Search results for "partition function"
showing 5 items of 35 documents
Surface free energy of the open XXZ spin-1/2 chain
2012
We study the boundary free energy of the XXZ spin-$\tf{1}{2}$ chain subject to diagonal boundary fields. We first show that the representation for its finite Trotter number approximant obtained by Bortz, Frahm and G\"{o}hmann is related to the partition function of the six-vertex model with reflecting ends. Building on the Tsuchiya determinant representation for the latter quantity we are able to take the infinite Trotter number limit. This yields a representation for the surface free energy which involves the solution of the non-linear integral equation that governs the thermodynamics of the XXZ spin-1/2 chain subject to periodic boundary conditions. We show that this integral representati…
1980
A phenomenological theory of the Phase Distribution Chromatography (PDC)-separation effect is outlined and a theoretical equation for the measured PDC-calibration curves is given. Assuming a reversible-thermodynamical equilibrium in the polystyrene-PDC-column, only a relatively small part of the measured PDC-calibration curves could be explained: namely those running below their tangents. In order to explain the whole sigmoidal shape of the experimental curves, a theory of steady state in the system sol/gel was developed assuming deformation of the polymer coil near the gel front due to the stress related to the velocity gradient. The resulting dynamical flow-equilibrium differs highly from…
Totally asymmetric exclusion process fed by using a non-Poissonian clock
2015
In this article we consider the one-dimensional totally asymmetric open-boundary exclusion process fed by a process with power-law-distributed waiting times. More specifically, we use a modified Pareto distribution to define the jump rate for jumps into the system. We then characterize the propagation of fluctuations through the system by kinetic Monte Carlo simulations and by numerical evaluation of the steady-state partition function. peerReviewed
2019
Abstract The aim of this work is to present a formulation to solve the one-dimensional Ising model using the elementary technique of mathematical induction. This formulation is physically clear and leads to the same partition function form as the transfer matrix method, which is a common subject in the introductory courses of statistical mechanics. In this way our formulation is a useful tool to complement the traditional more abstract transfer matrix method. The method can be straightforwardly generalised to other short-range chains, coupled chains and is also computationally friendly. These two approaches provide a more complete understanding of the system, and therefore our work can be o…
Calculation of the Phase Behavior of Lipids
1998
The self-assembly of monoacyl lipids in solution is studied employing a model in which the lipid's hydrocarbon tail is described within the Rotational Isomeric State framework and is attached to a simple hydrophilic head. Mean-field theory is employed, and the necessary partition function of a single lipid is obtained via a partial enumeration over a large sample of molecular conformations. The influence of the lipid architecture on the transition between the lamellar and inverted-hexagonal phases is calculated, and qualitative agreement with experiment is found.