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The Role of Excited Oxygen Molecules in the Formation of the Secondary Ozone Layer at 87 to 97 km

2018

The secondary ozone layer is located at elevations of 87 to 97 km in the upper mesosphere – lower thermosphere. It overlaps with the ionospheric D-layer. Daytime intensive UV radiation is dissociating O2 molecules to O atoms and photoexcitating O2 molecules up to 11.07eV level. Ozone photolysis between the wavelengths of 118.7–121.6 nm produces three oxygen atoms from one ozone molecule. Collision reactions of O2(B3 Σu —) and O2(X3 Σg —, υ≥26) with O2(X3 Σg —, υ=0) produce additional oxygen atoms. The number of oxygen atoms is maintained at such a high level that a small but significant ozone concentration survives. UV radiation weakens radically during the night. The number of O atoms show…

secondary ozone zoneOzone010504 meteorology & atmospheric scienceschemistry.chemical_elementEnvironmental Science (miscellaneous)Photochemistry01 natural sciencesOxygenchemistry.chemical_compound0103 physical sciencesOzone layer010303 astronomy & astrophysicsDissociative recombination0105 earth and related environmental sciencesNature and Landscape ConservationO2+ dissociative recombinationEcologyPhotodissociationPollutionchemistryExcited statenightglowsAbsorption (chemistry)Thermospherevibrational and electronical excitation of O2photoexcitation of O2
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