Search results for "ozone"

Altitude effect in UV radiation during the Evaluation of the Effects of Elevation and Aerosols on the Ultraviolet Radiation 2002 (VELETA-2002) field …

2008

[1] The Evaluation of the Effects of Elevation and Aerosols on the Ultraviolet Radiation 2002 (VELETA-2002) field campaign was designed to study the influence of aerosols and altitude on solar UV irradiance. The altitude effect (AE) was evaluated for UV irradiance under cloudless conditions by taking spectral and broadband measurements in SE Spain in the summer of 2002 at three nearby sites located at different heights (680 m, 2200 m, and 3398 m). A spectral radiative transfer model (Santa Barbara DISORT Atmospheric Radiative Transfer (SBDART)) was also applied, mainly to evaluate the tropospheric ozone impact on AE. Results are related to the optical properties and air mass origin of the a…

Data flow of spectral UV measurements at Sodankylä and Jokioinen

2016

Abstract. The data flow involved in a long-term continuous solar spectral UV irradiance monitoring program is investigated and structured to provide an overall view on the multiphase process from data acquisition to the final products. The program employing Brewer spectrophotometers as measuring instruments is maintained by the Finnish Meteorological Institute (FMI) ever since the 1990s at two sites in Finland: Sodankylä (67° N) and Jokioinen (61° N). It is built upon rigorous operation routines, processing procedures, and tools for quality control (QC) and quality analysis (QA) under continuous development and evaluation. Three distinct levels of data emerge, each after certain phase in th…

Stratosphere-troposphere exchange: A review, and what we have learned from STACCATO

2003

[1] This paper provides a review of stratosphere-troposphere exchange (STE), with a focus on processes in the extratropics. It also addresses the relevance of STE for tropospheric chemistry, particularly its influence on the oxidative capacity of the troposphere. After summarizing the current state of knowledge, the objectives of the project Influence of Stratosphere-Troposphere Exchange in a Changing Climate on Atmospheric Transport and Oxidation Capacity (STACCATO), recently funded by the European Union, are outlined. Several papers in this Journal of Geophysical Research– Atmospheres special section present the results of this project, of which this paper gives an overview. STACCATO deve…

2017

Abstract. Lightning represents one of the dominant emission sources for NOx in the troposphere. The direct release of oxidised nitrogen in the upper troposphere does not only affect ozone formation, but also chemical and microphysical properties of aerosol particles in this region. This study investigates the direct impact of LNOx emissions on upper-tropospheric nitrate using a global chemistry climate model. The simulation results show a substantial influence of the lightning emissions on the mixing ratios of nitrate aerosol in the upper troposphere of more than 50 %. In addition to the impact on nitrate, lightning substantially affects the oxidising capacity of the atmosphere with substan…

2017

Abstract. Ozone (O3) is an important atmospheric oxidant, a greenhouse gas, and a hazard to human health and agriculture. Here we describe airborne in situ measurements and model simulations of O3 and its precursors during tropical and extratropical field campaigns over South America and Europe, respectively. Using the measurements, net ozone formation/destruction tendencies are calculated and compared to 3-D chemistry–transport model simulations. In general, observation-based net ozone tendencies are positive in the continental boundary layer and the upper troposphere at altitudes above  ∼  6 km in both environments. On the other hand, in the marine boundary layer and the middle tropospher…

2017

Abstract. We analysed the extensive dataset from the HUMPPA-COPEC 2010 and the HOPE 2012 field campaigns in the boreal forest and rural environments of Finland and Germany, respectively, and estimated the abundance of stabilised Criegee intermediates (SCIs) in the lower troposphere. Based on laboratory tests, we propose that the background OH signal observed in our IPI-LIF-FAGE instrument during the aforementioned campaigns is caused at least partially by SCIs. This hypothesis is based on observed correlations with temperature and with concentrations of unsaturated volatile organic compounds and ozone. Just like SCIs, the background OH concentration can be removed through the addition of su…

2020

Abstract. Aerosol mass spectrometers (AMS) are frequently applied in atmospheric aerosol research in connection with climate, environmental or health-related projects. This is also true for the measurement of the organic fraction of particulate matter, still the least understood group of components contributing to atmospheric aerosols. While quantification of the organic and/or inorganic aerosol fractions is feasible, more detailed information about individual organic compounds or compound classes can usually not be provided by AMS measurements. In this study, we present a new method to detect organic peroxides in the particle phase in real-time using an AMS. Peroxides (ROOR') are of high i…

Some aspects of the seasonal variation of carbon dioxide and ozone

1968

An attempt is made to estimate the seasonal source function, Q , of CO 2 on the basis of data for the biosphere, provided by Lieth, and for other sources. The variation of soil respiration appears to be the most uncertain factor. The resulting CO 2 variations in the atmosphere are calculated for horizontal exchange coefficients, K , which vary with latitude. Comparison with observations given by Bolin & Keeling shows that the results are not very sensitive with respect to the assumed variations of Q and of K with latitude. Previous results on the 0 3 budget are used to calculate seasonal variations of tropospheric 0 3 for stratospheric injection rates, and K values which vary with latitude.…

Stratospheric aerosol measurements in the Arctic winter of 1996/1997 with the M-55 Geophysika high-altitude research aircraft

2000

In-situ aerosol measurements were performed in the northern hemispheric stratosphere up to altitudes of 21 km between 13 November 1996 and 14 January 1997, inside and outside of the polar vortex during the Airborne Polar Experiment (APE) field campaign. These are measurements of particle size distributions with a laser optical particle counter of the FSSP-300 type operated during 9 flights on the Russian M-55 high-altitude research aircraft Geophysika. For specific flights, the FSSP-300 measurements are compared with balloon-borne data (launched from Kiruna, Sweden). It was found that the stratospheric aerosol content reached levels well below the background concentrations measured by the N…

Sampling of an STT event over the Eastern Mediterranean region by lidar and electrochemical sonde

2005

A two-wavelength ultraviolet (289–316nm) ozone Differential Absorption Lidar (DIAL) system is used to perform ozone measurements in the free troposphere in the Eastern Mediterranean (Northern Greece). The ozone DIAL profiles obtained during a Stratosphere-to-Troposphere Transport (STT) event are compared to that acquired by an electrochemical ozonesonde, in the altitude range between 2 and 10 km. The measurement accuracy of these two instruments is also discussed. The mean difference between the ozone profiles obtained by the two techniques is of the order of 1.11 ppbv (1.86%), while the corresponding standard deviation is 4.69 ppbv (8.16%). A case study of an STT event which occurred on 29…