Search results for "metal ions"

showing 2 items of 282 documents

Interaction of methyltin(IV) compounds with carboxylate ligands. Part 1: formation and stability of methyltin(IV)–carboxylate complexes and their rel…

2006

Quantitative data on the stability of mono-, di- and trimethyltin(IV)-carboxylate complexes (acetate, malonate, succinate, malate, oxydiacetate, diethylenetrioxydiacetate, tricarballylate, citrate, butanetetracarboxylate and mellitate) are reported at t=25°C and I → 0 mol l - 1 . Several mononuclear, mixed proton, mixed hydroxo and polynuclear species are formed in these systems. As expected, the stability trend is mono- > di- > trimethyltin(IV) and mono < di < tri < tetra < hexa for the organotin moieties and carboxylate ligands investigated, respectively. Moreover, ligands containing, in addition to carboxylic,-O-and-OH groups show a significantly higher stability with respect to analogou…

methyltin(IV) cationLigandStereochemistryMetal ions in aqueous solutionGeneral ChemistryHEXAMedicinal chemistryInorganic Chemistrymethyltin(IV)–carboxylate complexeschemistry.chemical_compoundMalonatechemistryspeciationStability constants of complexesmethyltin(IV) cationsChemical stabilitySettore CHIM/01 - Chimica AnaliticaCarboxylatemethyltin(IV)–carboxylate complexeBinding sitecarboxylate ligandmethyltin(IV) cations; carboxylate ligands; methyltin(IV)–carboxylate complexes; speciationcarboxylate ligands
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Modelling the dependence on medium, ionic strength and temperature of N-acetyl-L-cysteine acid-base properties, and its interactions with Na+, Mg2+, …

2017

N-acetyl-L-cysteine (NAC) is the acetylated precursor of L-cysteine, and it is strictly related to glutathione activity. NAC is used in medicine since more than 30 years, primarily as a mucolytic, though its properties are exploited in the treatment of many diseases, such as acute poisoning by acetaminophen (restoring protective levels of glutathione), HIV, contrast-induced nephropathy, type-2 DM (diabetes mellitus), and it also looks promising in the treatment of several psychiatric disorders [1]. This resulted in a huge number of scientific contributions published during the years on NAC (searching in some scientific databases, more than 10000 papers appear). As expected, most of them are…

speciationIonic strengthN-acetyl-L-cysteinemetal ionsSettore CHIM/01 - Chimica Analiticaacid-base propertie
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