Search results for "medium"
showing 10 items of 3746 documents
Electrochemical analysis of metallic heritage artefacts: voltammetry of microparticles (VMP)
2013
Abstract: This chapter discusses the application of the voltammetry of microparticles, a solid-state electrochemical technique, to the field of corrosion of archaeological metal. Identification of metals and alloys, identification, mapping and layer-by-layer analysis of corrosion products on metal surfaces using this technique are described. Applications include quantification of components of alloys and corrosion layers, and evaluation of metal conservation and the kinetics of long-term corrosion processes. Specific applications in archaeometry, conservation and restoration include authentication and dating.
A fractional order theory of poroelasticity
2019
Abstract We introduce a time memory formalism in the flux-pressure constitutive relation, ruling the fluid diffusion phenomenon occurring in several classes of porous media. The resulting flux-pressure law is adopted into the Biot’s formulation of the poroelasticity problem. The time memory formalism, useful to capture non-Darcy behavior, is modeled by the Caputo’s fractional derivative. We show that the time-evolution of both the degree of settlement and the pressure field is strongly influenced by the order of Caputo’s fractional derivative. Also a numerical experiment aiming at simulating the confined compression test poroelasticity problem of a sand sample is performed. In such a case, …
Antibacterial, physical and mechanical properties of bonding agent containing synthesized Zinc Dimethacrylate
2019
Background The aim of this study includes synthesis of zinc dimethacrylate ionomer (ZDMA) by a new method, incorporate it into resin bonding and evaluate its antibacterial, physical and mechanical properties. Material and methods Resin adhesives containing 0 to 5% wt of ZDMA was produced and the following tests were accomplished: A: Antibacterial test: 1.Direct contact test. 2.Material aging; in both of them the bacterial colony counting were performed. B: Physical test: 1.Degree of conversion (D.C). 2.Evaluating the amount of released Zinc ion release in aqueous medium. C: Mechanical test: 1.Compressive strength test. 2.Shear bond test (enamel and dentine separately). The obtained results …
Spectroscopic, radiochemical, and theoretical studies of the Ga3+-N-2-hydroxyethyl piperazine-N'-2-ethanesulfonic acid (HEPES buffer) system: evidenc…
2013
Recent reports have claimed a superior performance of HEPES buffer in comparison to alternative buffer systems for 67/68 Ga labeling in aqueous media. In this paper we report spectroscopic (1H and 71 Ga NMR), radiochemical, mass spectrometry and theoretical modeling studies on the Ga3+/HEPES system (HEPES = N-2-hydroxyethylpiperazine-N′-2-ethanesulfonic acid) performed with the aim of elucidating a potential contribution of HEPES in the 68/67 Ga radiolabeling process. Our results demonstrate that HEPES acts as a weakly but competitive chelator of Ga3+ and that this interaction depends on the relative Ga3+: HEPES concentration. A by-product formed in the labeling mixture has been identified …
Eine Kombination niedrig und hochauflösender dynamischer T1-gewichteter Sequenzen zur besseren Beurteilung der Morphologie Kontrastmittel aufnehmende…
2002
Purpose: Presentation of a new protocol for simultaneous acquisition of both low and high resolution T 1 -weighted images of breast lesions for dynamic contrast-enhanced MR mammography. Demonstration of possible diagnostic improvement with representative measurements in patients with suspected breast cancer by adding morphologic parameters from high resolution sequences to the analysis of the signal-time curve. Materials and Methods: Dynamic MR imaging was performed with a 1.5 T system (Magnetom SONATA, Siemens Medical Systems, Germany) and the manufacturer's double-breast coil. Coronal T 1 -weighted 3D FLASH sequences (spatial resolution 1.25 ×1.25 mm 2 ; slice thickness 1.7 mm) were acqui…
Onset of convective rolls in a circular porous duct with external heat transfer to a thermally stratified environment
2011
A horizontal circular duct filled with a fluid saturated porous medium is studied. The external wall is assumed to exchange heat with an external environment thermally stratified in the vertical direction. The external heat transfer is modeled through a third kind boundary condition, and a Biot number associated with the external heat transfer coefficient is defined. The linear stability of the basic state where the velocity field is zero is studied numerically. The condition of neutral stability is determined, by solving the system of elliptic governing equations for the disturbances through a Galerkin finite-element method. The neutral stability curves, together with the critical values o…
Onset of convection in a vertical porous cylinder with a permeable and conducting side boundary
2015
Abstract The onset of natural convection in a vertical porous cylinder saturated by a fluid is studied. The lateral confinement of the porous cylinder is due to an external porous medium having a permeability much smaller than that of the cylinder. Thus, the vertical side boundary of the cylinder is permeable and constrained by given pressure and temperature distributions. The lower and upper plane boundaries of the cylinder are impermeable walls. The lower wall is subject to a uniform heat flux, while the upper wall has a uniform temperature. The basic motionless state displays a uniform and vertical temperature gradient oriented downward. The linear stability analysis is carried out by us…
Viscous dissipation and thermoconvective instabilities in a horizontal porous channel heated from below
2010
Accepted version of av article from the journal: International Journal of Thermal Sciences. Published version available on Science Direct: http://dx.doi.org/10.1016/j.ijthermalsci.2009.10.010 A linear stability analysis of the basic uniform flow in a horizontal porous channel with a rectangular cross section is carried out. The thermal boundary conditions at the impermeable channel walls are: uniform incoming heat flux at the bottom wall, uniform temperature at the top wall, adiabatic lateral walls. Thermoconvective instabilities are caused by the incoming heat flux at the bottom wall and by the internal viscous heating. Linear stability against transverse or longitudinal roll disturbances …
Onset of convection in a porous rectangular channel with external heat transfer to upper and lower fluid environments
2012
Published version of an article in the journal: Transport in Porous Media. Also available from the publisher at: http://dx.doi.org/10.1007/s11242-012-0018-9 The conditions for the onset of convection in a horizontal rectangular channel filled with a fluid saturated porous medium are studied. The vertical sidewalls are assumed to be impermeable and adiabatic. The horizontal upper and lower boundary walls are considered as impermeable and subject to external heat transfer, modelled through a third-kind boundary condition on the temperature field. The external fluid environments above and below the channel, kept at different temperatures, provide the heating-from-below mechanism which may lead…
Onset of Convection in an Inclined Anisotropic Porous Layer with Internal Heat Generation
2019
The onset of convection in an inclined porous layer which is heated internally by a uniform distribution of heat sources is considered. We investigate the combined effects of inclination, anisotropy and internal heat generation on the linear instability of the basic parallel flow. When the Rayleigh number is sufficiently large, instability occurs and a convective motion is set up. It turns out that the preferred motion at convection onset depends quite strongly on the anisotropy ratio, &xi