Search results for "non-equilibrium thermodynamics"
showing 10 items of 122 documents
The generalized Kadanoff-Baym ansatz with initial correlations
2018
Within the non-equilibrium Green's function (NEGF) formalism, the Generalized Kadanoff-Baym Ansatz (GKBA) has stood out as a computationally cheap method to investigate the dynamics of interacting quantum systems driven out of equilibrium. Current implementations of the NEGF--GKBA, however, suffer from a drawback: real-time simulations require {\em noncorrelated} states as initial states. Consequently, initial correlations must be built up through an adiabatic switching of the interaction before turning on any external field, a procedure that can be numerically highly expensive. In this work, we extend the NEGF--GKBA to allow for {\em correlated} states as initial states. Our scheme makes i…
Effect of nonequilibrium charge screening in A + B ? 0 bimolecular reactions in condensed matter
1993
The formalism of many-particle densities developed earlier by the present authors is applied to the study of the cooperative effects in the kinetics of bimolecular A +B--*0 reactions between oppositely charged particles (reactants). It is shown that unlike the Debye-Hiickel theory in statistical physics, here charge screening has essentially a nonequilibrium character. For the asymmetric mobility of reactants (DA=0, D~4:0) the joint spatial distribution of similar immobile reactants A reveals at short distances a singular character associated with their aggregation. The relevant reaction rate does not approach a steady state (as it does in the symmetric case, DA=DB), but increases infinitel…
Attenuation of the fourth sound in liquid helium II via extended thermodynamics
2004
Abstract This work continues a study begun in previous works, where a non-standard model of liquid helium II is proposed, in which a small entropy transfer is associated with the superfluid component. In this work the influence of this superfluid entropy on the propagation of the fourth sound is analyzed. From experimental data for velocities and attenuations of the first and second sound, the model provides speed and attenuation coefficient of the fourth sound in a porous medium as a function of the ratio ss/s between the superfluid entropy ss and the total entropy s. These values are determined in the two limiting cases ss/s=0 and =0.02, for various values of temperature and pressure.
Noise enhanced stability in magnetic systems
2009
In this paper noise enhanced stability in magnetic systems is studied by both an Ising-type model and a Preisach–Arrhenius model as well as a dynamic Preisach model. It is shown that in one nonequilibrium Ising system noise enhanced stability occurs and that dynamic Preisach model has the capability to predict the occurrence of noise enhanced stability in magnetic systems. On the contrary, in a Preisach–Arrhenius model of a single quadrant magnetic material, noise enhanced stability is not detected.
Model for ion transport in bipolar membranes.
1990
A simple theory for multi-ionic transport, nonequilibrium water dissociation, and space-charge effects in bipolar membranes is developed on the basis of some of the concepts used in the solid-state n-p junction. Ion transport is described in terms of the Nernst-Planck flux equation and nonequilibrium water dissociation is accounted for by the Onsager theory of the second Wien effect. The model is expected to be of interest for biological and synthetic membranes, and can explain a number of observed effects.
Effect of reactant spatial distribution in theA+B→0reaction kinetics in one dimension with Coulomb interaction
1996
The effect of nonequilibrium charge screening in the kinetics of the one-dimensional, diffusion-controlled $A+B\ensuremath{\rightarrow}0$ reaction between charged reactants in solids and liquids is studied. The incorrectness of the static, Debye-H\"uckel theory is shown. Our microscopic formalism is based on the Kirkwood superposition approximation for three-particle densities and the self-consistent treatment of the electrostatic interactions defined by the nonuniform spatial distribution of similar and dissimilar reactants treated in terms of the relevant joint correlation functions. Special attention is paid to the pattern formation due to a reaction-induced non-Poissonian fluctuation sp…
Vortex density waves and high-frequency second sound in superfluid turbulence hydrodynamics
2010
In this paper we show that a recent hydrodynamical model of superfluid turbulence describes vortex density waves and their effects on the speed of high-frequency second sound. In this frequency regime, the vortex dynamics is not purely diffusive, as for low frequencies, but exhibits ondulatory features, whose influence on the second sound is here explored.
Spectral incoherent solitons: a localized soliton behavior in the frequency domain
2008
We show both theoretically and experimentally in an optical fiber system that a noninstantaneous nonlinear environment supports the existence of spectral incoherent solitons. Contrary to conventional solitons, spectral incoherent solitons do not exhibit a confinement in the spatiotemporal domain, but exclusively in the frequency domain. The theory reveals that the causality condition inherent to the nonlinear response function is the key property underlying the existence of spectral incoherent solitons. These solitons constitute nonequilibrium stable states of the incoherent field and are shown to be robust with respect to binary collisions.
SCALING THEORY AND THE CLASSIFICATION OF PHASE TRANSITIONS
1992
The recent classification theory for phase transitions (R. Hilfer, Physica Scripta 44, 321 (1991)) and its relation with the foundations of statistical physics is reviewed. First it is outlined how Ehrenfests classification scheme can be generalized into a general thermodynamic classification theory for phase transitions. The classification theory implies scaling and multiscaling thereby eliminating the need to postulate the scaling hypothesis as a fourth law of thermodynamics. The new classification has also led to the discovery and distinction of nonequilibrium transitions within equilibrium statistical physics. Nonequilibrium phase transitions are distinguished from equilibrium transiti…
Critical behavior of active Brownian particles
2017
We study active Brownian particles as a paradigm for a genuine nonequilibrium phase transition requiring steady driving. Access to the critical point in computer simulations is obstructed by the fact that the density is conserved. We propose a method based on arguments from finite-size scaling to determine critical points and successfully test it for the two-dimensional (2D) Ising model. Using this method allows us to accurately determine the critical point of two-dimensional active Brownian particles at ${\mathrm{Pe}}_{\text{cr}}=40(2), {\ensuremath{\phi}}_{\text{cr}}=0.597(3)$. Based on this estimate, we study the corresponding critical exponents $\ensuremath{\beta}, \ensuremath{\gamma}/\…