Search results for "métal"
showing 10 items of 112 documents
Nouveaux complexes cationiques du groupe 4 comme potentielles paires frustrées de Lewis organométalliques : synthèse, réactivité, catalyse
2017
In 2006, the concept of “frustrated Lewis pairs” (called FLPs) was introduced. The main characteristic of these compounds is their ability to activate cooperatively small molecules without the use of a metal (H2, CO2, alkene alkyne…). Initially based on P/B combination, the concept has been extended to several other main group elements (N/B, P/Al, N/Al …). Recently, FLPs have been extended to the transition metal realm. These organometallic FLPs (OmFLPs) are obviously non-metal free systems but they extend significantly the scope of FLP applications. Seeking to develop such systems, a research toward new omFLP combinations (N/Ti+, N/Zr+) has been initiated in our group, based on the synthes…
Interconnecteurs métalliques de piles à combustible de type SOFC - Résistance à la corrosion et conductivité électrique à haute température
2009
The need of interconnect to connect individual cells into electrical series in a SOFC stack appears as one of the most important point in fuel cell technology. The main important criteria requires for interconnect is an excellent oxidation resistance in air and in H2/H2O. The goal of this study is to determine the influence on corrosion behaviour of a reactive element oxide coating (La2O3, Y2O3) realized by MOCVD on different metallic alloys like Crofer22APU, Haynes230 and Fe30Cr. The realisation of long ageing (7 700 and 15 400 hours) proved to be insightful. The corrosion kinetic experiments, the oxide scale characterisation and ASR measurements established that the presence of perovskite…
Functionalised Imidazoporphyrins and their application in catalysis
2017
A broad series of functionalized imidazo[4,5-b]porphyrins was synthesized by the acid-catalyzed condensation of 2,3-dioxo-5,10,15,20-tetraarylchlorins with aromatic aldehydes. Both steric and electronic features of meso-aryl substituents influence on the product yield ranging from 18% to 90%.Single-crystal X-ray diffraction analysis of the structure of zinc(II) 5,10,15,20-tetramesityl-2-(4-pyridyl)-1H-imidazo[4,5-b]porphyrinate showed that this compound forms 1D coordination chains in the solid state.The post-synthetic modifications of imidazo[4,5-b]porphyrins were investigated by performing the Suzuki-Miyaura coupling reaction, preparing water-soluble imidazoporphyrins and linear/angular b…
Fabrication and optical characterization of long-range plasmonic waveguide interconnects for Tb/s datacom links
2019
Since the 1980s, researchers have been trying to design so-called "optical" computers, in which electrical signals would be replaced by photonic signals. For this, it is necessary to look at interconnection problems between components. This thesis deals with the problem of optical interconnection between electronic components. In order to propose a solution to this problem, we will study two types of plasmonic structures, a first structure of a single solid block where the information wave is reflected on an air prism, this structure is composed of a guide of metal wave covered with a layer of photoresist and it is named "ultra-long-distance plasmonic guide" (ULR-SPP). The second structure …
L'évolution des premières métallurgies extractives du cuivre
2003
International audience; L'histoire de la métallurgie extractive débute avec le cuivre. Malgré la rareté, des témoignages archéologiques, l'étude des sites d'extraction et notamment des déchets permet depuis peu de caractériser, au moins partiellement, les premiers procédés. Ainsi, on arrive aujourd'hui à documenter ce qui fut une véritable révolution au tout début de cette métallurgie, quand, d'une activité à faible production durant le Chalcolithique et le début de l'âge du Bronze, on passe progressivement à une véritable production de masse vers le milieu et la fin de l'âge du Bronze. Les premiers procédés sont non scorifiants, ils séparent mal le stérile du métal, et conduisent à des per…
En direct de l’essai patrimonial des 42 parcelles d’INRAE à Versailles : impacts de fertilisations centenaires en profondeur du NEOLUVISOL de lœss
2020
International audience; Après l’étude d’évolutions pédologiques et géochimiques dans l’horizon de surface (van Oort et al., 2016, 2017a), ce nouveau volet du projet de valorisation du dispositif des 42 parcelles de l’Inra de Versailles présente les effets d’apports continus de matières fertilisantes à l’échelle du solum, pour une dizaine de traitements : ammoniacaux, engrais-Na et/ou K, phosphatés, CaCO$_3$, fumier et témoins. Pour chaque traitement, les profils de teneur en éléments (0-120 cm) ont été comparés avec le bilan 1929-2014 en surface (0-25 cm), afin de raisonner la pertinence d’études des impacts d’activités anthropiques, restreintes à l’horizon de surface. En l’absence de végét…
Characterization of the metal artefacts of the two craft-quarters of the roman vicus Bliesbruck (Moselle)
2014
Diese Arbeit ist ein vollständiges Studium der Metallfunde aus den zwei Handwerkervierteln von Bliesbruck (Moselle, Frankreich). Diese Funde stammen aus vierzigjahrelangen Ausgrabungen. Das Korpus besteht aus 450 Kg Metall (Eisen, Kupferlegierungen, weisse Metalle, Gold) wovon 4 200 Objekte und 22 000 Nägel. Eine Objekt- und Funktionsidentifizierung und eine typologische Nägelzahl haben es ermöglicht, die Objektverbindungen wieder zusammenzusetzen und die Daten nach verschiedenen Kriterien einander gegenüberzustellen : Metall, Lage (Viertel und Grundstück), Chronologie und Befundnummertyp. Diese Datenüberfülle und -verschiedenheit ermöglichen das Korpus nach vielartigen geographischen Maβst…
Relationships between societies and their environment in the Sahel in southwestern Niger over the past four thousand years : a geoarchaeological appr…
2013
The Sahel, a zone between the Sahara Desert and the Sudan forests, is currently experiencing major environmental changes. Since the droughts in 1970s and 1980s, and with the high population growth rate, vegetation cover has deteriorated considerably, contributing to increased runoff and soil erosion. Starting from this observation, we undertook the study of past societies in the Niamey region, to assess their impact on the environment. The lack of archaeological data meant that it was necessary to identify key indicators of occupation during the Neolithic and the Iron Age. In addition to providing new evidence to date the Neolithic site of Kirkissoy, a sedimentary study was conducted on a p…