Search results for "perturbation theory"
showing 10 items of 584 documents
Eta-eta' Photoproduction and the axial isoscalar neutral current coupling
1995
We show that coherentη andη′ photoproduction by means of the Primakoff Effect on the proton depends on the strange component of the neutral axial current coupling. We construct polarization asymmetries that are sensitive to this coupling through theγ−Z interference. Theη′ is not a Goldstone boson of a spontaneously broken chiral symmetry, but a phenomenological analysis of theη andη′ production through chiral perturbation theory allows to calculate the observables of interest. The polarized proton or polarized photon asymmetries are predicted to be close to 10−4 for −q 2∼0.1−0.5 GeV2.
Computational investigation and experimental considerations for the classical implementation of a full adder on SO2 by optical pump-probe schemes
2008
International audience; Following the scheme recently proposed by Remacle and Levine Phys. Rev. A 73, 033820 2006 , we investigate the concrete implementation of a classical full adder on two electronic states X˜ 1A1 and C ˜ 1B2 of the SO2 molecule by optical pump-probe laser pulses using intuitive and counterintuitive stimulated Raman adiabatic passage excitation schemes. The resources needed for providing the inputs and reading out are discussed, as well as the conditions for achieving robustness in both the intuitive and counterintuitive pump-dump sequences. The fidelity of the scheme is analyzed with respect to experimental noise and two kinds of perturbations: The coupling to the neigh…
Momentum dependence of the decay η→π+π−π0
1998
Abstract The π 0 momentum dependence of the decay η → π + π − π 0 has been measured with the Crystal Barrel detector. The analysis is based on 3230 events. The results of this independent measurement are compared to new chiral perturbation theory calculations and previous measurements.
Analysis of a slow–fast system near a cusp singularity
2016
This paper studies a slow fast system whose principal characteristic is that the slow manifold is given by the critical set of the cusp catastrophe. Our analysis consists of two main parts: first, we recall a formal normal form suitable for systems as the one studied here; afterwards, taking advantage of this normal form, we investigate the transition near the cusp singularity by means of the blow up technique. Our contribution relies heavily in the usage of normal form theory, allowing us to refine previous results. (C) 2015 Elsevier Inc. All rights reserved.
Ab initio determination of the ionization potentials of DNA and RNA nucleobases
2006
Quantum chemical high level ab initio coupled-cluster and multiconfigurational perturbation methods have been used to compute vertical and adiabatic ionization potentials of the five canonical DNA and RNA nucleobases: uracil, thymine, cytosine, adenine, and guanine. Several states of their cations have been also calculated. The present results represent a systematic compendium of these magnitudes, establishing theoretical reference values at a level not reported before, calibrating computational strategies, and guiding the assignment of the features in the experimental photoelectron spectra. Daniel.Roca@uv.es Mercedes.Rubio@uv.es Manuela.Merchan@uv.es Luis.Serrano@uv.es
Slow-roll corrections in multi-field inflation: a separate universes approach
2018
In view of cosmological parameters being measured to ever higher precision, theoretical predictions must also be computed to an equally high level of precision. In this work we investigate the impact on such predictions of relaxing some of the simplifying assumptions often used in these computations. In particular, we investigate the importance of slow-roll corrections in the computation of multi-field inflation observables, such as the amplitude of the scalar spectrum $P_\zeta$, its spectral tilt $n_s$, the tensor-to-scalar ratio $r$ and the non-Gaussianity parameter $f_{NL}$. To this end we use the separate universes approach and $\delta N$ formalism, which allows us to consider slow-roll…
NMR chemical shift calculations within local correlation methods: the GIAO-LMP2 approach
2000
A scheme for the calculation of NMR chemical shifts using local second-order Moller–Plesset (LMP2) perturbation theory together with gauge-including atomic orbitals (GIAOs) is presented. Test calculations on the basis of a preliminary implementation within a conventional GIAO-MP2 code show that the deviations between GIAO-LMP2 and GIAO-MP2 are small, e.g., for 13C typically less than 1 ppm, and that the GIAO-LMP2 approach holds great promise for application to larger molecules.
Selected dissociation‐ and correlation‐consistent configuration interaction by a perturbative criterion
1990
We propose a perturbative criterion to select the most important dissociation‐ or correlation‐consistent type of contributions to perform generalized valence bond‐configuration interaction (GVB‐CI) calculations, dissociation‐consistent configuration interaction (DCCI) or correlation‐consistent configuration interaction (CCCI) approach, respectively. The procedure presented is computationally less demanding than the CCCI proposed by Goddard and co‐workers. To ensure the distance consistency of the MOs used, the nonvalence virtual orbitals are obtained by a projection technique. The results obtained for a few test calculations show the ability of the suggested approach to get close results to…
Experimental and theoretical studies of Λ doublings and permanent electric dipoles in the low-lying Π1 states of NaCs
2006
We present experimental data on the electric permanent dipole moments d(v',J') and lambda splittings (q factors) in the quasidegenerate (3) 1pi(e/f) state of the NaCs molecule over a wide range of the vibrational (v') and rotational (J') quantum numbers by using the combination of dc Stark mixing and electric radio frequency-optical double resonance methods. Within the experimental (3) 1pi state v' ranged from v' = 0 to 34, q values exhibited a pronounced decrease from 7.91x10(-6) to 0.47x10(-6) cm(-1), while absolute value(d) values varied between 8.0 and 5.0 D. Experimental evaluation yielded small d values about 1 D for D2 1pi state v'3 levels. The experiment is supported by ab initio el…
Study of eta K(K)over-bar and eta ' K(K)over-bar with the fixed center approximation to Faddeev equations
2013
In the present work we investigate the three-body systems of eta K (K) over bar and eta'K (K) over bar, by taking the fixed center approximation to Faddeev equations. We find a clear and stable resonance structure around 1490 MeV in the squared eta K (K) over bar scattering amplitude, which is not sensitive to the renormalization parameters. Conversely, we get only an enhancement effect of the threshold in the eta'K (K) over bar amplitude that indicates the difficulty to bind the eta'K (K) over bar system as a consequence of the eta'K interaction being weaker than the eta K one. We associate the eta K (K) over bar state found to the eta(1475).