Search results for "mof"
showing 10 items of 174 documents
Spin-Crossover Modification through Selective CO2 Sorption
2013
[EN] We present a spin-crossover Fe-II coordination polymer with no permanent channels that selectively sorbs CO2 over N-2. The one-dimensional chains display internal voids of similar to 9 angstrom diameter, each being capable to accept one molecule of CO2 at 1 bar and 273 K. X-ray diffraction provides direct structural evidence of the location of the gas molecules and reveals the formation of O=C=O(delta(-))center dot center dot center dot pi interactions. This physisorption modifies the spin transition, producing a 9 K increase in T-1/2.
Structure solution of zeolites by automated electron diffraction tomography - Impact and treatment of preferential orientation
2014
Abstract In this paper the reliability of structure solution of nano-crystalline porous compounds with preferred orientation based on automated electron diffraction tomography (ADT) is discussed. It will be shown that the limitations of the data acquisition geometry can be overcome by completing the missing diffraction data with additional diffraction information. Apart from different ways of sample preparation, data merging with either additional ADT data sets or intensities derived from X-ray powder diffraction comprise an effective way to improve the accuracy of the structure solution.
Applications of automated diffraction tomography (ADT) on nanocrystalline porous materials
2013
Abstract Many porous materials, both inorganic and hybrid organic–inorganic, can only be synthesized as nanocrystals. X-ray powder diffraction delivers one-dimensional data from the overall sample and is therefore often limited by peak overlap at low or medium resolution and by peak broadening. Thus, structure solution of materials with large unit cells and low symmetry, disorder or pseudosymmetry, or available only in polyphasic systems, turns out to be problematic or even impossible. Electron diffraction allows collecting three-dimensional structure information from nanocrystalline materials, but is traditionally biased by low completeness of the diffraction data, dynamical scattering and…
Thermofluid-dynamic assessment of the EU-DEMO divertor single-circuit cooling option
2023
Until 2019, the thermo-hydraulic development of the EU-DEMO divertor was based on the “double-circuit” concept, in which two independent cooling circuits served by two different Primary Heat Transfer Systems were used to cool the Plasma-Facing Components (PFC) and the Cassette Body (CB). During the Divertor Final Design Review Meeting, held in May 2020, the possibility to adopt a single cooling circuit to serve both components was suggested. This new cooling circuit was originally conceived with the aim of simplifying remote maintenance, with potential benefits for some aspects of safety and balance of plant design and integration. During the years from 2020 to 2022, in the fram…
CONTRIBUTIONS TO (COLEOPTERA: STAPHYLINIDAE) IN DUMBRAVA SIBIULUI FOREST, ROMANIA IN TERMS OF THE YEARS 2013-2014
2015
This research study describes the results obtained during the years 2013-2014 by capturing in the soil traps, the epigenous artropodofauna in the Dumbrava Sibiului Forest. In addition, the entomofauna structure was studied and ecological interpretations were achieved regarding aspects such as: abundance, dominance, phenology of the collected species collected making a their description from an ecological and ethological point of view. Also the Species were presented and biologically described at the capture data. The experience was run in the period 2013- 2014 (April 2, 2013 and March 21, 2014) and some of the data were taken from a study conducted from 2011-2014 by author together with the…
Indice di efficenza energetica: Valutazione delle caratteristiche prestazionali per la certificazione degli edifici attraverso esperienze applicative.
2010
Indice di efficenza energetica: Valutazione delle caratteristiche prestazionali per la certificazione degli edifici attraverso esperienze applicative.
New Microbe Killers: Self-Assembled Silver(I) Coordination Polymers Driven by a Cagelike Aminophosphine
2019
New Ag(I) coordination polymers, formulated as [Ag(µ
Fine-tuning of the confined space in microporous metal–organic frameworks for efficient mercury removal
2017
Offsetting the impact of human activities on the biogeochemical cycle of mercury has become necessary for a sustainable planet. Herein, we report the development of a water-stable and eco-friendly metal–organic framework, which has the formula {Cu4II[(S,S)-methox]2}·5H2O (1), where methox is bis[(S)-methionine]oxalyl diamide. Its features include narrow functional channels decorated with thioalkyl chains, which are able to capture HgCl2 from aqueous media in an efficient, selective, and rapid manner. The conscious design effort in terms of size, shape, and reactivity of the channels results in extremely efficient immobilization of HgCl2 guest species in a very stable conformation, similar t…
Analysis of steady state thermal-hydraulic behaviour of the DEMO Divertor cassette body cooling circuit
2017
Abstract Within the framework of the Work Package DIV 1 – “Divertor Cassette Design and Integration” of the EUROfusion action, a research campaign has been jointly carried out by ENEA and University of Palermo to investigate the thermal-hydraulic performances of the DEMO divertor cassette cooling system. A comparative evaluation study has been performed considering the two different options under consideration for the divertor cassette body coolant, namely subcooled pressurized water and helium. The research activity has been carried out following a theoretical-computational approach based on the finite volume method and adopting a qualified Computational Fluid-Dynamic (CFD) code. CFD analy…
Dupuytren contracture in diabetic hand
2011
Dupuytren's disease (DD) is a fibroproliferative disorder of unknown origin causing palmar nodules and flexion contracture of the digits. About 5% of individuals with DD are diabetic, with an increased prevalence that is proportional to the duration of the diabetes. The association with diabetes mellitus is well recorded, with a reported prevalence of between 3% and 32%. This review considers the evidence behind the association between DD and diabetes mellitus, considering the pathogenesis, clinical manifestations and therapies that can be found in the literature.