Search results for "nitrile"

Rotational State Change of Acetonitrile Vapor on MCM-41 upon Capillary Condensation with the aid of Time-Correlation Function Analysis of IR Spectros…

2000

The infrared spectra of adsorbed acetonitrile on MCM-41 (porewidth = 3.2 nm) were measured at 303 K. In the CN stretching ν2 region, two bands were observed at 2265 cm− 1 and 2254 cm− 1, assigned to hydrogen-bonded molecules on surface hydroxyls of MCM-41, and physisorbed molecules in mesopores, respectively. We designate here the 2265 cm− 1 band as the ν2α band and the 2254 cm− 1 band as the ν2β band. The bandwidth of the fundamental transition ν2fβ, was obtained by removing the overlap with hot band transitions of the same mode, ν2α band, and other modes by least-squares fitting. Before capillary condensation, the relaxation time τ obtained from the bandwidth of the ν2fβ band was smaller …

Trichomonazide Wirkstoffe, 5. Mitt. (Dichloranilino)ethentricarbonitrile

1986

Die copolymerisation des acroleins mit einigen vinylmonomeren. Polymere acroleine. 9. Mitt.

1958

Die Copolymerisation des Acroleins in wasrigem Medium wird untersucht und die copolymerisationsparameter folgender Systeme bestimmt: Acrolein/Aacrylnitril (r1 = 1,09; r2 = 0,77); Acrolein/Acrylamid (r1 = 2,0; r2 = 0,76); Acrolein/Acrylsauremethylester (r1 = 0,2; r2 = 10,0) und Acrolein/Vinylacetat (r1 = 3,3; r2 = 0,1). Ferner werden die Qund e-Werte fur Acrolein berechet und sein Verhalten bei der Copolymerisation diskutiert. The copolymerisation of acrolein in aqueous medium has been investigated and the reactivity ratios of the following systems were determined: acrolein/acrylonitrile (r1 = 1.09; r2 = 0.77 ); acrolein/acrylamide (r1 = 2.0; r2 = 0.76); acrolein/methacrylate (r1 = 0.2; r2 =…

Electrochemical synthesis of diaryl dichalcogenides in acetonitrile, with two sacrificial electrodes: diseleno and ditelluro derivatives of quinolones

1993

Photocatalytic oxidation of acetonitrile in aqueous suspension of titanium dioxide irradiated by sunlight

2004

The photocatalytic oxidation of acetonitrile (CH3CN) was carried out in aqueous suspensions of polycrystalline TiO2 P25 Degussa irradiated by sunlight. A plug flow photoreactor in a total recycle loop was used for carrying out reactivity experiments in which the concentrations of acetonitrile, of its intermediate oxidation products and of not-purgeable organic carbon (NPOC) were monitored. The influence of the presence of strong oxidant species (H2O2, S2O82−, ClO−) on the process rate was studied. The dependence of acetonitrile photo-oxidation rate on the substrate concentration and on the catalyst amount was also investigated. The photodegradation rate of substrate and NPOC followed first …

An MEDT study of the mechanism and selectivities of the [3+2] cycloaddition reaction of tomentosin with benzonitrile oxide

2019

Electrochemistry, spectroelectrochemistry and catalytic activity of biscobalt bisporphyrin dyads towards dioxygen reduction

2011

Three face-to-face biscobalt bisporphyrin dyads, including one incorporating a copper(II) ion inside the linker, were synthesized and characterized both spectroscopically and electrochemically in three non-aqueous solvents, dichloromethane, benzonitrile and pyridine. The electrocatalytic reduction of dioxygen with these derivatives on an electrode surface in 1.0 M HClO4 was also investigated and the results are compared to that obtained with "regular" Pacman biscobalt bisporphyrins under the same experimental conditions. Surprisingly, the tris-metal species ( Cu-bisCo ) catalyzes the reduction of O2 mainly via a 2e- transfer process, leading to H2O2 , while the bis-metal (bisCo) catalyst p…

Understanding the kinetic solvent effects on the 1,3-dipolar cycloaddition of benzonitrile N-oxide: a DFT study

2011

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, ISSN : 0894-3230, DOI : 10.1002/poc.1858, Issue : 7, Volume : 24, pp. 611 – 618, JUILLET 2011.

Electrosynthesis of Stable Betulin‐Derived Nitrile Oxides and their Application in Synthesis of Cytostatic Lupane‐Type Triterpenoid‐Isoxazole Conjuga…

2021

ChemInform Abstract: Light Induced C-C Coupling of 2-Chlorobenzazoles with Carbamates, Alcohols, and Ethers.

2016

A light induced, transition-metal-free C-C coupling reaction of 2-chlorobenzazoles with aliphatic carbamates, alcohols, and ethers is presented. Inexpensive reagents, namely sodium acetate, benzophenone, water, and acetonitrile, are employed in a simple reaction protocol using a cheap and widely available 25 W energy saving UV-A lamp at ambient temperature.