Search results for "organic carbon"

Seawater carbonate chemistry and carbon sources of mussel shell carbonate

2018

Ocean acidification and warming is widely reported to affect the ability of marine bivalves to calcify, but little is known about the underlying mechanisms. In particular, the response of their calcifying fluid carbonate chemistry to changing seawater carbonate chemistry remains poorly understood. The present study deciphers sources of the dissolved inorganic carbon (DIC) in the calcifying fluid of the blue mussel (Mytilus edulis) reared at two pH (8.1 and 7.7) and temperature (16 and 22 °C) levels for five weeks. Stable carbon isotopic ratios of seawater DIC, mussel soft tissues and shells were measured to determine the relative contribution of seawater DIC and metabolically generated carb…

High-pressure NMR spectroscopy: An in situ tool to study tin-catalyzed synthesis of organic carbonates from carbon dioxide and alcohols. Part 2 [1]

2015

Dialkoxide diorganotin(IV) complexes are known to readily react with carbon dioxide under pressure and they are considered as suitable catalyst precursor models for the direct synthesis of organic carbonates. To gain a better understanding of CO2 insertion processes with Sn-OR bonds, the reactivity of n-Bu2Sn(OCH(CH3)(2))(2) (2) was investigated using high-pressure NMR (HP-NMR) spectroscopy. In deuterated solvents (isopropanol-d(8) and toluene-d(8)) under 50 bar of CO2 pressure at 80 degrees C, Sn-119{H-1} NMR experiments revealed the exclusive formation of an unprecedented tetraorganodistannoxane species, characterized as the bis[diisopropycarbonatotetrabutyldistannoxane] complex, {[n-Bu2S…

Assessment of PAHs and total content of organic matter in Landfill Leachate and Groundwater

2006

Effects of dissolved organic matter from a eutrophic lake on the freely dissolved concentrations of emerging organic contaminants

2014

The authors studied the effects of dissolved organic matter (DOM) on the bioavailability of bisphenol A (BPA) and chloramphenicol by measuring the freely dissolved concentrations of the contaminants in solutions containing DOM that had been isolated from a mesocosm in a eutrophic lake. The abundance and aromaticity of the chromophoric DOM increased over the 25-d mesocosm experiment. The BPA freely dissolved concentration was 72.3% lower and the chloramphenicol freely dissolved concentration was 56.2% lower using DOM collected on day 25 than using DOM collected on day 1 of the mesocosm experiment. The freely dissolved concentrations negatively correlated with the ultraviolent absorption coef…

Effect of catchment characteristics on aquatic carbon export from a boreal catchment and its importance in regional carbon cycling

2013

Inland waters transport and emit into the atmosphere large amounts of carbon (C), which originates from terrestrial ecosystems. The effect of land cover and land-use practises on C export from terrestrial ecosystems to inland waters is not fully understood, especially in heterogeneous landscapes under human influence. We sampled for dissolved C species in five tributaries with well-determined subcatchments (total size 174.5 km(2)), as well as in various points of two of the subcatchments draining to a boreal lake in southern Finland over a full year. Our aim was to find out how land cover and land-use affect C export from the catchments, as well as CH4 and CO2 concentrations of the streams,…

Modelling the Impacts of Climate Change on Dissolved Organic Carbon

2009

Dissolved organic carbon (DOC) from peat soils has implications both for the ecology of receiving waters and for the quality and treatment costs of water used for human consumption. Fluxes of DOC from peat soils are also relevant in the context of the global carbon cycle. Chapter 12 in this volume has reviewed the evidence for the effects of different environmental factors on the decomposition of peat soils and the export of DOC, drawing on literature and long-term data acquired from a number of European sites. The conclusion from this and many other studies is that, although there may be other influences such as land management and recovery from acid deposition, climate factors are a major…

Heterogeneity of carbon loss and its temperature sensitivity in East-European subarctic tundra soils

2016

Arctic peatlands store large stocks of organic carbon which are vulnerable to the climate change but their fate is uncertain. There is increasing evidence that a part of it will be lost as a result of faster microbial mineralization. We studied the vulnerability of 3500-5900 years old bare peat uplifted from permafrost layers by cryogenic processes to the surface of an arctic peat plateau. We aimed to find biotic and abiotic drivers of CLOSS from old peat and compare them with those of adjacent, young vegetated soils of the peat plateau and mineral tundra. The soils were incubated in laboratory at three temperatures (4°C, 12°C and 20°C) and two oxygen levels (aerobic, anaerobic). CLOSS was …

Removal of total organic carbon from peat solution by hybrid method—Electrocoagulation combined with adsorption

2018

Abstract Humic substances end up in water from the drainage basin causing eutrophication and the spread of algae. These natural organic substances have an influence on the physical, chemical and biological properties of the water system. Adsorption and electrocoagulation (EC) are commonly used purification methods in the water and wastewater treatment. Both methods are used by themselves for removing a wide range of impurities. In this research, the novelty was to study the effect of combined activated carbon (AC) adsorption and electrocoagulation method on the removal of organic substances as total organic carbon (TOC) from the peat solution. With the hybrid method, TOC content was efficie…

Multiple-stressor effects on river biofilms under different hydrological conditions

2016

Summary We studied the relative importance of environmental factors (river flow, nutrients, dissolved organic matter) and organic micro-pollutants [herbicides, insecticides, industrial organic compounds, personal care products, antibiotics and pharmaceuticals, (PhCs)] to the structure and function of epilithic biofilms under various hydrological conditions and land uses. Biofilms from four river basins in the Iberian Peninsula (Llobregat, Ebro, Jucar and Guadalquivir) were analysed in summer–autumn during a wet period and base-flow conditions. The sites experienced different levels of pollution. We used variance partitioning (Redundancy Detrended Analysis, RDA) to link environmental stresso…

Effect of air pressure on the electro-Fenton process at carbon felt electrodes

2018

Abstract The effect of air pressure on electro-Fenton (PrEF process) was evaluated using two organic substances (maleic acid and Acid Orange 7) as model organic pollutants. First experiments were performed using a conventional carbon felt (CF) cathode. At room pressure, a slow removal of maleic acid was obtained, together with the generation of formic acid. Conversely, using pressurized air, the removal of maleic acid was dramatically accelerated and the formation of formic acid was not detected. The utilization of a carbon felt modified by the deposition of carbon black + PTFE mixture (MCF) and of pressurized air allowed to achieve even faster and almost total (>95%) removal of total organ…