Search results for "mines"

showing 10 items of 2609 documents

Interplay between spin-crossover and luminescence in a multifunctional single crystal iron( ii ) complex: towards a new generation of molecular senso…

2019

Multifunctional mononuclear iron( ) complex coordinated with six phosphorescent ligands exhibiting correlated spin-crossover transition and enhanced fluorescence.

Coordination spherePhotoluminescenceMaterials scienceSpin statesMolecular SensorsPhotoluminescentSpin transition[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistry01 natural sciencesSpin crossover[CHIM]Chemical SciencesIron complex010405 organic chemistrydigestive oral and skin physiologyGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistry0104 chemical sciencesChemistrySynergyChemical physicsHigh spin and Low spinSpin Cross-OverLight emissionLuminescenceSingle crystal
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Selective Encapsulation and Enhancement of the Emission Properties of a Luminescent Cu(I) Complex in Mesoporous Silica

2018

Copper complexChemistrypolymorphOrganic Chemistry02 engineering and technologyMesoporous silica010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesBiochemistryCatalysis0104 chemical sciencesEncapsulation (networking)Inorganic ChemistryChemical engineeringsilicaDrug DiscoveryluminescenceencapsulationPhysical and Theoretical Chemistry0210 nano-technologyLuminescenceta116copper complexHelvetica Chimica Acta
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Mutation Analysis of Core Binding Factor A1 in Patients with Cleidocranial Dysplasia

1999

SummaryCleidocranial dysplasia (CCD) is a dominantly inherited disorder characterized by patent fontanelles, wide cranial sutures, hypoplasia of clavicles, short stature, supernumerary teeth, and other skeletal anomalies. We recently demonstrated that mutations in the transcription factor CBFA1, on chromosome 6p21, are associated with CCD. We have now analyzed the CBFA1 gene in 42 unrelated patients with CCD. In 18 patients, mutations were detected in the coding region of the CBFA1 gene, including 8 frameshift, 2 nonsense, and 9 missense mutations, as well as 2 novel polymorphisms. A cluster of missense mutations at arginine 225 (R225) identifies this residue as crucial for CBFA1 function. …

Core binding factorRecombinant Fusion ProteinsDNA Mutational AnalysisGreen Fluorescent ProteinsMolecular Sequence DataMutation MissenseHuman malformation syndromeCore Binding Factor Alpha 1 SubunitBiologyTransfectionmedicine.disease_causeBone and BonesCleidocranial dysplasiaCell LineFrameshift mutationCBFA1GeneticsmedicineHumansMissense mutationGenetics(clinical)SupernumeraryFrameshift MutationGenetics (clinical)Sequence DeletionGeneticsMutationPolymorphism GeneticCleidocranial DysplasiaCore Binding FactorsArticlesmedicine.diseaseOsteochondrodysplasiaNeoplasm ProteinsRadiographyNuclear localizationLuminescent ProteinsPhenotypeMicroscopy FluorescenceMutation testingTranscription factorHaploinsufficiencyToothTranscription FactorsThe American Journal of Human Genetics
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Amphiphilic poly(hydroxyethylaspartamide) derivative-based micelles as drug delivery systems for ferulic acid

2008

Self-assembling micelles, potentially useful as drug delivery systems for ferulic acid (FA), were obtained in aqueous media from amphiphilic alpha,beta-poly(N-2-hydroxyethyl)-dl-aspartamide (PHEA) copolymers bearing at the polyamino acidic backbone both poly(ethyleneglycol) (2000 or 5000 Da) and hexadecylamine (C(16)) moieties, at a concentration of 7 x 10(- 3) and 4 x 10(- 3) g/l, respectively, with nanometre size and negative zeta potential. These micelles were able to entrap FA and to release it in a prolonged way in phosphate buffer solution at pH 7.4 and human plasma. These systems were also stable in storage conditions and have no cytotoxic effects on Caco-2, 16 HBE, HuDe and K562 cel…

Coumaric AcidsAction PotentialsPharmaceutical ScienceBuffersCoumaric acidMicelleFerulic acidMicechemistry.chemical_compoundDrug Delivery SystemsPhagocytosisamphiphilic copolymers micelles ferulic acidPolymer chemistryAmphiphileZeta potentialCopolymerAnimalsHumansTechnology PharmaceuticalOrganic chemistryMicellespolymeric micellesFluorescent DyesAmphiphilic copolymersalphabeta-poly(N-2-hydroxyethyl)-DL-aspartamidePlant ExtractsRhodaminesMacrophagesHydrogen-Ion ConcentrationchemistrySettore CHIM/09 - Farmaceutico Tecnologico ApplicativoDrug deliveryPEGylationCaco-2 CellsK562 CellsPeptidesRhodamine B baseferulic acidJournal of Drug Targeting
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Different regimes of electronic coupling and their influence on exciton recombination in vertically stacked InAs/InP quantum wires

2006

8 páginas, 8 figuras.

CouplingMaterials sciencePhotoluminescenceAcoustics and UltrasonicsCondensed matter physicsExcitonStackingPhysics::OpticsElectronCondensed Matter PhysicsCondensed Matter::Mesoscopic Systems and Quantum Hall EffectSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsWavelengthCondensed Matter::Materials ScienceStack (abstract data type)Quantum
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WS2/MoS2 Heterostructures via Thermal Treatment of MoS2 Layers Electrostatically Functionalized with W3S4 Molecular Clusters

2020

The preparation of 2D stacked layers that combine flakes of different nature, gives rise to countless number of heterostructures where new band alignments, defined at the interfaces, control the electronic properties of the system. Among the large family of 2D/2D heterostructures, the one formed by the combination of the most common semiconducting transition metal dichalcogenides WS2/MoS2, has awaken great interest due to its photovoltaic and photoelectrochemical properties. Solution as well as dry physical methods have been developed to optimize the synthesis of these heterostructures. Here a suspension of negatively charged MoS2 flakes is mixed with a methanolic solution of a cationic W3S…

CouplingMaterials sciencePhotoluminescencebusiness.industryHeterojunctionThermal treatmentHomogeneous distribution7. Clean energylaw.inventionTransition metallawCluster (physics)OptoelectronicsCalcinationbusiness
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Comparison of the sensitivity to spectral variation of voltage- and current-matched tandem devices with luminescent coupling and thickness optimizati…

2016

Using models that do not take luminescent coupling into account, voltage-matched tandem devices have previously been shown to be less sensitive to spectral variation than their current-matched counterparts. The present paper compares the spectral sensitivity of voltage-matched and current-matched tandem devices by applying a detailed balance model that takes luminescent coupling into account. Current-matched stacks where the thickness of the top cell thickness has been optimized are also considered. The main finding is that luminescent coupling reduces the difference in spectral sensitivity between voltage-matched and current-matched devices. There is still a significant difference, however…

CouplingMaterials scienceTandembusiness.industryDetailed balance02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical sciencesOpticsSpectral sensitivityOptoelectronicsSensitivity (control systems)Current (fluid)0210 nano-technologybusinessLuminescenceVoltage2016 IEEE 43rd Photovoltaic Specialists Conference (PVSC)
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WS 2 /MoS 2 Heterostructures through Thermal Treatment of MoS 2 Layers Electrostatically Functionalized with W 3 S 4 Molecular Clusters

2020

The preparation of 2D stacked layers combining flakes of different nature gives rise to countless numbers of heterostructures where new band alignments, defined at the interfaces, control the electronic properties of the system. Among the large family of 2D/2D heterostructures, the one formed by the combination of the most common semiconducting transition metal dichalcogenides, WS2 /MoS2 , has awakened great interest owing to its photovoltaic and photoelectrochemical properties. Solution as well as dry physical methods have been developed to optimize the synthesis of these heterostructures. Here, a suspension of negatively charged MoS2 flakes is mixed with a methanolic solution of a cationi…

CouplingPhotoluminescence010405 organic chemistrybusiness.industryChemistryOrganic ChemistryHeterojunctionGeneral ChemistryThermal treatmentCondensed Matter::Mesoscopic Systems and Quantum Hall Effect010402 general chemistry01 natural sciences7. Clean energyHomogeneous distributionCatalysis0104 chemical scienceslaw.inventionCondensed Matter::Materials ScienceTransition metallawCluster (physics)OptoelectronicsCalcinationbusinessChemistry – A European Journal
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Purcell-enhancement of the radiative PL decay in perylenediimides by coupling with silver nanoparticles into waveguide modes

2017

In this work, an interesting approach to enhance the coupling between excitons and plasmons is proposed by integrating highly luminescent perylenediimides (PDIs) and Ag metal nanoparticles (MNPs) in the core of a multilayer dielectric waveguide. The combination of the weak plasmonic coupling and the high scattering of MNPs gives rise to a significant improvement of the PDI photoluminescence and Purcell factor (PF) in forward-scattering geometry. Furthermore, when the PDI-MNP system is used as the core of a multilayer waveguide, a Purcell factor enhancement larger than 10 is observed, which is explained by an increase in the exciton-plasmon coupling under the light confinement in the wavegui…

CouplingWaveguide (electromagnetism)Materials sciencePhotoluminescencePhysics and Astronomy (miscellaneous)business.industryScatteringExcitonPhysics::OpticsNanoparticle02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesQuantitative Biology::Cell Behavior0104 chemical sciencesCondensed Matter::Materials ScienceOptoelectronics0210 nano-technologybusinessLuminescencePlasmonApplied Physics Letters
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Modular synthesis of tetrasubstituted imidazoles and trisubstituted oxazoles by aldimine cross-coupling.

2008

Couplingchemistry.chemical_classificationAldimineChemistryStereochemistryOrganic ChemistryImidazolesGeneral ChemistryCrystallography X-RayCatalysisUmpolungC c couplingCyclizationIminesOxazolesCarbanionChemistry (Weinheim an der Bergstrasse, Germany)
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