Search results for "matériaux"
showing 10 items of 117 documents
Antiferromagnetic Interactions in Copper(II) µ-Oxalato Dinuclear Complexes: The Role of the Counterion
2018
We report the preparation, crystal structure determination, magnetic properties and DFT calculations of five oxalato-bridged dicopper(II) complexes of formula [Cu-2(bpy)(2-)(H2O)(2)(C2O4)](CF3SO3)(2) (1), [Cu-2(bpy)(2)(C2O4)](PF6)(2) (2), [Cu-2(bpy)(2)(C2O4)](ClO4)(2) (3), [Cu-2(bpy)(2)Cl-2(C2O4)]center dot H2O (4) and [Cu-2(bpy)(2)(NO2)(2)(C2O4)] (5) (bpy = 2,2'-bipyridine and C2O42-= oxalate). Compounds 1, 2, 4 and 5 crystallize in the monoclinic system and 3 crystallizes in the triclinic system. The oxalate ligands in 1-5 adopt the bis-bidentate coordination mode and the two bpy molecules act as terminal ligands. The coordination of the counterions and the surroundings of the copper(II) …
Photo-thermal control of surface plasmon mode propagation at telecom wavelengths
2016
Surface plasmon polaritons (SPPs) is the promising versatile platform proposed for guiding electromagnetic waves at nanoscale dimensions. In this context dynamic control of SPPs prop- agation is of paramount importance. Thermo-optical (TO) effect is considered as an efficient technique for performing active control of plasmonic devices. Among the thermo-optical based plasmonic devices demonstrated so far TO coefficient is dominantly provided by a dielectric material on top of the metal sustaining the SPP mode, however, the role of TO properties of the metal has been rarely investigated for plasmonic applications especially at the telecom frequency ranges. Therefore, the aim of this thesis i…
Investigation of thick sheet AHSS springback in combined bending under tension
2012
In this paper, we investigate the springback behavior of several advanced high-strength sheet steels (TRIP, Dual-Phase, ferrite-bainite) with thicknesses up to 4 mm. Samples were tested by means of the bending-under-tension (BUT) test. The BUT has been extensively applied, in the literature, to relatively thin (1 mm and thinner) sheet metals for automotive applications; the applicability of several guidelines from the literature was investigated in this work in the context of thick advanced high strength steel (AHSS) sheets and using a sample width of 12 mm. The monotonic decrease of springback as back force increased was confirmed for this category of sheet steels, and a general trend for …
FULL PAPER: Earth for social housing in Palestine: an alternative for a sustainable refurbishment of building’s envelopes
2016
The suitable climates in the cities of Jericho and Gaza boosted the emergence of new attempts to revive earthen architecture on organizational and individual levels. These attempts produced a number of earthen buildings in the last few years following the crucial need to find alternative low cost material instead of natural stone, which is used in a large scale in Palestine. Similar attempts had a certain response to the social needs and economic situation there. This paper focuses on the possibility of using earth as an alternative material to refurbish the envelopes of existing housing units including two categories; firstly, refurbishing envelopes of housing units those were partially de…
Experimental studies on the detachment of multi-walled carbon nanotubes by a mobile liquid interface
2017
International audience; Retention and detachment of colloidal particles from surfaces is often considered only in terms of spontaneous chemical dispersion when the surface is already fully submerged. Nevertheless, interfacial processes, where the particles are caught on a mobile liquid contact line by capillary effects are ubiquitous. Theoretical description of such interfacial processes exist for spherical microcolloids, while for anisotropic shapes the literature is limited. Arc-discharge synthesized multiwalled carbon nanotube (MWNT) material contains besides the very anisotropic tubes also irregular amorphous carbon particles (ACP) that both are strongly hydrophobic. As a water–air–soli…
Study of new tellurite glasses in the TeO2-ZnO-La2O3 (TZL) system for the manufacturing of mid-infrared multimaterial optical fibers and specialty op…
2023
This thesis work was carried out using tellurite glasses from the TeO2-ZnO-La2O3 (TZL) ternary diagram for optical fibers manufacturing. The choice to use this system is motivated by the ambition to improve the transmission of optical signals within oxide glasses for which absorption bands related to OH groups are present in the transparency window. A structural study is first carried out on these glasses by Raman spectroscopy in order to understand the influence of the composition on physicochemical properties (especially on optical and thermal properties) but also to estimate the ability of a vitreous matrix to reorganize when subjected to a thermal solicitation such as the preform-to-fib…
Évêques constructeurs dans la Bourgogne de l'an mil
2013
Contribution à l'inventaire des mesures de capacité en pierre : quelques exemples dans le département de Saône-et-Loire
2010
La vigne et la pierre comme matières du paysage viticole de la Côte bourguignonne.
2009
Le château du Clos de Vougeot émergeant dans une mer de vignes dorées est le paysage de référence emblématique de la Bourgogne viticole (Illus. 1). Cependant, Stendhal, visitant la Côte en 18381, ne voyait la valeur de ce paysage qu'à travers l'évocation de ses vins : " A la sortie de Dijon, je regarde de tous mes yeux cette fameuse Côte-d'Or si célèbre en Europe. Il faut se rappeler le fameux vers : Les personnes d'esprit sont-elles jamais laides ? " " Sans ses vins admirables, je trouverais que rien au monde n'est plus laid que cette fameuse Côte-d'Or. [...]. La Côte-d'Or n'est donc qu'une petite montagne bien sèche et bien laide ; mais on distingue les vignes avec leurs petits piquets et…