Search results for "mercury"

Mapping of the magnetic field to correct systematic effects in a neutron electric dipole moment experiment

2021

Experiments dedicated to the measurement of the electric dipole moment of the neutron require outstanding control of the magnetic-field uniformity. The neutron electric dipole moment (nEDM) experiment at the Paul Scherrer Institute uses a Hg199 co-magnetometer to precisely monitor temporal magnetic-field variations. This co-magnetometer, in the presence of field nonuniformity, is, however, responsible for the largest systematic effect of this measurement. To evaluate and correct that effect, offline measurements of the field nonuniformity were performed during mapping campaigns in 2013, 2014, and 2017. We present the results of these campaigns, and the improvement the correction of this eff…

Preconcentration and speciation analysis of mercury : 3D printed metal scavenger-based solid-phase extraction followed by analysis with inductively c…

2021

A selective method for preconcentration and determination of methylmercury (MeHg) and inorganic mercury (iHg) in natural water samples at the ng L−1 level has been developed. The method involves adsorption of Hg species into a 3D printed metal scavenger and sequential elution with acidic thiourea solutions before ICP-MS determination. Experimental parameters affecting the preconcentration of MeHg and iHg such as the sample matrix, effect of the flow rate on adsorption, eluent composition, and elution mode have been studied in detail. The obtained method detection limits, considering the preconcentration factors of 42 and 93, were found to be 0.05 ng L−1 and 0.08 ng L−1 for MeHg and iHg, res…

Influence of prenatal exposure to environmental pollutants on human cord blood levels of glutamate

2013

El pdf del artículo es la versión post-print.

Modelling of mercury emissions from large solid fuel combustion and biomonitoring in Cz-Pl border region

2016

Tightening of norms for air protection leads to a development of new and significantly more effective techniques for removing particulate matter, SOx and NOx from flue gas which originates from large solid fuel combustion. Recently, it has been found that combinations of these environmental technologies can also lead to the reduction of mercury emissions from coal power plants. Now the greatest attention is paid especially to the coal power plant in Opatovice nad Labem, close to Hradec Kralove. Its system for flue gas dedusting was replaced by a modern type of cloth fabric filter with the highest particle separation efficiency which belongs to the category of BAT. Using this technology, tog…

First combined flux chamber survey of mercury and CO2 emissions from soil diffuse degassing at Solfatara of Pozzuoli crater, Campi Flegrei (Italy): M…

2014

Abstract There have been limited studies to date targeting gaseous elemental mercury (GEM) flux from soil emission in enriched volcanic substrates and its relation with CO 2 release and tectonic structures. In order to evaluate and understand the processes of soil–air exchanges involved at Solfatara of Pozzuoli volcano, the most active zone of Campi Flegrei caldera (Italy), an intensive field measurement survey has been achieved in September 2013 by using high-time resolution techniques. Soil–air exchange fluxes of GEM and CO 2 have been measured simultaneously at 116 points, widely distributed within the crater. Quantification of gas flux has been assessed by using field accumulation chamb…

Evaluation of a lattice-Boltzmann method for mercury intrusion porosimetry simulations

2004

We have simulated intrusion of a non-wetting liquid into pores of varying shape and size. Simulations were based on the lattice-Boltzmann method and the Shan–Chen multiphase model. The liquid–solid contact angle for pores with circular cross-section was found to be equal to that for pores with square cross-section, and constant even for small pore sizes if the discretised shape of the circular cross-section was taken into account. For comparison, contact angle was also determined for a liquid column descending in a capillary tube, and the results were found to be consistent. Application of the method to mercury intrusion porosimetry is discussed.

Measurements of gaseous elemental mercury (GEM) in diffuse soil emission using the static closed-chamber method

2015

Measurements aimed to evaluate the contribution of natural and anthropogenic gaseous elemental mercury (GEM) to the atmosphere are critical for monitoring and mitigating the impact of this highly toxic air contaminant. Notwithstanding, the amounts of GEM originating from different sources are difficult to be estimated, since specific protocols dictating the most appropriate sampling and analytical techniques are lacking. This study was aimed to test a methodological approach enables to measure GEM released through diffuse degassing from the soil, a mechanism that in volcanic and geothermal areas significantly contributes to the discharge of geogenic fluids to the atmosphere. A static closed…

New evidences on mercury emissions from Earth volcanism

2010

Hyperstoichiometric interaction between silver and mercury at the nanoscale.

2012

Breaking through the stoichiometry barrier: As the diameter of silver particles is decreased below a critical size of 32?nm, the molar ratio of aqueous HgII to Ag0 drastically increases beyond the conventional Hg/Ag ratio of 0.5:1, leading to hyperstoichiometry with a maximum ratio of 1.125:1 (see figure). Therein, around 99?% of the initial silver is retained to rapidly form a solid amalgam with reduced mercury.

Inorganic Mercury Sequestration by a Poly(ethylene imine) Dendrimer in Aqueous Solution

2015

The interaction of the G-2 poly(ethylene imine) dendrimer L, derived from ammonia as initiating core, with Hg(II) and HgCl4 2− was studied in aqueous solution by means of potentiometric (pH-metric) measurements. Speciation of these complex systems showed that L is able to form a wide variety of complexes including 1:1, 2:1, 3:1 and 3:2 metal-to-ligand species, of different protonation states, as well as the anion complexes ((H7L)HgCl4) 5+ and ((H8L)HgCl4) 6+ . The stability of the metal complexes is very high, making L an excellent sequestering agent for Hg(II), over a large pH range, and a promising ligand for the preparation of functionalized activated carbons to be employed in the remedi…