Search results for "octaethylporphyrin"

showing 2 items of 2 documents

CCDC 2051302: Experimental Crystal Structure Determination

2021

Related Article: Irina Osadchuk, Nele Konrad, Khai-Nghi Truong, Kari Rissanen, Eric Clot, Riina Aav, Dzmitry Kananovich, Victor Borovkov|2021|Symmetry|13|275|doi:10.3390/sym13020275

Space GroupCrystallography{mu-237812131718-octaethyl-5-[2-(237812131718-octaethylporphyrin-5-yl)ethyl]porphyrinato}-bis{N-[35-bis(trifluoromethyl)phenyl]octahydro-2H-benzimidazol-2-imine}-di-zinc(ii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Gallium(III) and Indium(III) Complexes with meso-Monophosphorylated Porphyrins: Synthesis and Structure. A First Example of Dimers Formed by the Self…

2017

International audience; The synthesis and structural characterization, both in solution by means of H-1 and P-31 NMR and UV-vis spectroscopies and in the solid state by X-ray diffraction on single crystal, of a series of gallium(III) and indium(III) meso-mono(diethoxyphosphoryl)porphyrins bearing different peripheral substituents as well as the corresponding monoesters and phosphonic acids are reported. This work describes the first example of the X-ray structure of a self-assembled dimer formed via strong binding between the oxygen atom of the phosphonate substituent and the gallium(III) cations of adjacent porphyrin molecules [Ga-O = 1.9708(13) angstrom].

coordinationchlorideDimerSubstituentchemistry.chemical_elementmalaria pigment[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistryPhotochemistry01 natural sciencessupramolecular chemistryInorganic Chemistrychemistry.chemical_compoundoctaethylporphyrinMoleculecleavagePhysical and Theoretical ChemistryGalliumsoluble diamagnetic modelmolecular-structure010405 organic chemistrycrystal-structure[ CHIM.INOR ] Chemical Sciences/Inorganic chemistryPhosphonatePorphyrin0104 chemical sciencesCrystallographychemistryoxidesSingle crystalIndium
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