Search results for "nanomaterial"
showing 10 items of 330 documents
Stable n-type thermoelectric multilayer thin films with high power factor from carbonaceous nanofillers
2016
Abstract High power factor n-type organic thermoelectric nanocomposites are assembled by alternately depositing double walled-nanotubes (DWNT), stabilized by polyethyleneimine (PEI), and graphene stabilized by polyvinylpyrrolidone (PVP), from water using the layer-by-layer (LbL) assembly technique. This unique combination of carbon nanomaterials exhibits an electrical conductivity of 300 S cm−1 and a relatively stable power factor of 190 μW m−1 K−2 at room temperature.
Stability of Halloysite, Imogolite, and Boron Nitride Nanotubes in Solvent Media
2018
Inorganic nanotubes are attracting the interest of many scientists and researchers, due to their excellent application potential in different fields. Among them, halloysite and imogolite, two naturally-occurring aluminosilicate mineral clays, as well as boron nitride nanotubes have gained attention for their proper shapes and features. Above all, it is important to reach highly stable dispersion in water or organic media, in order to exploit the features of this kind of nanoparticles and to expand their applications. This review is focused on the structural and morphological features, performances, and ratios of inorganic nanotubes, considering the main strategies to prepare homogeneous col…
Effect of Charge Transfer in Magnetic-Plasmonic Au@MOx (M = Mn, Fe) Heterodimers on the Kinetics of Nanocrystal Formation
2015
Heteronanoparticles represent a new class of nanomaterials exhibiting multifunctional and collective properties, which could find applications in medical imaging and therapy, catalysis, photovoltaics, and electronics. This present work demonstrates the intrinsic heteroepitaxial linkage in heterodimer nanoparticles to enable interaction of the individual components across their interface. It revealed distinct differences between Au@MnO and Au@Fe3O4 regarding the synthetic procedure and growth kinetics, as well as the properties to be altered by the variation of the electronic structure of the metal oxides. The chemically related metal oxides differ concerning their band gap; while MnO is a M…
From Wood and Hemp Biomass Wastes to Sustainable Nanocellulose Foams
2021
Abstract Transition to the circular economy requires the implementation of recycling and reuse routes for waste products. This research addresses one of the leading emerging areas, i.e., the development of sustainable materials and natural waste processing, namely wood and hemp byproducts. The cellulosic nanomaterials derived from these under-utilized waste residues and byproducts also serve as promising natural precursors for advanced applications, e.g., biomedical, pollution filtering, and thermal insulation. The wood and hemp fibrils were prepared by microfluidic processing of 0.2 – 1.0 wt% cellulose water suspensions. After freeze-drying, the resulting foam materials were characterized …
Upconversion luminescent nanoparticles in physical sensing and in monitoring physical processes in biological samples.
2015
The most frequently used strategy for sensing is based on the emission variation of a photoactive system and it can be classified as chemical or physical depending on its response to either a chemical or a physical stimulus. There are a large number of luminescent nanomaterials that respond to chemical species, but comparatively, with the exception of temperature sensing, to date there are few examples showing the capacity of photoactive nanosystems responsive to physical stimuli, such as magnetic and electric fields, high radiation energy, tension/pressure, viscosity, etc, and very few of them comprise upconversion nanoparticles (UCNPs). These nanomaterials consist of an inorganic matrix d…
Integration of solution processed materials in polymer waveguides
2015
Active solution processed nanomaterials have emerged as a very high promising candidates for photonic applications. The reason of this arises from the facts that they exhibit high quantum yield emission at room temperature and wavelength tunability, other than their processing involves easy and cheap fabrication techniques and a versatile integration on different substrates. In this way, active properties of different solution processed materials, as colloidal quantum dots, organic dyes and rare earth nanoparticles, have been exploited to demonstrate spontaneous emission or optical modulation in photonic devices. However, in spite of such an attractiveness of these nanomaterials, little has…
Whispering gallery mode resonators coated with Au nanoparticles
2019
Whispering gallery mode resonators (WGMRs) are very interesting for sensing because a resonance shift could be caused by any perturbation of the surrounding environment. Additionally such a resonator is coated with nanomaterials to tailor and enhance the sensitivity for a specific purpose. WGMR were fabricated using standard telecommunication fiber and a hydrogen flame, characterized using the scan method to obtain the quality factors and then coated with gold nanoparticles (Au NPs) using dip coating method and characterized again for comparison. Au NPs were chosen because their positive impact on microresonator sensitivity has been mentioned before and the surface can later be functionaliz…
Photocycle of Excitons in Nitrogen-Rich Carbon Nanodots: Implications for Photocatalysis and Photovoltaics
2020
Nitrogen-rich carbon nanodots have emerged as promising nanomaterials for a wide range of applications where a highly emissive and photoactive material with low toxicity and cost-effectiveness is required. One of their hallmarks is indeed a bright, tunable fluorescence of excitonic nature. Disentangling the origin of their optical absorption and fluorescence properties and uncovering relaxation channels and interactions with solvents are some of the most debated issues in the field. Uncovering these aspects is essential for targeted applications, especially in the fields of photocatalysis but also photovoltaics and optoelectronics. Here, we present dedicated transient absorption measurement…
Micro-photoluminescence of Carbon Dots Deposited on Twisted Double-Layer Graphene Grown by Chemical Vapor Deposition
2021
Carbon-based nanomaterials, such as carbon dots (CDs) and graphene (Gr), feature outstanding optical and electronic properties. Hence, their integration in optoelectronic and photonic devices is easier thanks to their low dimensionality and offers the possibility to reach high-quality performances. In this context, the combination of CDs and Gr into new nanocomposite materials CDs/Gr can further improve their optoelectronic properties and eventually create new ones, paving the way for the development of advanced carbon nanotechnology. In this work, we have thoroughly investigated the structural and emission properties of CDs deposited on single-layer and bilayer graphene lying on a SiO2/Si …
Three dimensional nanoscale analysis reveals aperiodic mesopores in a covalent organic framework and conjugated microporous polymer.
2019
The integrated analytical approach developed in this study offers a powerful methodology for the structural characterisation of complex molecular nanomaterials. Structures of a covalent organic framework based on boronate esters (COF-5) and a conjugated microporous polymer (Aza-CMP) have been investigated by a combination of several electron microscopy techniques elucidating the three-dimensional topology of the complex polycrystalline (COF) and non-crystalline (CMP) materials. Unexpected, aperiodic mesoporous channels of 20-50 nm in diameter were found to be penetrating the COF and CMP particles, which cannot be detected by X-ray diffraction techniques. The mesopores appear to be stable un…