Search results for "melting"

Craton reactivation on the Labrador Sea margins: 40Ar/39Ar age and Sr–Nd–Hf–Pb isotope constraints from alkaline and carbonatite intrusives

2007

Abstract The once-contiguous North Atlantic craton (NAC) is crosscut by the Labrador Sea that opened during the Early Cenozoic after extensive Mesozoic continental rifting and removal of cratonic mantle. This large-scale structural change within the cratonic lithosphere was followed at about 150 Ma by the cessation of ultrapotassic and potassic-to-carbonatitic magma production, which had prevailed throughout much of the NAC history. At Aillik Bay, a sequence of olivine lamproites (1374.2 ± 4.2 Ma, 2σ), aillikites/carbonatites (590–555 Ma), and nephelinites (141.6 ± 1.0 Ma, 2σ) erupted through the southern NAC edge on the present-day Labrador Sea margin. Links between these alkaline magma ty…

Crystal structure of a 1:1 salt of 4-amino­benzoic acid (vitamin B10) with pyrazinoic acid

2018

The paper reports the crystal structure of novel salt of 4-amino­benzoic acid (Vitamin B10) with pyrazinoic acid.

A classical phenotype of Anderson-Fabry disease in a female patient with intronic mutations of the GLA gene: a case report

2012

Abstract Background Fabry disease (FD) is a hereditary metabolic disorder caused by the partial or total inactivation of a lysosomal hydrolase, the enzyme α-galactosidase A (GLA). This inactivation is responsible for the storage of undegraded glycosphingolipids in the lysosomes with subsequent cellular and microvascular dysfunction. The incidence of disease is estimated at 1:40,000 in the general population, although neonatal screening initiatives have found an unexpectedly high prevalence of genetic alterations, up to 1:3,100, in newborns in Italy, and have identified a surprisingly high frequency of newborn males with genetic alterations (about 1:1,500) in Taiwan. Case presentation We des…

Melting point, molecular symmetry and aggregation of tetrachlorobenzene isomers: the role of halogen bonding

2018

Tetrachlorobenzenes represent one of the best known, but not yet fully understood, group of isomers of the structure–melting point relationship. The differences in melting temperatures of these structurally related compounds were rationalized in terms of the hierarchy and nature of formed noncovalent interactions, and the molecular aggregation that is influenced by molecular symmetry. The highest melting point is associated with the highly symmetric 1,2,4,5-tetrachlorobenzene isomer. The structures of less symmetrical 1,2,3,4-tetrachlorobenzene and 1,2,3,5-tetrachlorobenzene, determined at 270 and 90 K, show a distinct pattern of halogen bonds, characterized by the different numbers and typ…

LA PERCEZIONE DEL BARBARICUM. LIBANIO E LA REALTÀ EXTRA ANTIOCHENA

2015

This paper aims at exploring both the city of Antioch in the 4th century ad as a transit city, thus a melting-pot of cultures, and Libanius the rhetor: but they will be considered with regard to the extra- Antiochian context. Between the lines of Libanius’speeches emerges the primary function of the Empire, that is to say the defence of the polis – a perfect microcosm – against barbarian hordes, observed according to classical stereotypes. Much has already written about Libanius’ image deformation of barbaric peoples, influenced by literary tradition: nevertheless, a careful analysis of his works will show some ability to place them in the wake of Libanius’ coeval climate, especially when t…

Response to comment on Properties and inter­actions – melting point of tri­bromo­benzene isomers

2022

A supported titanium postmetallocene catalyst: Effect of selected conditions on ethylene polymerization

2011

Ethylene polymerization with a titanium complex [N,N-ethylenebis(3-methoxysalicylideneiminato)titanium dichloride] immobilized on the magnesium support with the formula MgCl2(THF)0.32(Et2AlCl)0.36 was studied. In particular, the effects of polymerization temperature, monomer pressure, and polymerization time on the activity of the catalyst and on the polyethylene properties (molecular weight and its distribution, melting point, crystallinity, and bulk density) were evaluated. The findings of investigations prove that the studied supported titanium catalyst is highly active in ethylene polymerization, and its activity increases with increasing temperature and monomer pressure. Moreover, stab…

Liquid Structure Scenario of the Archetypal Supramolecular Deep Eutectic Solvent: Heptakis(2,6-di-O-methyl)-β-cyclodextrin/levulinic Acid

2023

The concept of supramolecular solvents has been recently introduced, and the extended liquid-state window accessible for mixtures of functionalized cyclodextrins (CDs) with hydrogen bond (HB) donor species, e.g., levulinic acid, led to the debut of supramolecular deep eutectic solvents (SUPRA-DES). These solvents retain CD’s inclusion ability and complement it with enhanced solvation effectiveness due to an extended HB network. However, so far, these promising features were not rationalized in terms of a microscopic description, thus hindering a more complete capitalization. This is the first joint experimental and computational study on the archetypal SUPRA-DES: heptakis- (2,6-di-O-methyl)…