Search results for "mixture"

Ionic Liquids Binary Mixtures: Promising Reaction Media for Carbohydrates Conversion in 5-HMF

Anthropogenic soils: general aspects and features

2015

In recent decades man's role in soil formation has become a matter of great concern among soil scientists. Man is now considered a soil-forming factor and anthrosolization is recognised as a soil-forming process that consists of a collection of geomorphic and pedological processes resulting from human activities. These human activities include deep working, intensive fertilization, the addition of extraneous materials, irrigation with sediment-rich waters and wet cultivation. In this paper we review the influence of man as a soil forming factor stressing also some peculiar aspects linked to their classification.

Rapid continous radiochemical separations by thermochromatography in connection with a gas-jet recoil-transport system

1980

Abstract A combination of a gas-jet recoil-transport system with a thermochromatographic system has been studied as a technique for rapid, continuous radiochemical separations. Fission products were used as a model for complex mixtures of elements. A nitrogen gas-jet containing potassium chloride clusters was applied to transport nuclides produced in a reactor from the target area to the thermochromatographic column. Conversion of the reaction products carried by the gas-jet volatile species was achieved by stopping the clusters in a quartz-wool plug located in the column and kept at high temperatures and feeding a reactive gas into the column. Several reactive gases producing volatile chlo…

Melittin Modulates Keratinocyte Function through P2 Receptor-dependent ADAM Activation

2012

Melittin, the major component of the bee venom, is an amphipathic, cationic peptide with a wide spectrum of biological properties that is being considered as an anti-inflammatory and anti-cancer agent. It modulates multiple cellular functions but the underlying mechanisms are not clearly understood. Here, we report that melittin activates disintegrin-like metalloproteases (ADAMs) and that downstream events likely contribute to the biological effects evoked by the peptide. Melittin stimulated the proteolysis of ADAM10 and ADAM17 substrates in human neutrophil granulocytes, endothelial cells and murine fibroblasts. In human HaCaT keratinocytes, melittin induced shedding of the adhesion molecu…

High-Temperature Electrolysis of Kraft Lignin for Selective Vanillin Formation

2020

Lignin represents the largest renewable resource of aromatic moieties on earth and harbors a huge potential as a sustainable feedstock for the synthesis of biobased aromatic fine chemicals. Due to the complex, heterogeneous, and robust chemical structure of the biopolymer, the valorization is associated with significant challenges. Unfortunately, technical lignins, which are a large side stream of the pulp and paper industries, are mainly thermally exploited. In this study, technical Kraft lignin was selectively electrochemically depolymerized to the aroma chemical vanillin. Using electricity, toxic and/or expensive oxidizers could be replaced. The electrodegradation of Kraft lignin was per…

Chemometric investigation on structural changes in pine kraft lignin during pulping

2000

Abstract Various structural changes which take place in dissolved lignin during the laboratory-scale kraft pulping of Scots pine (Pinus sylvestris) were studied. Lignin samples were subjected to the alkaline cupric oxide oxidation and the analytical data further processed by various multivariate chemometric techniques (principal component analysis, PCA; principal component regression, PCR; and projection to latent structures, PLS). Several models applicable to the indirect measurement of common pine kraft pulp properties (i.e., total cooking yield, kappa number and ISO brightness) were produced.

Image Quality Assessment Measure Based on Natural Image Statistics in the Tetrolet Domain

2012

This paper deals with a reduced reference (RR) image quality measure based on natural image statistics modeling. For this purpose, Tetrolet transform is used since it provides a convenient way to capture local geometric structures. This transform is applied to both reference and distorted images. Then, Gaussian Scale Mixture (GSM) is proposed to model subbands in order to take account statistical dependencies between tetrolet coefficients. In order to quantify the visual degradation, a measure based on Kullback Leibler Divergence (KLD) is provided. The proposed measure was tested on the Cornell VCL A-57 dataset and compared with other measures according to FR-TV1 VQEG framework.

Fabric evolution and the related swelling behaviour of a sand/bentonite mixture upon hydro-chemo-mechanical loadings

2015

This experimental study investigates the swelling behaviour of an 80/20 sand/bentonite mixture and the associated fabric evolution under different hydro-chemo-mechanical loadings. Free and confined swelling tests are performed on specimens compacted to different dry densities and wetted with different pore fluids. Controlled suction confined swelling tests are performed to determine the suction–swelling pressure relationship for two different densities. An extensive microstructural characterisation is performed to relate the observed swelling behaviour to the evolution of the different pore networks during wetting. Based on the microstructural analysis, an expression is proposed to determi…

Kinetic and equilibrium study for cadmium and copper removal from aqueous solutions by sorption onto mixed alginate/pectin gel beads

2013

Abstract Kinetic and equilibrium studies have been carried out to evaluate Cd(II) and Cu(II) sorption from aqueous solution by calcium alginate and new synthesized hybrid calcium alginate/pectate gel beads with different alginate/pectate concentration ratios. Physical and chemical properties of the beads were characterized by different techniques (SEM, EDX, TGA). The best experimental pH conditions were selected on the basis of a study on the acid–base properties of pectin and alginate in aqueous solution and their ability to act as sequestering agents for copper(II) and cadmium(II) ions. Calcium released during the sorption process was determined in order to elucidate a possible ion exchan…

Mercury(II) removal from aqueous solution by sorption onto alginate, pectate and polygalacturonate calcium gel beads. A kinetic and speciation based …

2013

Abstract Gel beads of calcium alginate, pectate and polygalacturonate salts have been tested as sorbent materials for mercury(II) removal from aqueous solutions. Physico-chemical properties of gel beads, defined by SEM–EDX, TGA and texture and density analysis, were correlated with gel beads sorption capacity towards Hg 2+ ion. A speciation study in aqueous solution was carried out to define the strength of interaction of mercury ion with the polymers investigated and to assess the more suitable experimental conditions to achieve the best effectiveness of Hg 2+ sorption by gel beads. On the basis of the speciation study, pH values in the 3–5.5 pH range were considered appropriated for mercu…