Search results for "pentafluorophenyl"

showing 4 items of 64 documents

CCDC 1440372: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Dalton Trans.|45|3711|doi:10.1039/C6DT00416D

bis(cyclopentadienyl)-(1-(2-(dicyclohexylphosphanyl)phenyl)-2-phenylhydrazin-1-ido)-zirconium(iv) tetrakis(pentafluorophenyl)borateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

Reactive nanorods based on activated esterpolymers: a versatile template-assisted approach for the fabrication of functional nanorods

2011

A new route for the fabrication of polymeric nanorods with functional moieties via post-modification of reactive nanorods is described. To this end reactive nanorods with a homogenous and narrow size distribution were fabricated by utilizing an anodic aluminium oxide (AAO) template-assisted approach. The nanorods are based on activated pentafluorophenyl esters, to enable quantitative post-modification with amines under very mild reaction conditions yielding the corresponding functionalized amide. Post-modification with fluorescent dyes as well as the conversion into well-dispersed rod-shaped poly(N-isopropylacrylamide) (PNIPAM) hydrogels that exhibit a thermal-responsive phase transition wa…

chemistry.chemical_classificationMaterials scienceFabricationPolymers and PlasticsOrganic Chemistrytechnology industry and agricultureBioengineeringNanotechnologyPentafluorophenyl estersPolymerBiochemistrychemistry.chemical_compoundchemistryAmideSelf-healing hydrogelsDrug deliveryAluminium oxideNanorodPolym. Chem.
researchProduct

CCDC 1880078: Experimental Crystal Structure Determination

2019

Related Article: Wenqian Shan, Nicolas Desbois, Sandrine Pacquelet, Stéphane Brandès, Yoann Rousselin, Jeanet Conradie, Abhik Ghosh, Claude P. Gros, Karl M. Kadish|2019|Inorg.Chem.|58|7677|doi:10.1021/acs.inorgchem.8b03006

diammine-(2-(5-((5-(2-oxidophenyl)-2H-pyrrol-2-ylidene)(pentafluorophenyl)methyl)-1H-pyrrol-2-yl)phenolato)-cobalt(iii) chloroform solvate monohydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

The pentafluorophenyl group as π-acceptor for anions: a case study

2015

Chemical science 6(1), 354-359 (2015). doi:10.1039/C4SC02762K

positive chargesChemistryStereochemistryChemieSolid-stateGeneral Chemistryhapticities540side-chainsstructural dataAcceptor3. Good healthIonevaluation criteriakey elementsComputational chemistryGroup (periodic table)pentafluorophenylddc:540HapticitySide chainStatistical analysiselectron-deficientta116Chemical Science
researchProduct