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Inelastic neutron scattering study of proton dynamics in Ca(OH)2 at 20 K
1995
Abstract Inelastic neutron scattering (INS) spectra of Ca(OH) 2 at 20 K are presented from 30 to 4000 cm −1 for a powder sample, from 30 to 12000 cm −1 for an oriented single-crystal. INS band splitting due to the lattice density-of-states is observed. Polarization effects reveal the orientation of atomic displacements for each mode and a new band assignment scheme is proposed. For the single-crystal, the v OH mode and overtones are observed. This oscillator shows only moderate anharmonicity. Spectrum simulation reveals that INS spectral intensities are not consistent with simple normal coordinates and harmonic force-fields for Ca(OH) 2 entities. A new dynamical model is proposed, including…
X-ray, conformation and electronic structures of 1-nitropyrrolidine
2016
Abstract The chemistry of pyrrolidine compounds has drawn much attention because of their biological activities. The crystal and molecular structure of 1-nitropyrrolidine (C4H8NNO2) at 150K, along with calculated structures (DFT and MP2), are reported herein. In the solid-state, the asymmetric part of the unit cell is composed of one quartermolecule at the position of two perpendicular mirror planes and the five-membered ring is disordered over a mirror plane, revealing the twisted conformation. Both geometries suggest slight sp3 hybridization of the amine nitrogen atom. The non-planar geometry suggests the lack of conjugation of the amine nitrogen lone pair with the nitro group, however th…
Variable Cooperative Interactions in the Pressure and Thermally Induced Multistep Spin Transition in a Two-Dimensional Iron(II) Coordination Polymer
2020
Two types of experiments conducted to investigate the effect of pressure on the spin crossover (SCO) properties of the 2D Fe(II) coordination polymer formulated {Fe[bipy(ttr)2]}n are reported, namely, (1) magnetic measurements performed at variable temperature and at fixed pressure and (2) visible spectroscopy at variable pressure and fixed temperature. The magnetic experiments carried out under a hydrostatic pressure constraint of 0.04, 0.08, and 0.8 GPa reveal a two-step spin transition behavior. The characteristic critical temperatures of the spin transition are shifted upward in temperature as pressure increases. The slope of the straight-line of the Tc vs P plot, dTc/dP, is 775 K/GPa a…
Gravitational-wave Detection and Parameter Estimation for Accreting Black-hole Binaries and Their Electromagnetic Counterpart
2020
We study the impact of gas accretion on the orbital evolution of black-hole binaries initially at large separation in the band of the planned Laser Interferometer Space Antenna (LISA). We focus on two sources: (i)~stellar-origin black-hole binaries~(SOBHBs) that can migrate from the LISA band to the band of ground-based gravitational-wave observatories within weeks/months; and (ii) intermediate-mass black-hole binaries~(IMBHBs) in the LISA band only. Because of the large number of observable gravitational-wave cycles, the phase evolution of these systems needs to be modeled to great accuracy to avoid biasing the estimation of the source parameters. Accretion affects the gravitational-wave p…
Detection of X-ray flares from AX J1714.1-3912, the unidentified source near RX J1713.7-3946
2018
Molecular clouds are predicted to emit nonthermal X-rays when they are close to particle-accelerating supernova remnants (SNRs), and the hard X-ray source AX J1714.1-3912, near the SNR RX J1713.7-3946, has long been considered a candidate for diffuse nonthermal emission associated with cosmic rays diffusing from the remnant to a closeby molecular cloud. We aim at ascertaining the nature of this source by analyzing two dedicated X-ray observations performed with Suzaku and Chandra. We extracted images from the data in various energy bands, spectra, and light curves and studied the long-term evolution of the X-ray emission on the basis of the ~4.5 yr time separation between the two observatio…
Edge-Based Missing Data Imputation in Large-Scale Environments
2021
Smart cities leverage large amounts of data acquired in the urban environment in the context of decision support tools. These tools enable monitoring the environment to improve the quality of services offered to citizens. The increasing diffusion of personal Internet of things devices capable of sensing the physical environment allows for low-cost solutions to acquire a large amount of information within the urban environment. On the one hand, the use of mobile and intermittent sensors implies new scenarios of large-scale data analysis
Is agro-tourism eco-friendly?
2017
The paper will highlight the impact of agro-tourism on environment in Romania, focusing on the Sibiu County. Thanks to the results obtained from this analysis, research and information collection, the paper will give some answers regarding the question: are agro-tourisms environmentally friendly? The authors identify potential causes of environmental pollution from agro-tourism and some resources that could be economically used. The negative and positive aspects on the increase of agro-tourism activities in the proposed region will be also discussed taking into account there impact on the environment. Based on the obtained results, the authors will propose a method for the management of res…
Ground deformation reveals the scale-invariant conduit dynamics driving explosive basaltic eruptions
2021
The mild activity of basaltic volcanoes is punctuated by violent explosive eruptions that occur without obvious precursors. Modelling the source processes of these sudden blasts is challenging. Here, we use two decades of ground deformation (tilt) records from Stromboli volcano to shed light, with unprecedented detail, on the short-term (minute-scale) conduit processes that drive such violent volcanic eruptions. We find that explosive eruptions, with source parameters spanning seven orders of magnitude, all share a common pre-blast ground inflation trend. We explain this exponential inflation using a model in which pressure build-up is caused by the rapid expansion of volatile-rich magma ri…
The nature of ice-nucleating particles affects the radiative properties of tropical convective cloud systems
2020
Abstract. Convective cloud systems in the maritime tropics play a critical role in global climate, but accurately representing aerosol interactions within these clouds persists as a major challenge for weather and climate modelling. We quantify the effect of ice-nucleating particles (INP) on the radiative properties of a complex Tropical Atlantic deep convective cloud field using a regional model with an advanced double-moment microphysics scheme. Our results show that the domain-mean daylight outgoing radiation varies by up to 18 W m−2 depending on the bio- and physico-chemical properties of INP. The key distinction between different INPs is the temperature dependence of ice formation, whi…
Raw material, gestures, artefacts. An approach to the work of bone and ivory in the Iron Age in the Iberian peninsula
2018
Abstract This work seeks to give visibility to the industry of hard animal materials that is documented during the Iron Age in the Iberian peninsula. We focus on the analysis of three common artefacts within the bone and ivory industry in the Iberian culture (between the 6th to the 1st Century BC): pins, perforated plates and combs. We have studied these objects from a technological point of view, thanks to a series of experimental work carried out in order to meet different operational chains, necessary to manufacture each one of these items and tools that could be used for this purpose. So, we searched the archaeological tool models to work bone and ivory, and whenever it has been possibl…