Search results for "pentamethylcyclopentadienyl"

showing 10 items of 44 documents

CCDC 1426906: Experimental Crystal Structure Determination

2016

Related Article: Erik Ekengard, Kamlesh Kumar, Thibault Fogeron, Carmen de Kock, Peter J. Smith, Matti Haukka, Magda Monari, Ebbe Nordlander|2016|Dalton Trans.|45|3905|doi:10.1039/C5DT03739E

(eta5-pentamethylcyclopentadienyl)-(N-(7-chloroquinolin-4-yl)-N'-(pyridin-2-ylmethyl)ethane-12-diamine)-chloro-rhodium(iii) chloride dichloromethane solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Pentamethylcyclopentadienyl-rhodium and iridium complexes containing (N^N and N^O) bound chloroquine analogue ligands: synthesis, characterization an…

2016

The synthesis and characterization of twenty new pentamethylcyclopentadienyl-rhodium and iridium complexes containing N^N and N^O-chelating chloroquine analogue ligands are described. The in vitro antimalarial activity of the new ligands as well as the complexes was evaluated against the chloroquine sensitive (CQS) NF54 and the chloroquine resistant (CQR) Dd2 strains of Plasmodium falciparum. The antimalarial activity was found to be good to moderate; although all complexes are less active than artesunate, some of the ligands and complexes showed better activity than chloroquine (CQ). In particular, rhodium complexes were found to be considerably more active than iridium complexes against t…

Models Molecularantimalarial propertiesStereochemistryPlasmodium falciparumDrug ResistanceMolecular Conformationchemistry.chemical_elementCrystal structureChemistry Techniques Synthetic010402 general chemistryIridiumLigands01 natural sciencesChlorideRhodiumIridium and Rhodium complexes chloroquine analog ligands Crystal structures in vitro antimalarian activityInorganic Chemistrychemistry.chemical_compoundAntimalarialsmedicineOrganometallic CompoundsMoietyRhodiumIridiumta116iridium complexesGroup 2 organometallic chemistrySchiff basechloroquine analogue ligands010405 organic chemistrypentamethylcyclopentadienyl-rhodium complexesChloroquine0104 chemical scienceschemistryDerivative (chemistry)medicine.drug
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CCDC 876053: Experimental Crystal Structure Determination

2013

Related Article: M.Martin-Ortiz, M.Gomez-Gallego, C.R.de Arellano, M.A.Sierra|2012|Chem.-Eur.J.|18|12603|doi:10.1002/chem.201202327

Space GroupCrystallography(2-(9-(tetrahydro-2H-pyran-2-yl)-9H-purin-6-yl)phenyl)-chloro-(eta^5^-pentamethylcyclopentadienyl)-iridiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2109022: Experimental Crystal Structure Determination

2022

Related Article: Charline Sire, Hélène Cattey, Anthonia Tsivery, Jean‐Cyrille Hierso, Julien Roger|2022|Adv.Synth.Catal.|364|440|doi:10.1002/adsc.202101211

Space GroupCrystallography(eta5-pentamethylcyclopentadienyl)-bromo-[3-(diphenylphosphanyl)pyren-4-yl]-rhodium(iii) dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 200715: Experimental Crystal Structure Determination

2003

Related Article: H.Brunner, M.M.Kubicki, A.Lange, J.Wachter, E.Vigier, M.Zabel|2003|Angew.Chem.,Int.Ed.|42|3547|doi:10.1002/anie.200350931

Space GroupCrystallography(mu~2~-Stibinosulfide-SSSbSb)-tetracarbonyl-bis(eta^5^-pentamethylcyclopentadienyl)-di-molybdenum hexafluorophosphate tetrahydrofuran solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 290685: Experimental Crystal Structure Determination

2006

Related Article: A.Lange, M.M.Kubicki, J.Wachter, M.Zabel|2005|Inorg.Chem.|44|7328|doi:10.1021/ic050493e

Space GroupCrystallography(mu~3~-disulfido)-tris(mu~3~-sulfido)-tetrakis((eta^5^-pentamethylcyclopentadienyl)-rhodium) toluene solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 676308: Experimental Crystal Structure Determination

2013

Related Article: C.Groger,M.M.Kubicki,W.Meier,M.Pronold,J.Wachter,M.Zabel|2009|Organometallics|28|5633|doi:10.1021/om900600t

Space GroupCrystallography(mu~4~-Thioxophosphanido)-(mu~3~-thioxophosphanido)-(mu~3~-sulfido)-bis(eta^5^-pentamethylcyclopentadienyl)-tridecacarbonyl-di-molybdenum-tri-tungstenCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1426907: Experimental Crystal Structure Determination

2016

Related Article: Erik Ekengard, Kamlesh Kumar, Thibault Fogeron, Carmen de Kock, Peter J. Smith, Matti Haukka, Magda Monari, Ebbe Nordlander|2016|Dalton Trans.|45|3905|doi:10.1039/C5DT03739E

Space GroupCrystallographyCrystal System(eta5-pentamethylcyclopentadienyl)-(N-(7-chloroquinolin-4-yl)-N'-(pyridin-2-ylmethylene)ethane-12-diamine)-chloro-iridium(iii) chloride trihydrateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2074193: Experimental Crystal Structure Determination

2022

Related Article: Charline Sire, Hélène Cattey, Anthonia Tsivery, Jean‐Cyrille Hierso, Julien Roger|2022|Adv.Synth.Catal.|364|440|doi:10.1002/adsc.202101211

Space GroupCrystallographyCrystal System(eta5-pentamethylcyclopentadienyl)-chloro-[3-(diphenylphosphanyl)pyren-4-yl]-rhodium dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 952795: Experimental Crystal Structure Determination

2014

Related Article: Marta Valencia, Mamen Martín-Ortiz, Mar Gómez-Gallego, Carmen Ramírez de Arellano, Miguel A. Sierra|2014|Chem.-Eur.J.|20|3831|doi:10.1002/chem.201304091

Space GroupCrystallographyCrystal System(eta^5^-Pentamethylcyclopentadienyl)-(1-(anthracen-9-yl)-3-methoxy-1-[2-(9-methyl-9H-purin-6-yl)phenyl]-3-oxoprop-1-en-2-yl)-chloro-rhodium dichloromethane solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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