Search results for "nucleation"
showing 10 items of 364 documents
Competition of coagulation sink and source rate: New particle formation in the Pearl River Delta of China
2010
The coagulation sink and its role in new particle formation are investigated based on data obtained during the PRIDE-PRD2004 campaign at Xinken of Pearl River Delta, China. Analysis of size distributions and mode contributions of the coagulation sink show that the observed higher load of accumulation mode particles impose a significant effect on the coagulation sink and result in higher coagulation sinks at Xinken despite of the lower total particle number compared with other areas. Hence it is concluded that the higher coagulation sink may depress the occurrence frequency of new particle formation events. The strategies targeting at controlling accumulation mode particles may have influenc…
Diamond nucleation on iridium: local variations of structure and density within the BEN layer
2009
Abstract The diamond nuclei generated by the bias enhanced nucleation (BEN) on iridium are gathered in well defined areas (“domains”). In atomic force microscopy (AFM) measurements they become manifest in a 1 nm downward step. The fine structure of the carbon layer inside and outside these domains has been studied by small spot Auger electron spectroscopy (AES), high resolution transmission electron microscopy (HRTEM), AFM and lateral force microscopy (LFM). The Auger spectra of the carbon KLL peak taken in an ultra high vacuum setup revealed diamond features inside and more graphitic features outside the domains. The comparison with the intensity of the Auger signal originating from the un…
Crystal size distribution in Jurassic Ferrar flows and sills (Victoria Land, Antarctica): evidence for processes of cooling, nucleation, and crystall…
1996
Jurassic Ferrar rocks in Victoria Land (Antarctica) occur predominantly as basaltic or andesitic flows and sills. Both show characteristic petrographical and chemical variations, which can be related to in-situ differentiation processes. Such characteristics have been investigated at one flow (“Colonnade flow”) and one sill (“Thumb Point sill”) in the Prince Albert Mountains (Central Victoria Land) based on a statistical grain size analysis and the application of the crystal size distribution theory. A third magma body (“HiTi-unit”), which in previous literature was described as a flow, does not show clear similarities to either the flow or sill. Sill and flow are in-situ differentiated wit…
Nucleation pathway and kinetics of phase-separating active Brownian particles
2016
Suspensions of purely repulsive but self-propelled Brownian particles might undergo phase separation, a phenomenon that strongly resembles the phase separation of passive particles with attractions. Here we employ computer simulations to study the nucleation kinetics and the microscopic pathway active Brownian disks take in two dimensions when quenched from the homogeneous suspension to propulsion speeds beyond the binodal. We find the same qualitative behavior for the nucleation rate as a function of density as for a passive suspension undergoing liquid-vapor separation, suggesting that the scenario of an effective free energy also extends to the kinetics of phase separation. We study the …
Demixing time and temperature influence on porosity and interconnection of PLLA scaffolds prepared via TIPS
2009
Scaffolds suitable for tissue engineering applications were prepared by Thermally Induced Phase Separation (TIPS) starting from a ternary solution PLLA/ dioxane/water. The experimental protocol consisted of three consecutive steps, a first quench from the homogeneous solution to an appropriate demixing temperature (within the binodal region), a liquid-liquid demixing stage for a given time and a final quench from the demixing temperature to a low temperature (within the spinodal region). A large variety of morphologies, in terms of average pore size and interconnection were obtained upon modifying the demixing time and temperature, owing to the interplay of nucleation and growth processes d…
CFD simulation of ZnO nanoparticle precipitation in a supercritical water synthesis reactor
2012
International audience; Continuous hydrothermal flow synthesis process has shown great advantages concerning the control of particle size and morphology through the optimization of supercritical water processing parameters. In particular, micromixing is a key issue of the process for controlling the nucleation mechanism. A Computational Fluid Dynamics (CFD) model is suggested for nanoparticle size determination using a population balance approach. Models for reaction kinetics, thermodynamics, nucleation and growth are presented. The effects of base concentration and hydrodynamics are investigated. Results show that the CFD may be valuable simulation tool for controlling the size and the sha…
Segmented Flow-Based Multistep Synthesis of Cadmium Selenide Quantum Dots with Narrow Particle Size Distribution
2015
A continuous-flow microreactor was used to synthetize II-VI semiconductor quantum dots (CdSe). In order to improve the size distribution of the nanoparticles, the synthesis was carried out in a two-step procedure. A seed solution was obtained in a separate nucleation step, followed by a controllable growth step. Quantum dots that are synthesized with the two-step method show a much narrower size distribution in comparison to those obtained in a conventional batch synthesis.
Mercaptophenol-Protected Gold Colloids as Nuclei for the Crystallization of Inorganic Minerals: Templated Crystallization on Curved Surfaces
1999
The self-assembly of monolayers of thiols on gold(111) surfaces yields substrates that are able to template in a controlled manner, the nucleation and growth of crystals of calcium carbonate from solution. In the absence of additives, various factors such as the nature of the thiol, the temperature, and the pH are now established as influencing the nature and relative amounts of the different CaCO3 phases (calcite, vaterite, and aragonite). Recently, we have been able to extend the use of thiol/gold self-assembled monolayers as templates for the growth of inorganic crystals by utilizing protected gold colloids instead of flat gold surfaces. The thiol monolayers that protect the colloids pro…
Smaller calcite lattice deformation caused by occluded organic material in coccoliths than in mollusk shell.
2015
7 pages; International audience; The growth and nucleation of biominerals are directed and affected by associated biological molecules. In this paper, we investigate the influence of occluded biomolecules on biogenic calcite from the coccolithophorid Pleurochrysis carterae and from chalk, a rock composed predominantly of fossil coccoliths. We compare the results with data on chalk from the extensively studied mussel Pinna nobilis that served as a control. Using high resolution synchrotron powder X-ray diffraction combined with in situ heating, the influence of organic compounds on the structure of the inorganic phase was probed. Two heating cycles allow us to differentiate the effects of th…
Early homogenous amorphous precursor stages of calcium carbonate and subsequent crystal growth in levitated droplets.
2008
An in situ study of the contact-free crystallization of calcium carbonate in acoustic levitated droplets is reported. The levitated droplet technique allows an in situ monitoring of the crystallization while avoiding any foreign phase boundaries that may influence the precipitation process by heterogeneous nucleation. The diffusion-controlled precipitation of CaCO3 at neutral pH starts in the initial step with the homogeneous formation of a stable, nanosized liquid-like amorphous calcium carbonate phase that undergoes in a subsequent step a solution-assisted transformation to calcite. Cryogenic scanning electron microscopy studies indicate that precipitation is not induced at the solution/a…