Search results for "metalli"
showing 10 items of 993 documents
Harvinaisista maametalleista ja niiden erotusmenetelmistä
2014
Työn tarkoituksena oli selvittää soveltuvia kemiallisia tekniikoita harvinaisten maametallien erottamiseen sekä luontaisista, että ihmisperäisen teollisuuden lähteistä. Tavoitteena oli saavuttaa hyvä näkemys aiheen historiasta, kehityksestä ja nykytilasta. Harvinaiset maametallit ovat kemiallisesti samankaltainen joukko, johon sisältyvät skandium, yttrium ja lantanoidit. Työssä käydään läpi harvinaisten maametallien keskeinen kemia, käyttö, saatavuus ja maailmanmarkkinoiden asettamat haasteet. Kiinan harvinaisten maametallien tuotanto ja sen aiheuttamat vaikutukset maailmankauppapolitiikkaan ovat merkittäviä, ja työssä korostetaan tällä hetkellä vallitsevaa tilannetta harvinaisten maametall…
Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes
2014
A new fluorescent terpyridyl-diphenylacetylene hybrid fluorophore 4'-[4-{(4-methoxyphenyl)ethynyl}phenyl]-2,2':6',2''-terpyridine, L, was synthesized via Sonogashira cross-coupling of 4'-(4-bromophenyl)-2,2':6',2''-terpyridine and 4-ethynylanisole in the presence of Pd(PPh3)4/CuI as a catalyst. The solid state structure of L shows a trans arrangement of pyridine nitrogen atoms along the interannular bond in the terpyridine domain. Five transition metal complexes of L, {[FeL2](CF3SO3)2 (1), [ZnL2](ClO4)2 (2), [CdL2](ClO4)2 (3), [RuL2](PF6)2 (4), and PtMe3IL (5)}, have also been synthesized and characterized by spectroscopic methods and single crystal X-ray analysis. The X-ray crystal structu…
Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes
2015
A new fluorescent terpyridyl-diphenylacetylene hybrid fluorophore 4′-[4-{(4-methoxyphenyl)ethynyl}phenyl]-2,2′:6′,2′′-terpyridine, L, was synthesized via Sonogashira cross-coupling of 4′-(4-bromophenyl)-2,2′:6′,2′′-terpyridine and 4-ethynylanisole in the presence of Pd(PPh3)4/CuI as a catalyst. The solid state structure of L shows a trans arrangement of pyridine nitrogen atoms along the interannular bond in the terpyridine domain. Five transition metal complexes of L, {[FeL2](CF3SO3)2 (1), [ZnL2](ClO4)2 (2), [CdL2](ClO4)2 (3), [RuL2](PF6)2 (4), and PtMe3IL (5)}, have also been synthesized and characterized by spectroscopic methods and single crystal X-ray analysis. The X-ray crystal structu…
Liposomes modified by mono- and bis-phthalocyanines: A comprehensive EPR study.
2016
The impact of selected metallophthalocyanines, featuring diverse molecular structure, upon the fluidity of liposome membranes was studied using the spin label EPR technique. The “mono”-type MPc’s (M = Zn, Sn; Pc = C32H16N8 is the phthalocyanine ligand) and sandwich LnPc2 complexes (Ln = Nd, Sm, Gd) were explored. Liposomes were obtained in a sonication process, from egg yolk lecithin (EYL) in water. TEMPO and 16-DOXYL spin labels were used to monitor the peripheral and central part of the lipid double layer, respectively, which allowed to localize the phthalocyanine additive within the bilayer, as well as to perform independent measurements of changes in fluidity upon addition thereof. All …
Organismi unicellulari "spie" dell'inquinamento dell'ambiente marino.
2008
Dix ans d'archéologie forestière dans le Châtillonnais (Côte-d'Or) : enclos, habitats, parcellaires
2010
National audience; Ces recherches sur les ensembles de structures de pierre sous forêt sont mises en œuvre depuis dix ans et sont inté- grées depuis 2003 dans le P.C.R. ‘Vix et son Environnement', dirigé par C. Mordant, S. Wirth et B. Chaume. Les vestiges étudiés sont implantés dans deux milieux géographiques distincts mais contigus : le plateau calcaire recouvert par la forêt domaniale de Châtillon, et les rebords de la Digeanne et du Brevon qui entaillent ce plateau à l'est et au sud. La prospection présente ici des caractères particuliers liés au couvert forestier. Les relevés G.P.S. sont intégrés dans un S.I.G. et constituent la base de cette étude, dans un va et vient…
Stellar populations of galaxies in the ALHAMBRA survey up toz ∼ 1
2018
Aims. We aim at constraining the stellar population properties of quiescent galaxies. These properties reveal how these galaxies evolved and assembled since z similar to 1 up to the present time. Methods. Combining the ALHAMBRA multi-filter photo-spectra with the fitting code for spectral energy distribution MUFFIT (MUlti-Filter FITting), we built a complete catalogue of quiescent galaxies via the dust-corrected stellar mass vs. colour diagram. This catalogue includes stellar population properties, such as age, metallicity, extinction, stellar mass, and photometric redshift, retrieved from the analysis of composited populations based on two independent sets of simple stellar population (SSP…
Teollisuus verkottuneessa innovaatiotaloudessa : esimerkkinä Keski-Suomen konepajateollisuus
2011
Mass-Metallicity Relation from Cosmological Hydrodynamical Simulations and X-ray Observations of Galaxy Groups and Clusters
2018
Recent X-ray observations of galaxy clusters show that the distribution of intra-cluster medium (ICM) metallicity is remarkably uniform in space and time. In this paper, we analyse a large sample of simulated objects, from poor groups to rich clusters, to study the dependence of the metallicity and related quantities on the mass of the systems. The simulations are performed with an improved version of the Smoothed-Particle-Hydrodynamics \texttt{GADGET-3} code and consider various astrophysical processes including radiative cooling, metal enrichment and feedback from stars and active galactic nuclei (AGN). The scaling between the metallicity and the temperature obtained in the simulations ag…
The origin of ICM enrichment in the outskirts of present-day galaxy clusters from cosmological hydrodynamical simulations
2018
The uniformity of the intra-cluster medium (ICM) enrichment level in the outskirts of nearby galaxy clusters suggests that chemical elements were deposited and widely spread into the intergalactic medium before the cluster formation. This observational evidence is supported by numerical findings from cosmological hydrodynamical simulations, as presented in Biffi et al. (2017), including the effect of thermal feedback from active galactic nuclei. Here, we further investigate this picture, by tracing back in time the spatial origin and metallicity evolution of the gas residing at z=0 in the outskirts of simulated galaxy clusters. In these regions, we find a large distribution of iron abundanc…