyclic loading whose amplitude varies in an essentially random manner. In particular, this study concentrates on the general problem of directly relating fatigue cycle distribution to the power spectral density (PSD) by means of closed-form expressions that avoid expensive digital simulations of the stress process. At present, all the methods proposed to achieve this objective are based on the use of a single parameter of the PSD. In this work, by numerical simulations and theoretical considerations, it is shown that the statistical distribution of fatigue cycles depends on f…

0209 industrial biotechnologyStochastic processMechanical EngineeringMathematical analysisSpectral density02 engineering and technologyNarrow band020303 mechanical engineering & transports020901 industrial engineering & automationDistribution (mathematics)Amplitude0203 mechanical engineeringCalculusCyclic loadingClosed-form expressionMathematicsVibration fatigueProceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science
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FAST: a randomised phase II study of zolbetuximab (IMAB362) plus EOX versus EOX alone for first-line treatment of advanced CLDN18.2-positive gastric …

2021

Claudin 18.2 (CLDN18.2) is contained within normal gastric mucosa epithelial tight junctions; upon malignant transformation, CLDN18.2 epitopes become exposed. Zolbetuximab, a chimeric monoclonal antibody, mediates specific killing of CLDN18.2-positive cells through immune effector mechanisms.The FAST study enrolled advanced gastric/gastro-oesophageal junction and oesophageal adenocarcinoma patients (aged ≥18 years) with moderate-to-strong CLDN18.2 expression in ≥40% tumour cells. Patients received first-line epirubicin + oxaliplatin + capecitabine (EOX, arm 1, n = 84) every 3 weeks (Q3W), or zolbetuximab + EOX (loading dose, 800 mg/mIn the overall population, both PFS [hazard ratio (HR) = 0…

0301 basic medicineAdultmedicine.medical_specialtyAdolescentEsophageal NeoplasmsPopulationMedizinPhases of clinical researchAdenocarcinomaGastroenterologyLoading doseCapecitabine03 medical and health sciences0302 clinical medicineStomach NeoplasmsInternal medicineAntineoplastic Combined Chemotherapy ProtocolsmedicineClinical endpointHumanseducationCapecitabineeducation.field_of_studybusiness.industryHazard ratioAntibodies MonoclonalHematologyOxaliplatin030104 developmental biologyOncology030220 oncology & carcinogenesisClaudinsEsophagogastric Junctionbusinessmedicine.drugEpirubicinAnnals of oncology : official journal of the European Society for Medical Oncology
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