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showing 10 items of 233 documents

Improvement in the performance of low temperature H2-O2 fuel cell with chitosanephosphotungstic acid composite membranes

2016

Abstract Free-standing chitosan/phosphotungstic acid polyelectrolyte membranes, prepared by ionotropic gelation on alumina porous supports, were employed as proton conductor in low temperature H 2 –O 2 fuel cell. A drying step on glass substrate was introduced in the fabrication procedure to reduce shrinkage and consequent corrugation. Membranes were tested with electrodes prepared according to different procedures and with two different Pt loadings, namely 0.5 and 1 mg cm −2 . Both the investigated kinds of electrodes allowed to get very promising power peaks of 550 mW cm −2 in spite of the different Pt content. The polarization curves and the electrochemical impedance spectra suggest that…

Materials scienceEnergy Engineering and Power Technology02 engineering and technologyCondensed Matter Physic010402 general chemistry01 natural sciencesH2-O2 PEMFCChitosanchemistry.chemical_compoundPhosphotungstic acidPolarization (electrochemistry)ShrinkageProton conductorChitosanRenewable Energy Sustainability and the EnvironmentHeteropolyacid021001 nanoscience & nanotechnologyCondensed Matter PhysicsPolyelectrolytePt loading0104 chemical sciencesComposite membraneMembraneFuel TechnologySettore ING-IND/23 - Chimica Fisica ApplicatachemistryChemical engineeringElectrode0210 nano-technology
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A comparative study of fatigue behaviour of flax/epoxy and glass/epoxy composites

2012

Experimental investigations on flax and glass fabrics reinforced epoxy specimens, i.e. FFRE and GFRE, submitted to fatigue tests are presented in this paper. Samples having [0/90]3S and [±45]3S stacking sequences, with similar fibre volume fractions have been tested under tension–tension fatigue loading. The specific stress-number of cycles to failure (S–N) curves, show that for the [0/90]3S specimens, FFRE have lower fatigue endurance than GFRE, but the [±45]3S FFRE specimens offer better specific fatigue endurance than similar GFRE, in the studied life range (<2 × 10^6). Overall, the three-stage stiffness degradation is observed in all cases except for [0/90]3S FFRE specimens, which prese…

Materials scienceMatériaux [Sciences de l'ingénieur]A. Polymer–matrix composites (PMCs)[ SPI.MAT ] Engineering Sciences [physics]/MaterialsGlass epoxy[ SPI.MECA.STRU ] Engineering Sciences [physics]/Mechanics [physics.med-ph]/Mechanics of the structures [physics.class-ph]02 engineering and technology[SPI.MAT]Engineering Sciences [physics]/Materials0203 mechanical engineeringFLAX FIBERS[SPI.MECA.MEMA]Engineering Sciences [physics]/Mechanics [physics.med-ph]/Mechanics of materials [physics.class-ph]B. FatigueComposite materialMécanique: Mécanique des matériaux [Sciences de l'ingénieur]Mécanique: Mécanique des structures [Sciences de l'ingénieur]B. Mechanical propertiesGeneral EngineeringA. Glass fibresEpoxy021001 nanoscience & nanotechnologyStiffening020303 mechanical engineering & transportsStiffness degradationCreep[SPI.MECA.STRU]Engineering Sciences [physics]/Mechanics [physics.med-ph]/Structural mechanics [physics.class-ph]visual_art[ CHIM.MATE ] Chemical Sciences/Material chemistry[ SPI.MECA.MEMA ] Engineering Sciences [physics]/Mechanics [physics.med-ph]/Mechanics of materials [physics.class-ph]Fatigue loadingCeramics and Compositesvisual_art.visual_art_mediumFlax fibres0210 nano-technologyCREEP
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Experimental characterization of composite laminates under low-velocity multi-impact loading

2019

The use of composite materials undergoes a significant growth in many industries including aeronautic, railway, and automotive. Laminated composites are often subjected to severe loading conditions...

Materials scienceMechanical EngineeringDelamination02 engineering and technologyComposite laminates021001 nanoscience & nanotechnologyCharacterization (materials science)020303 mechanical engineering & transports0203 mechanical engineeringMechanics of MaterialsImpact loadingMaterials ChemistryCeramics and CompositesLaminated compositesComposite material0210 nano-technologyJournal of Composite Materials
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Viscoelastic properties of the Achilles tendon in vivo

2013

It has been postulated that human tendons are viscoelastic and their mechanical properties time-dependent. Although Achilles tendon (AT) mechanics are widely reported, there is no consensus about AT viscoelastic properties such as loading rate dependency or hysteresis, in vivo. AT force-elongation characteristics were determined from 14 subjects in an ankle dynamometer at different loading rates using motion capture assisted ultrasonography. AT stiffness and elongation were determined between 10 – 80% of maximum voluntary contraction (MVC) force at fast and slow loading rates. As subjects were unable to consistently match the target unloading rate in the slow condition, AT hysteresis was on…

Materials scienceMedial gastrocnemiusViscoelasticityStiffnessIn vivojäykkyysmedicineSimulationUltrasonographyAchilles tendonMultidisciplinaryResearchHysteresisStiffnessultraäänimusculoskeletal systemhystereesiTendonjänneHysteresismedicine.anatomical_structureultraäänitutkimusElongationAnklemedicine.symptomLoading rate dependencyBiomedical engineeringSpringerPlus
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Static and dynamic elasticity of some thermotropic liquid-crystalline copolyesters

1997

Two series of thermotropic liquid crystalline copolyesters were studied in static and dynamic tensile deformation. Static loading generally does not lead to any peculiar phenomena: the stress-strain diagrams are linear or convex, except one copolyester fibre, the stress-strain diagram of which is concave at high temperatures. On the contrary, in dynamic loading the elasticity modulus increased during deformation for all the samples investigated. So it can be assumed that formation of a more rigid and stable structure takes place due to the dynamic deformation.

Materials sciencePolymers and PlasticsGeneral MathematicsCondensed Matter PhysicsCopolyesterThermotropic crystalBiomaterialsSynthetic fiberMechanics of MaterialsDynamic loadingSolid mechanicsUltimate tensile strengthCeramics and CompositesComposite materialDeformation (engineering)Elastic modulusMechanics of Composite Materials
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Model of delamination propagation in brittle-matrix composites under cyclic loading

2001

A model of interlaminar fatigue crack growth based on damage accumulation ahead of the crack is proposed. Linear cumulative assumption is used for damage estimation, and a quadratic failure criterion is applied for complex interlaminar loading. Model parameters are determined from mode I and mode II fatigue tests, and used to predict mixed-mode delamination propagation rate. Comparison of theoretical prediction with mixed-mode test results for different brittle graphite FRP at several mode- and load ratios show reasonable agreement.

Materials sciencePolymers and PlasticsMechanical EngineeringDelaminationMode (statistics)laminated compositeFracture mechanics02 engineering and technologyParis' lawFibre-reinforced plastic021001 nanoscience & nanotechnologyFatigue limitdelaminationMatrix (mathematics)020303 mechanical engineering & transportsBrittleness0203 mechanical engineeringMechanics of MaterialsMaterials ChemistryCeramics and CompositesComposite material0210 nano-technologycyclic loadingJOURNAL OF REINFORCED PLASTICS AND COMPOSITES
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Analysis-oriented stress–strain model of CRFP-confined circular concrete columns with applied preload

2018

The compressive behavior of FRP-confined concrete is a current issue in the field of structural retrofitting. The available models well predict the stress–strain behavior under monotonic and cyclic loads. However, in the practical applications, columns that need an increasing of bearing capacity are often strengthened under serviceability load conditions, with a stress and strain state that could change the response of the reinforced systems with respect to the case of the unloaded state. In this paper, the compressive behavior of circular FRP-confined concrete columns with preload is analyzed with the introduction of a modified analysis-oriented model. Differently from the classical formul…

Materials scienceServiceability (structure)0211 other engineering and technologies020101 civil engineeringMonotonic function02 engineering and technology0201 civil engineeringFRP-confined concrete021105 building & constructionRetrofittingGeneral Materials ScienceBearing capacityCivil and Structural Engineeringbusiness.industryStress–strain curveStructural engineeringBuilding and ConstructionFibre-reinforced plasticStrength of materialsPreloadingSettore ICAR/09 - Tecnica Delle CostruzioniMechanics of MaterialsSolid mechanicsStrengtheningMaterials Science (all)businessConfinementFRP
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Effect of the loading rate on ultimate strength of composites. Application: Pressure vessel slow burst test

2013

International audience; The strength of unidirectional elastic fibre composites is shown to depend on the loading rate as the viscoelastic nature of the matrix results in a fall in breaking load as the rate is reduced. The simulation of the accumulation of fibre breaks leading to failure, takes into account all physical phenomena involved fibre failure, including the stochastic nature of fibre strength, stress transfer through the matrix between reinforcements, interfacial debonding and the viscoelastic nature of the matrix. The kinetics of composite failure are seen to involve the initial formation of random fibre breaks which at higher loads coalesce into clusters of broken fibres. The ra…

Materials scienceSpeed effectPressure vessels[ SPI.MAT ] Engineering Sciences [physics]/MaterialsComposite numberMicromechanicsFibre break02 engineering and technology021001 nanoscience & nanotechnologyPressure vesselViscoelasticity[SPI.MAT]Engineering Sciences [physics]/MaterialsStress (mechanics)Matrix (mathematics)Mathematics::Algebraic Geometry020303 mechanical engineering & transports0203 mechanical engineeringUltimate tensile strengthCeramics and CompositesLoading rateMicromechanicsComposite material0210 nano-technologyCivil and Structural EngineeringComposite Structures
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General stress-strain model for concrete or masonry response under uniaxial cyclic compression

2002

The paper proposes analytical forms able to represent with very good approximation the constitutive law experimentally deducible by means of uniaxial cyclic compressive tests on material having softening post-peak behaviour in compression and negligible tensile strength. The envelope, unloading and reloading curves characterizing the proposed model adequately approach structural responses corresponding to different levels of nonlinearity and ductility, requiring a not very high number of parameters to be calibrated experimentally. The reliability of the model is shown by comparing the results that it is able to provide with the ones analytically deduced from two reference models (one for co…

Materials scienceUniaxial compressionConcrete modelbusiness.industryMechanical EngineeringConstitutive equationStress–strain curveBuilding and ConstructionStructural engineeringMasonryCompression (physics)Constitutive lawSettore ICAR/09 - Tecnica Delle CostruzioniMechanics of MaterialsUltimate tensile strengthCyclic loadingbusinessDuctilityEnvelope (mathematics)SofteningMasonry modelCivil and Structural Engineering
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Evaluation of the shakedown limit load multiplier for stochastic seismic actions

2017

A new approach for the evaluation of the shakedown limit load multiplier for structures subjected to a combination of quasi-statically variable loads and seismic actions is presented. The common case of frame structures constituted by elastic perfectly plastic material is considered. The acting load history during the lifetime of the structure will be defined as a suitable combination of never ending quasi-statical loads, variable within an appropriate given domain, and stochastic seismic actions occurring for limited time interval. The proposed approach utilizes the Monte Carlo method in order to generate a suitable large number of seismic acceleration histories and the corresponding shake…

Mathematical optimizationElastic plastic frameMonte Carlo method02 engineering and technologyCondensed Matter Physic01 natural sciences0203 mechanical engineeringQuasi-statical and seismic loadingMechanics of Material0101 mathematicsDynamic shakedownMathematicsbusiness.industryCumulative distribution functionMechanical EngineeringProbabilistic approachStructural engineeringCondensed Matter PhysicsShakedown010101 applied mathematicsMonte Carlo method020303 mechanical engineering & transportsMechanics of MaterialsLimit loadMultiplier (economics)businessSettore ICAR/08 - Scienza Delle Costruzioni
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