Search results for "méthane"
showing 7 items of 7 documents
A fuzzy-logic-based controller for methane production in anaerobic fixed-film reactors
2017
The main objective of this work was to develop a controller for biogas production in continuous anaerobic fixed-bed reactors, which used effluent total volatile fatty acids (VFA) concentration as control input in order to prevent process acidification at closed loop. To this aim, a fuzzy-logic-based control system was developed, tuned and validated in an anaerobic fixed-bed reactor at pilot scale that treated industrial winery wastewater. The proposed controller varied the flow rate of wastewater entering the system as a function of the gaseous outflow rate of methane and VFA concentration. Simulation results show that the proposed controller is capable to achieve great process stability ev…
Co-production of Hydrogen and Methane From the Organic Fraction of Municipal Solid Waste in a Pilot Scale Dark Fermenter and Methanogenic Biofilm Rea…
2018
The co-production of biohydrogen and methane from the organic fraction of municipal solid waste was investigated using a two-stage AD system, composed of a pilot scale dark fermenter (DF) and a continuous methanogenic biofilm reactor. From the DF process, a biohydrogen yield of 41.7 (± 2.3) ml H2/gVSadded was achieved. The liquid DF effluent (DFE) was rich in short chain volatile fatty acids, i.e., mainly acetic and butyric acid. The DFE was valorized by producing methane in the methanogenic biofilm reactor. Two methanogenic biofilm reactors were used to assess the biotic and abiotic role of the DFE on the performance of the reactors. Regardless of the different DFE feeding (i.e., biotic an…
Le méthane dans l'atmosphère de Titan. De la spectroscopie fondamentale à la planétologie
2008
Le méthane (CH4) joue sur Tian, le plus gros satellite de Saturne, un rôle similaire à celui de l'eau sur Terre. Il y est de plus à l'origine d'une chimie organique complexe. La spectroscopie étant la technique privilégiée pour mesurer le CH4 dans les atmosphères planétaires, des modèles précis de l'absorption de la lumière par cette molécule doivent être développés. Les résultats récents obtenus dans ce domaine à l'Institut Carnot de Bourgogne, en collaboration étroite avec des planétologues, permettent notamment de contribuer à l'interprétation des résultats de la mission Cassini-Huygens.
"Expanded" local mode approach and isotopic effect in polyatomic molecules
2014
In this thesis, on the base of the "expanded", local mode approach and general isotopic substitution theory we obtain sets of simple analytical relations between spectroscopic parameters (harmonic frequencies, anharmonic coefficients, ro-vibrational parameters, different kinds of Fermi and Coriolis-type interaction parameters) of the CH2D2, CH3D and CHD3 molecules. All of them are expressed as simple functions of spectroscopic parameters of the mother CH4 molecule. Test calculations with the isotopic relations show that even without including prior informations about the isotopic species, numerical results of calculations are in a good agreement both with experimental data and results of ab…
Approche Unitaire en Spectroscopie Moléculaire
1996
International audience
Simulation de spectres à haute température : une approche statistique du compromis résolution / précision
2010
International audience; Malgré les progrès continus enregistrés dans le domaine de la spectroscopie moléculaire, théorique et expérimentale, les banques de données spectroscopiques disponibles présentent des lacunes importantes, notamment pour l'interprétation des observations des environnements astrophysiques à haute température. Ce constat s'applique en particulier à la molécule de méthane présente dans les atmosphères de nombreux objets astrophysiques. La modélisation du coefficient d'absorption du méthane dans le proche infrarouge et/ou à haute température continue à défier les théoriciens du fait de la complexité intrinsèque de son spectre rovibrationnel. De fait, les analyses à haute …
Etude des effets collisionnels dans les molécules tétraédriques. Applications au méthane perturbé par l'argon
1996
This thesis is devoted to the study of relaxational and collisional line-broadening processes in the first vibrational polyads of tetrahedral molecules. In a first part, the particular internal dynamics of such molecules is discussed. The second chapter reviews the literature on phenomena induced by intermolecular interactions involving this type of molecules. More theoretical aspects are developed in the second part. The so-called tetrahedral tensorial formalism adapted to the construction of Hamiltonians and transition moments of tetrahedral molecules is described. Main features of the infrared line-shapes theories and of semi-classical line-broadening and line-shifting calculations are a…