Search results for "passiv"
showing 10 items of 512 documents
Photocurrent spectroscopy of thin passive films
2002
Publisher Summary This chapter reviews theoretical background on the photoelectrochemistry of metal and semiconductor electrodes on which photocurrent spectroscopy (PCS) relies, by focusing particularly on new features that are typical of the photoelectrochemical behavior of thin passive films and usually absent in the behavior of bulk crystalline semiconductors. The chapter also highlights the advantages of PCS in getting in situ information on the structure of the metal-passive-film-electrolyte systems and shows a more recent quantitative use of this technique in characterizing the composition of passive films. The formation of a protective film on a metallic surface is a key step in esta…
Photoelectrochemical Techniques in Corrosion Studies
2005
Dry Mechanochemical Synthesis of Highly Luminescent, Blue and Green Hybrid Perovskite Solids
2019
A simple method to obtain bright photoluminescent wide bandgap mixed‐halide 3D perovskites is reported. The materials are prepared by dry mechanochemical synthesis (ball‐milling) starting from neat binary precursors, and show enhanced photoluminescence upon the addition of an adamantane derivative in the precursors' mixture. The structural characterization suggests that the additive does not participate in the crystal structure of the perovskite, which remains unvaried even with high loading of amantadine hydrochloride. By simple stoichiometric control of the halide precursors, the photoluminescence can be finely tuned from the UV to the green part of the visible spectrum. Photoluminescence…
Different natures of surface electronic transitions of carbon nanoparticles
2017
The photoluminescence behaviour of carbon-based nanodots is still debated. Both core and surface structures are involved in the emission mechanism, and the electronic transitions can be modified by external agents such as metal ions or pH, but the general relation between the structure and the optical function is poorly understood. Here, we report a comparative study on the effects of these variables, changing the core structure from crystalline to amorphous, and modifying the surface structure by different passivation procedures. Our results highlight that the emission mechanism of the tunable visible fluorescence is identical for crystalline and amorphous samples, indicating the independe…
Physico-chemical Properties of Anodic Oxide Films: from Passivity to Electronics
2014
Physico-chemical characterization of passive films on 316L stainless steel grown in high temperature water
2014
All-fiber incoherent frequency-to-time mapping method for microwave signal generation with baseband transmission and multicasting support
2008
We present a proof-of-principle experiment for achieving simultaneous distribution of baseband radio-frequency data and up-conversion with broadcasting support over a passive optical network. The technique is based on an incoherent frequency-to-time mapping method for pulse shaping. Specifically, we synthesize the spectral density function of sliced ASE noise from an EDFA with a periodic Mach-Zehnder fiber interferometer optical filter. By using external intensity modulation combined with propagation in an optical fiber, after photodetection, the resultant averaged temporal pulse profile resembles the shape of the incoherent source. The photodetected signal contains both the baseband data a…
High-overtone bulk acoustic resonator as passive ground penetrating RADAR cooperative targets
2013
International audience; RAdio-frequency Detection And Ranging instruments—RADARs—are widely used for applications aimed at measuring passive target velocity or ranging for various metrology applications such as ground position and localization. Within the context of using piezoelectric acoustic passive sensors as cooperative targets to RADARs probed through a radiofrequency link, this paper reports on investigating the compatibility of narrowband resonator architectures with the classical operation mode of wideband RADAR instruments. Since single mode resonators are hardly compatible due to the limited bandwidth of their spectrum, the investigation has been extended to High-overtone Bulk Ac…
PON Monitoring Technique Based on 2D Encoders and Wavelength-to-Time Mapping
2020
A PON monitoring technique is demonstrated based on an OTDR-like device and FBG-encoders having a unique combination of central wavelength and reflection bandwidth. This results in more compact and cost-efficient encoders than previous proposals.
The calculation of the mean radiant temperature of a subject exposed to the solar radiation – A generalised algorithm
2005
Abstract The thermal sensation experienced by a subject in a confined environment is significantly affected by the radiative heat exchange between the human body and the surrounding surfaces: it contributes as far as 30% of the whole thermal exchanges of the subject. Besides, the presence of high-intensity radiation sources like, for example, the sun, may appreciably modify the radiant field to which people are exposed. As a consequence, this could alter notably the comfort conditions. In order of properly taking into account this issue, a simple analytical method is introduced in this work, that allows the easy evaluation of the thermal radiant field induced by the presence of the solar ra…