Search results for "medium"
showing 10 items of 3746 documents
A Roof Tile from 1678 Found in Calasparra (Murcia) as an Abiding Medium of Writing
2017
Analysis of a red clay roof tile which bears an heretofore unknown inscription of the late 'procesal' script style and humanistic characters along with the date 1678, marking its exact year of manufacture. This tile was found on the roof of an old barn structure in ruins, located on 'Horno de Calasparra' Street (Murcia), before its demolition. We will also point out some of the more significant aspects of the historic profession of tile making, which has all but disappeared. Se expone a continuación una teja de barro cocido en cuyo lomo se observa incisa una inédita frase, presentando una escritura de tipo procesal tardío, con caracteres ya humanísticos, y una fecha, 1678, la cual marca el …
Classification et chronologie de bas fourneaux de réduction du fer à usage unique au sud-ouest du Niger
2016
In southwestern Niger, near Niamey, several thousand single-use bloomery furnaces have been mapped and identified. The archaeological study of approximately 30 furnaces and their slag reveals the existence of four methods for iron smelting: three types of pit furnace and one slag-tapping type. The slag pit furnaces are clearly differentiated by the form and volume of their pits. All slag-tapping furnaces drain off slag through small openings. The slag is tapped either vertically or laterally. According to radiocarbon dates, the smelting activity developed in the 2 nd century AD and intensified through to the 14 th century. It continued to evolve until the middle of the 20 th century. The lo…
Yeast cultures with UCP1 uncoupling activity as a heating device
2009
7 páginas, 5 figuras, 3 tablas -- PAGS nros. 300-306
Synchrotron Radiation-Based Micro-XANES and Micro-XRF Study of Unsuccessfully Produced Egyptian Blue from the Late Hellenistic Production Site of Kos…
2021
International audience; This paper examines the production technology of Egyptian blue, an ancient artificial pigment, through the investigation of an unsuccessfully produced pellet derived from the Hellenistic production site of Kos (Dodecanese, Greece). This heterogeneous material was investigated by a combination of laboratory and synchrotron radiation-based (SR) techniques: scanning electron microscopy coupled with energy-dispersive Xray spectrometry, micro-Raman spectroscopy, high-resolution SR micro-X-ray fluorescence spectroscopy, and SR micro-X-ray absorption near-edge structure spectroscopy (XANES), at the ID21 beamline of the European Synchrotron Radiation Facility. Principal comp…
Reaction between Cu-bearing minerals and hydrothermal fluids at 800 °C and 200 MPa: Constraints from synthetic fluid inclusions
2020
Abstract Transport and deposition of copper in the Earth's crust are mainly controlled by the solubility of Cu-bearing phases and the speciation of Cu in magmatic-hydrothermal fluids. To improve our understanding of copper mobilization by hydrothermal fluids, we conducted an experimental study on the interaction between Cu-bearing phases (metallic copper, Cu2O, CuCl) and aqueous chloride solutions (H2O ± NaCl ± HCl; with Cl concentrations of 0 to 4.3 mol kg-1). The experiments were run in rapid heat/rapid quench cold-seal pressure vessels at 800 °C, 200 MPa, and logfO2 ~ NNO+2.3. Either Cu or Au capsules were used as containers. The reaction products were sampled in situ by the entrapment o…
Electrochemical Characterization of Coinage Techniques the 17(th) Century: The maravedis Case
2017
[EN] The voltammetry of immobilized particles (VIMP) methodology was applied to the discrimination of Spanish maravedis produced in 10 different mints between 1661 and 1664 using characteristic signatures for the reduction of cuprite and tenorite in the patina of the coins and catalytic effects on the hydrogen evolution reaction (HER). The variation of the apparent tenorite/cuprite ratio with depth was fitted to potential laws differing from one mint to another for A Coruna, Burgos, Cordoba, Cuenca, Granada, Madrid, Trujillo, Segovia, Sevilla and Valladolid coins. Electrochemical data permitted to detect the changes in the composition (with lowering of the silver content) and manufacturing …
Microchemical surface analysis of historic copper-based coins by the combined use of FIB-FESEM-EDX, OM, FTIR spectroscopy and solid-state electrochem…
2019
[EN] A multi-technique strategy, including microscopy, spectroscopic and electrochemical techniques, is proposed to study thin corrosion layers that form on the surface of historic copper-based coins. An accurate characterisation of this external corrosion layer is important for selecting a suitable conservation and/or restoration treatment. For this purpose, a series of copper-based coins from different historical periods and provenances, which mainly exhibited atmospheric corrosion, was analysed. The morphology of the corrosion layer and the upper core of coins was studied in trenches done on coin surfaces with a focused ion beam gun, coupled to a field emission scanning electron microsco…
Raman spectroscopy characterization of 10-cash productions from the late Chinese emperors to the Republic
2017
[EN] The use of Raman spectroscopy for discriminating monetary emissions, a recurrent problem in much archaeological studies, is described. The method involves the record of Raman signatures of tenorite and crystalline and defective cuprite in the patina based on the idea that subtle, mint-characteristic variations in the composition and metallography of the base metal during the manufacturing process are reflected in the variation in depth of the composition and crystallinity of the corrosion patina. The technique was applied to a series of 10-cash copper coins produced around the transition between the Kuang Hsu and Hsuan Tung last Chinese emperors and the first Republic whose averaged co…
Archaeometric analysis of Roman bronze coins from the Magna Mater temple using solid-state voltammetry and electrochemical impedance spectroscopy
2017
Voltammetry of microparticles (VMP) and electrochemical impedance spectroscopy (EIS) techniques, complemented by SEM-EDX and Raman spectroscopy, were applied to a set of 15 Roman bronze coins and one Tessera from the temple of Magna Mater (Rome, Italy). The archaeological site, dated back between the second half and the end of the 4th century A.D., presented a complicated stratigraphic context. Characteristic voltammetric patterns for cuprite and tenorite for sub-microsamples of the corrosion layers of the coins deposited onto graphite electrodes in contact with 0.10 M HClO4 aqueous solution yielded a grouping of the coins into three main groups. This grouping was confirmed and refined usin…
Electrochemical discrimination of mints: The last Chinese emperors Kuang Hsü and Hsüan T'ung monetary unification.
2017
[EN] An electrochemical methodology for discriminating monetary emissions, a recurrent problem in much archaeological studies, is introduced. The method is based on the record of voltammetric signatures of cuprite and tenorite corrosion products in the patina using a minimally invasive nanosampling following the voltammetry of immobilized particles methodology. A model for the depth variation of voltammetric electrochemical parameters characterizing the composition of the corrosion patinas is presented. This model permits to rationalize electrochemical data and discriminate different monetary emissions. The application of this technique, corroborated by electrochemical impedance spectroscop…