Search results for "near-infrared"

FPGA based digital lock-in amplifier for fNIRS systems

2018

Lock-In Amplifiers (LIA) represent a powerful technique helping to improve signals detectability when low signal to noise ratios are experienced. Continuous Wave functional Near Infrared Spectroscopy (CW-fNIRS) systems for e-health applications usually suffer of poor detection due to the presence of strong attenuations of the optical recovering path and therefore small signals are severely dipped in a high noise floor. In this work a digital LIA system, implemented on a Zynq® Field Programmable Gate Array (FPGA), has been designed and tested to verify the quality of the developed solution, when applied in fNIRS systems. Experimental results have shown the goodness of the proposed solutions.

Thermo-Chromium: A Contactless Optical Molecular Thermometer.

2017

The unparalleled excited-state potential-energy landscape of the chromium(III)-based dye [1]3+ ([Cr(ddpd)2 ]3+ ; ddpd=N,N'-dimethyl-N,N'-dipyridin-2-yl-pyridin-2,6-diamine) enables a strong dual emission in the near infrared region. The temperature dependence of this dual emission allows the use of [1]3+ as an unprecedented molecular ratiometric thermometer in the 210-373 K temperature range in organic and in aqueous media. Incorporation of [1]3+ in biocompatible nanocarriers, such as 100 nm-sized polystyrene nanoparticles and solutol micelles, provides nanodimensional thermometers operating under physiological conditions.

Global modeling of the lower three polyads of PH_{3} Preliminary results

2009

International audience; In order to model the high-resolution infrared spectrum of the phosphine molecule in the 3 mu m region, a global approach involving the lower three polyads of the molecule (Dyad, Pentad and Octad) as been applied using an effective hamiltonian in the form of irreducible tensors. This model allowed to describe all the 15 vibrational states involved and to consider explicitly all relevant ro-vibrational interactions that cannot be accounted for by conventional perturbation approaches. 2245 levels (up to J=14) observed through transitions arising from 34 cold and hot bands including all available existing data as well as new experimental data have been fitted simultaneo…

2019

The HyPlant imaging spectrometer is a high-performance airborne instrument consisting of two sensor modules. The DUAL module records hyperspectral data in the spectral range from 400–2500 nm, which is useful to derive biochemical and structural plant properties. In parallel, the FLUO module acquires data in the red and near infrared range (670–780 nm), with a distinctly higher spectral sampling interval and finer spectral resolution. The technical specifications of HyPlant FLUO allow for the retrieval of sun-induced chlorophyll fluorescence (SIF), a small signal emitted by plants, which is directly linked to their photosynthetic efficiency. The combined use of both HyPlant modules opens up …

Titan's surface albedo variations over a Titan season from near-infrared CFHT/FTS spectra

2006

International audience; We have observed Titan in a series of campaigns from 1991 to 1996 with the Fourier Transform Spectrometer on the CFH telescope. The data acquired provide a lightcurve from the geometric albedos in the 0.9–View the MathML source spectral region. The 1991–1993 data were previously analyzed in Coustenis et al. [1995. Titan's surface: composition and variability from its near-infrared albedo. Icarus 118, 87–104] with a spherical particle code by McKay et al. [1989. The thermal structure of Titan's atmosphere. Icarus 80, 23–53]. We present here three new datasets from the 1994, 1995 and 1996 observations, with additional information from the 0.94-μm methane window on Tita…

A new method for the identification of archaeological soils by their spectral signatures in the vis-NIR region

2020

Abstract This paper introduces a statistical method to identify spectral signatures of buried archaeological remains and distinguish them from spectra of the background soil in the visible to near infrared region. The proposed method is based on the Principal Component Analysis (PCA). The difference between an archaeological spectrum and non-archaeological soil spectra is quantified by a so-called R value. R values larger than 1 indicate that the spectrum represents an archaeological material. The method is successfully applied to samples from five study sites in Italy and Hungary with special conditions. The reflection spectra are taken in a time-efficient way with a field spectrometer. Th…

Burned bones forensic investigations employing near infrared spectroscopy

2017

The use of near infrared (NIR) spectroscopy was evaluated, by using chemometric tools, for the study of the environmental impact on burned bones. Spectra of internal and external parts of burned bones, together with sediment samples, were treated by Principal Component Analysis and cluster classification as exploratory techniques to select burned bone samples, less affected by environmental processes, to properly carry out forensic studies. Partial Least Square Discriminant Analysis was used to build a model to classify bone samples based on their burning conditions, providing an efficient and accurate method to discern calcined and carbonized bone. Additionally, Partial Least Square regres…

In vivo photoprotection mechanisms observed from leaf spectral absorbance changes showing VIS–NIR slow-induced conformational pigment bed changes

2019

Abstract Regulated heat dissipation under excessive light comprises a complexity of mechanisms, whereby the supramolecular light-harvesting pigment–protein complex (LHC) shifts state from light harvesting towards heat dissipation, quenching the excess of photo-induced excitation energy in a non-photochemical way. Based on whole-leaf spectroscopy measuring upward and downward spectral radiance fluxes, we studied spectrally contiguous (hyperspectral) transient time series of absorbance A(λ,t) and passively induced chlorophyll fluorescence F(λ,t) dynamics of intact leaves in the visible and near-infrared wavelengths (VIS–NIR, 400–800 nm) after sudden strong natural-like illumination exposure. …

Water Structure in Proteins in Solid State Studied by Near Infrared Spectroscopy

2017

Water adsorption in proteins is the crucial process of protein folding and structure stabilizing. Adsorption of water on proteins can be evaluated by near-infrared spectroscopy, a useful technique for observing combination frequency of a water molecule. In this work, albumin, lysozyme, and silk, were used as models for α-helix and β-pleated sheet proteins. Their NIR spectra during water adsorption process were measured by using an NIR spectrometer equipped with a transflectance accessory. Moreover, the quantitative adsorption of water was determined by gravimetric technique. The results indicate that, there are five different NIR absorptions arise from the OH combination frequencies of wate…

2017

Functional near infrared spectroscopy (fNIRS) is a promising neuroimaging method for investigating networks of cortical regions over time. We propose a directed effective connectivity method (TPDC) allowing the capture of both time and frequency evolution of the brain’s networks using fNIRS data acquired from healthy subjects performing a continuous finger-tapping task. Using this method we show the directed connectivity patterns among cortical motor regions involved in the task and their significant variations in the strength of information flow exchanges. Intra and inter-hemispheric connections during the motor task with their temporal evolution are also provided. Characterisation of the …