Search results for "nimi"

Napoleon in Central Finland: The Fashion of Giving Children Rulers’ Names

2012

Challenges in EU External Climate Change Policy-Making in the Early Post-Lisbon Era: The UNFCCC Copenhagen Negotiations

2011

The 15th United Nations Framework Convention on Climate Change (UNFCCC) Conference of the Parties (COP) meeting held in Copenhagen from 7 to 18 December 2009, which took place one week after the entry into force of the Treaty of Lisbon on 1 December 2009, has brought about rather disappointing outcomes from the perspective of the European Union (EU), which had previously displayed substantial leadership within the UN climate regime. Contrary to the EU’s objectives for the COP15 meeting, no legally binding agreement was reached to succeed the Kyoto Protocol after 2012 and the final Copenhagen Accord contained disappointingly few ambitious targets. This chapter tries to explain how this resul…

Unveiling the Intramolecular Ionic Diels–Alder Reactions within Molecular Electron Density Theory

2021

The intramolecular ionic Diels–Alder (IIDA) reactions of two dieniminiums were studied within the Molecular Electron Density Theory (MEDT) at the ωB97XD/6-311G(d,p) computational level. Topological analysis of the electron localization function (ELF) of dieniminiums showed that their electronic structures can been seen as the sum of those of butadiene and ethaniminium. The superelectrophilic character of dieniminiums accounts for the high intramolecular global electron density transfer taking place from the diene framework to the iminium one at the transition state structures (TSs) of these IIDA reactions, which are classified as the forward electro density flux. The activation enthalpy ass…

Advanced energetics of a Multiple-Effects-Evaporation (MEE) desalination plant. Part II: Potential of the cost formation process and prospects for en…

2010

This paper represents the 2nd part of a paper in two parts. In part I a 2nd Principle analysis of a Multiple- Effects-Evaporation (MEE) process has been proposed. In this Part II perspectives for process improvement will be investigated, along two distinct research lines: the thermoeconomics-aided optimization of a new system and the increase of thermal efficiency for existing systems by a pinch-based plant retrofit. As concerns the first research line, a detailed productive structure for the plant stage (i.e. effect) examined in Part I is presented; the cost formation structure is then used to improve a simplified optimization process, revealing capable to properly reflect the interactions…

A worrisome failure of the CC2 coupled-cluster method when applied to ozone

2010

Abstract The approximate coupled-cluster singles and doubles model CC2 is widely used for calculations of excited states in large molecules. We demonstrate a surprising failure of the CC2 geometry optimization of ozone, whereby the CC2 method predicts a barrierless, exothermic, and symmetric dissociation to three oxygen atoms. This is particularly astonishing since both second-order Moller–Plesset perturbation theory and coupled-cluster singles and doubles give reasonable equilibrium structures. We find that [ [ H , T 1 ] , T 1 ] leads to an unbalanced treatment of T 1 and T 2 in the CC2 equations. Results presented here suggest that considerable caution should be exercised when applying th…

Andante filología

2010

Complexity of probabilistic versus deterministic automata

2005

Retention-pH profiles of acids and bases in hydrophilic interaction liquid chromatography

2018

Abstract The high proportion of acetonitrile used in many HILIC mobile phases significantly changes the acid-base properties of pH buffers and analytes foreseen from available data in water. In this paper, the recommended stability pH range for chromatographic columns is examined with various acetonitrile/water mixtures, resulting in a significant broadening in the operational pH window with the content of organic solvent. Additionally, the challenge of buffer selection in HILIC is also addressed. Commonly used ammonium acetate shrinks its pH buffering range in acetonitrile-rich mobile phases due to variations in the dissociation constants of the buffer constituents (acetic acid and ammoniu…

Franceses en Valencia durante el Reinado de Carlos II: Entre la Atracción y el Rechazo

2015

La inmigración francesa en el Reino de Valencia durante el siglo XVII no había sido hasta este momento abordada en profundidad, habiendo sido incluso olvidada en la conciencia colectiva y apenas estudiada por la historiografía; aunque las propias informaciones de la época llegaban a ofrecer la elevada cifra de 30.000 franceses viviendo en el Reino y unos 15.000 en la ciudad de Valencia. Para el estudio de la presencia francesa durante el reinado de Carlos II, dos fuentes fundamentales han permitido caracterizar y documentar esta inmigración: el registro de enfermos del Hospital General de Valencia, que ha proporcionado datos detallados de casi 4.000 inmigrantes franceses, y el Manifiesto de…

Synthesis of polymer materials for use as cell culture substrates

2007

International audience; Up to today, several techniques have been used to maintain cells in culture for studying many aspects of cell biology and physiology. More often, cell culture is dependent on proper anchorage of cells to the growth surface. Thus, poly-L-lysine, fibronectin or laminin are the most commonly used substrates. In this study, electrosynthesized biocompatible polymer films are proposed as an alternative to these standard substrates. The electrosynthesized polymers tested were polyethylenimine, polypropylenimme and polypyrrole. Then, the adhesion, proliferation and morphology of rat neuronal cell lines were investigated on these polymer substrates in an attempt to develop ne…