Search results for "monazite"
showing 6 items of 16 documents
Assessment of Five Monazite Reference Materials for U-Th/Pb Dating Using Laser-Ablation ICP-MS
2019
Monazite is a common accessory phosphate mineral that occurs under a wide range of pressure and temperature conditions in sedimentary, metamorphic and igneous rocks. Monazite contains high amounts of Th and U, rendering single monazite grains suitable for in-situ U-Th/Pb dating using laser ablation inductively-coupled mass spectrometry (LA-ICP-MS). Two key aspects of monazite dating that are critical for accurate age data with maximum precision are (i) optimized instrumental conditions to minimize analytical scatter and (ii) a well characterized reference material to ensure the accuracy of the obtained aged. Here, we analyzed five monazite reference materials (USGS 44069, 94-222, MAdel, Moa…
High-pressure lattice-dynamics of NdVO4
2017
High-pressure Raman-scattering measurements and ab initio calculations on NdVO4 have been carried out up to 30 GPa. Our combined experimental and theoretical study confirms that beyond 5.9 GPa NdVO4 undergoes an irreversible zircon to monazite transition. The coexistence of zircon and monazite phases is experimentally observed up to ~8 GPa (which agrees with the theoretical transition pressure), stabilizing the monazite phase as a single phase around 10 GPa. Calculations additionally predict the existence of a second high-pressure phase transition at 12.4 GPa. This reversible phase transition has been experimentally observed beyond 18.1 GPa and remains stable up to 30 GPa. The post-monazite…
Exploring the high-pressure behavior of the three known polymorphs of BiPO4: Discovery of a new polymorph
2015
We have studied the structural behavior of bismuth phosphate under compression. We performed x-ray powder diffraction measurements up to 31.5 GPa and ab initio calculations. Experiments were carried out on different polymorphs: trigonal (phase I) and monoclinic (phases II and III). Phases I and III, at low pressure (P < 0.2-0.8 GPa), transform into phase II, which has a monazite-type structure. At room temperature, this polymorph is stable up to 31.5 GPa. Calculations support these findings and predict the occurrence of an additional transition from the monoclinic monazite-type to a tetragonal scheelite-type structure (phase IV). This transition was experimentally found after the simultaneo…
High pressure phase transitions in NdVO4
2015
Raman-scattering measurements on NdVO4 suggest a pressure-induced zircon to monazite phase transition beyond 5.9 GPa. The monazite phase undergoes a second phase transition to a yet unknown phase at 18.1 GPa. Lattice-dynamics calculations well support the experimental findings and predict a possible orthorhombic structure for the post-monazite structure of NdVO4.
The Proterozoic P–T–t Evolution of the Kemp Land Coast, East Antarctica; Constraints from Si-saturated and Si-undersaturated Metapelites
2007
Integrated metamorphic and geochronological data place new constraints on the metamorphic evolution of a Neoproterozoic orogen in east Antarctica. Granulite-facies rocks from a 150 km stretch of the Kemp Land coast reflect peak conditions involving T � 870^9908 Ca t P� 7� 4^10 kbar, with pressure increasing westward towards an Archaean craton. Electron microprobe-derived (Th þ U)^Pb monazite ages from metapelitic assemblages indicate that the major mineral textures in these rocks developed during the c. 940 Ma Rayner Orogeny. Complex compositional zoning in monazite suggests high-T recrystallization over c. 25 Myr. Diversity in metapelitic reaction textures reflects silica and ferromagnesia…
Variscan evolution of the Tanneron Massif, SE France, examined through U-Pb monazite ages
2008
The Tanneron massif belongs to the southernmost segment of the Variscan belt in France and is composed of migmatitic orthogneisses and paragneisses cross-cut by a main tonalite–granite complex. Late Carboniferous detrital basins are bounded by north–south-trending ductile to brittle normal faults and delineate three distinct zones. Our new isotope dilution U–Pb monazite dating indicates a pre-Variscan history in the central part of the massif recorded by monazites from an orthogneiss yielding ages from 440 to 410 Ma, whereas monazites from a migmatitic paragneiss record a late Carboniferous high- T event at 317 ± 1 Ma. In the eastern part, a migmatization event is recorded by monazites from…