Search results for "medium"

Simulation of liquid penetration in paper

2006

Capillary penetration of a wetting liquid in a microtomographic image of paper board, whose linear dimension was close to the average length of wood fibers, was simulated by the lattice-Boltzmann method. In spite of the size of the system not being large with respect to the size of structural inhomogeneities in the sample, for unidirectional penetration the simulated behavior was described well by that of the Lucas-Washburn equation, while for radial penetration a radial capillary equation described the behavior. In both cases the average penetration depth of the liquid front as a function of time followed a power law over many orders of magnitude. Capillary penetration of small droplets of…

Solid-state pyrolysis of polyphenylene-metal complexes: A facile approach toward carbon nanoparticles

2007

Novel polyphenylene-metal complexes with discotic, linear, and dendritic geometries are synthesized by using a facile approach consisting of reactions between Co2(CO)8 and ethynyl functionalities in dichloromethane. Various carbon nanoparticles (CNPs), including graphitic carbon nanotubes (CNTs), graphitic carbon rods, and carbon-metal hybrid particles are obtained from the solid-state pyrolysis of these complexes. The ultimate structures of the CNPs are found to be dependant on the structure and composition of the starting compounds. Precursors containing graphenes always result in graphitic CNTs in high yield, whereas dendritic precursors give rodlike carbon materials. Alternatively, line…

Electromagnetic shielding efficiency in Ka-band: carbon foam versus epoxy/carbon nanotube composites

2012

The wide application of microwaves stimulates searching for new materials with high electrical conductivity and electromagnetic (EM) interference shielding effectiveness (SE). We conducted a comparative study of EM SE in K a -band demonstrated by ultra-light micro-structural porous carbon solids (carbon foams) of different bulk densities, 0.042 to 0.150  g/cm 3 , and conventional flexible epoxy resin filled with carbon nanotubes (CNTs) in small concentrations, 1.5 wt.%. Microwave probing of carbon foams showed that the transmission through a 2 mm-thick layer strongly decreases with decreasing the pore size up to the level of 0.6%, due to a rise of reflectance ability. At the same time, 1 mm…

Tool Failure in Sequential Cutting of two Different Materials

1985

In this paper the authors show that the premature tool breakage, characteristic of interrupted cutting, can be enhanced in sequential cutting of two materials having different mechanical and chemical properties. The results of experimental investigations carried out in turning pieces consisting of medium carbon steel and aluminium alloy show that the time to failure is significatively lower than that occurring in machining only one of the two materials; moreover the morphology of the damage depends by the cutting order. Working with the sequence steel-Al alloy welding phenomena caused by strong deoxidation due to the latter material are observed; these phenomena cause the early development …

Friction behaviour of heat isolating coatings in machining: mechanical, thermal and energy-based considerations

2003

Abstract This paper deals with possible modifications of the frictional behaviour exhibited during the cutting process resulting from the influence of the most-commonly used heat isolating coatings deposited on a WC-Co carbide substrate. For this study, three- and four-layered coatings with intermediate Al 2 O 3 ceramic layer and a monolayer TiAlN coating, which offer superior thermal protection of the carbide substrate, were examined. Orthogonal cutting tests were carried out by end-turning medium carbon steel and austenitic stainless steel workpieces. The experimental study was aimed at determining the fundamental frictional characteristics: dimensions of the tool-chip contact area, the f…

Friction and wear properties of titanium and oxidised titanium in dry sliding against hardened C45 steel

2004

Abstract The aim of the paper is to present the results of conformal pin-on-disc tribological tests concerning the hard oxidised zone created in superficial layer of a titanium specimen sliding against the hardened to a hardness of 690 HV carbon C45 steel counterspecimen. Tribological testing was carried out at room temperature and at unlubricated conditions. After tests the structures and chemical compositions of the wear debris and worn surfaces were a subject of SEM and X-ray investigations. In comparison with the baseline the technical quality titanium/C45 steel couple, the wear and lifetime performance of the oxidised titanium/steel C45couple was markedly superior. Dominant wear debris…

Electrochemical Characterization of Archaeological Tin-Opacified Lead-Alkali Glazes and Their Corrosion Processes

2005

The electrochemical response of weathered and unweathered archaeological tin-opacified glazes attached to paraffin-impregnated graphite electrodes is described. Upon comparison with the square wave voltammetric response of SnO2, PbO and PbO2, Sn- and Pb-centered reduction processes can be characterized. Reduction of Sn(IV) involves the stepwise formation of solid Sn(II) and Sn metal, successively, at potentials of −0.08 and −0.55 V vs. AgCl/Ag. Reduction of network-modifier Pb(II) in glazes occurs at −0.5 V and is accompanied by the reduction of network-forming Pb(IV) at potentials ranging from +0.65 to +0.20 V, confirming the presence of such centers in glazes. Voltammetric data suggest th…

Characterization of the Pore Structure of Monolithic Silicas

2011

Electron microscopic investigations on amorphous polycarbonate

1967

One-pot synthesis of graphene quantum dots and simultaneous nanostructured self-assembly via a novel microwave-assisted method: impact on triazine re…

2018

One-step methods for fabricating green materials endowed with diverse functions is a challenge to be overcome in terms of reducing environmental risk and cost. We report a fast and easy synthesis of multifunctional materials composed of only fluorescent dots with structural flexibility and high sorption capability. The synthesis consists of a one-pot microwave-assisted reaction for the simultaneous formation of graphene quantum dots (GQDs) from organic precursors and their spontaneous self-assembly forming porous architectures. The GQD-assemblies are robust and no signs of degradation were observed with most organic solvents. The ensuing GQDs and their porous solids were fully characterized…