Search results for "magnesium hydroxide"
showing 10 items of 24 documents
Initial Surface Film on Magnesium Metal. A Characterization by X-ray Photoelectron Spectroscopy (XPS) and Photocurrent Spectroscopy (PCS)
2007
Abstract A detailed investigation of the initial film grown on mechanically polished Mg electrodes has been carried out by ex situ X-ray Photoelectron Spectroscopy (XPS) and in situ Photocurrent Spectroscopy (PCS), allowing to reach a detailed picture of the passive layer structure. The XPS data show that the films formed soon after mechanical treatment and immersion in aqueous electrolyte have a bilayer structure, consisting of an ultra-thin MgO inner layer (∼2.5 nm) and a Mg(OH) 2 external layer. The thickness of the Mg(OH) 2 layer is a function of immersion time and solution temperature. After mechanical treatment and immersion in aqueous solution at room temperature, the MgO/Mg(OH) 2 la…
Influence of Operational Strategies for the Recovery of Magnesium Hydroxide from Brines at a Pilot Scale
2022
The continuous depletion of minerals caused by land mining and the increase in their demand have pushed the development of novel sustainable technological processes for mineral recovery from unconventional sources. In this context, magnesium (Mg) has gained considerable attention for its peculiar properties and high relevance of its compounds, such as magnesium hydroxide, Mg(OH)2. In the present work, the influence of several operating conditions on the Mg(OH)2 precipitation process was thoroughly investigated by adopting a novel multiple feed-plug flow reactor. The influence of (i) initial Mg2+ concentrations in the feed stream; (ii) brine and alkaline flow rates; and (iii) the product rec…
A pilot-plant for the selective recovery of magnesium and calcium from waste brines
2021
Abstract The problem of brines disposal has raised great interest towards new strategies for their valorisation through the recovery of minerals or energy. As an example, the spent brine from ion exchange resins regeneration is often discharged into rivers or lakes, thus impacting on the process sustainability. However, such brines can be effectively reconcentrated, after removal of bivalent cations, and reused for the resins regeneration. This work focuses on developing and testing a pilot plant for selective recovery of magnesium and calcium from spent brines exploiting a novel proprietary crystallization unit. This is part of a larger treatment chain for the complete regeneration of the …
Effective magnesium recovery via seawater brines mining
In the last couple of decades, a rising interest has been focused on the research of novel and unconventional sources for mining minerals, such as industrial waste brines. As an example, brines are produced by desalination plants and discharged directly, or after being treated, into receiving water bodies possibly causing environmental concerns and renouncing the possibility to recover minerals [1,2]. Within this framework, the Water Mining WU-H2020 project aims at implementing an advanced Zero Liquid Discharge (ZLD) demo systems for the extraction of minerals and valuables products from industrial waste brines through a circular approach. The ZLD demo plant consists of: (i) Nano Filtration…
A novel colorimetric experimental technique for the characterisation of metal hydroxides reactive crystallization phenomena
2021
The reactive crystallization of metal hydroxides constitutes a field of raising interest driven by the importance of metals recovery and the wide industrial applications of their hydroxides. A popular example is related to the case of magnesium hydroxide (Mg(OH)2), which is widely employed in the fields of water treatment, desulphurization of fuel gases, pharmaceutical industry, refractory field and flame retardants
CFD-PBM simulation of Mg(OH)2 precipitation from saltwork brine
2021
Recovery of magnesium hydroxide from real bitterns
Operational analysis of a novel reactive crystallizer for the production of Magnesium Hydroxide from waste brines
SELECTIVE CRYSTALLISATION OF MAGNESIUM AND CALCIUM HYDROXIDES FROM INDUSTRIAL WASTE BRINES: A PILOT STUDY
2021
In the last years, a rising interest has been focused on the valorization of waste brines from industrial processes, such as desalination plants. In most current scenarios, waste brines are disposed directly, or after being treated, into a receiving water bodies, often causing environmental concerns and, more importantly, renouncing to the possibility of using such a waste as source of valuable raw materials. In fact, these brines are typically rich in useful salts and minerals, whose recovery can increase the environmental and economical sustainability of the industrial process [1-2]. The ZERO BRINE EU-H2020 project aims at the development of technologies for the recovery of salts, mineral…
Development of a pilot plant for the recovery of magnesium hydroxide from waste brines
Waste brines from various industrial processes, mainly from saltworks, are an important source of minerals, such as magnesium, table salt and potable water.