Search results for "nanoribbons"

showing 4 items of 54 documents

Synthesis of Nonplanar Graphene Nanoribbon with Fjord Edges

2021

As a new family of semiconductors, graphene nanoribbons (GNRs), nanometer-wide strips of graphene, have appeared as promising candidates for next-generation nanoelectronics. Out-of-plane deformation of π-frames in GNRs brings further opportunities for optical and electronic property tuning. Here we demonstrate a novel fjord-edged GNR (FGNR) with a nonplanar geometry obtained by regioselective cyclodehydrogenation. Triphenanthro-fused teropyrene 1 and pentaphenanthro-fused quateropyrene 2 were synthesized as model compounds, and single-crystal X-ray analysis revealed their helically twisted conformations arising from the [5]helicene substructures. The structures and photophysical properties …

Terahertz radiationCrystallography X-RayBiochemistryCatalysislaw.inventionchemistry.chemical_compoundsymbols.namesakeColloid and Surface ChemistrylawSpectroscopy Fourier Transform InfraredPolycyclic CompoundsDensity Functional TheoryPyrenesbusiness.industryGrapheneCommunicationStereoisomerismGeneral ChemistryNanostructuresSemiconductorHelicenechemistryNanoelectronicsChemical physicssymbolsDensity functional theoryGraphitebusinessRaman spectroscopyGraphene nanoribbons
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Theoretical Simulations on Electric Properties of CNT-Me and GNR-Me Interconnects Using Effective Media Approach

2011

Abstract To overcome disadvantages of nowadays microtechnology, a further miniaturization of electronic devices, high integration level as well as increase of both operation frequencies and power density is required, including the use of adequate materials and innovative chip interconnects. Due to their unique physical properties, especially due to a ballistic (without losses) mechanism of conductivity, carbon nanotubes (CNTs) and graphene nanoribbons (GNRs) attract a permanently growing technological interest, for example, as promising candidates for nanointerconnects in a high-speed electronics.

ab initio electronic structure calculationComputer scienceGraphene nanoribbonsCarbon nanotubesNanotechnologyCarbon nanotubeCNT-Me and GNR-Me interconnectsConductivityChirality effectslaw.inventionlawConductance and resistanceMiniaturizationGeneral Earth and Planetary SciencesMicrotechnologyElectronicsGraphene nanoribbonsGeneral Environmental SciencePower densityProcedia Computer Science
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Edge-stress -induced spontaneous twisting of graphene nanoribbons

2012

We present a continuum model for spontaneous twisting of graphene nanoribbons driven by compressive edge stresses. Based on a geometrically nonlinear theory of plates, we identify scaling laws for the dependence of twist angles on ribbon width. Strikingly, we find the existence of a critical width below which a ribbon will not undergo spontaneous twisting, preferring an in-plane stretching mode instead. The model predictions are shown to be in excellent qualitative and quantitative agreement with density-functional tight-binding simulations. More generally, our model provides a unifying picture of twisting in graphene nanoribbons with different edge orientations and chemical functionalizati…

electronic structure calculationsgrafeeninanoribbons
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Modeling the mechanical behavior of carbon nanostructures

2016

Low-dimensional nanostructures are expected to have vast number of applications in the future. Particularly large amount of research has been invested in the atomthick carbon membrane called graphene, which has become popular due to its unique electronic and mechanical properties. This thesis presents studies of the mechanical and electromechanical properties of several different types of graphene nanostructures. In addition, short detours are performed in order to study the elasticity of gold nanostructures and topology effects in graphene nanoribbons. The research is performed by using several different simulation methods. In simulations the system parameters and environment can be chosen…

topologymekaniikkahiiligraphenesimulationfysikaaliset ominaisuudetkimmoisuusnanorakenteetgrafeenielasticitysimulointitopologiamechanicsgraphene nanoribbonselectromechanics
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