Search results for "petrol"
showing 10 items of 1738 documents
Mercury emissions from soils and fumaroles of Nea Kameni volcanic centre, Santorini (Greece)
2013
There have been limited studies to date targeting mercury emissions from volcanic fumarolic systems, and no mercury flux data exist for soil or fumarolic emissions at Santorini volcanic complex, Greece. We present results from the first geochemical survey of Hg and major volatile (CO2, H2S, H2O and H-2) concentrations and fluxes in the fumarolic gases released by the volcanic/hydrothermal system of Nea Kameni islet; the active volcanic center of Santorini. These data were obtained using a portable mercury spectrometer (Lumex 915+) for gaseous elemental mercury (GEM) determination, and a Multi-component Gas Analyzer System (Multi-GAS) for major volatiles. Gaseous Elemental Mercury (GEM) conc…
In situ carbon and oxygen isotopes measurements in carbonates by fiber coupled laser diode-induced calcination: A step towards field isotopic charact…
2021
International audience; Natural stable isotopes ratios (δ13Ccarb and δ18Ocarb) of carbonates archived in the geological record are routinely used to reconstruct local and global paleo temperatures and the secular evolution of the biogeochemical carbon cycle. The state-of-the-art technique, employed since the mid 20th century, to measure these isotopic ratios starts with field sampling followed by several steps of physical and chemical laboratory preparation including: (i) microdrilling and/or sawing and crushing, (ii) CO2 release by wet acid digestion, (iii) gas equilibration, purification and transfer, before (iv) gas phase IRMS measurements. While these steps are time and resource consumi…
Simulating speleothem growth in the laboratory: Determination of the stable isotope fractionation (δ13C and δ18O) between H2O, DIC and CaCO3
2019
Abstract Here we present novel cave-analogue experiments directly investigating stable carbon and oxygen isotope fractionation between the major involved species of the carbonate system (HCO3−, CO2, CaCO3 and H2O). In these experiments, which were performed under controlled conditions inside a climate box, a thin film of solution flew down an inclined marble or glass plate. After different distances of flow and, thus, residence times on the plate, pH, electrical conductivity, supersaturation with respect to calcite, precipitation rate as well as the δ18O and δ13C values of the dissolved inorganic carbon (DIC) and the precipitated CaCO3 were obtained. Progressive precipitation of CaCO3 along…
Climatic fluctuations and seasonality during the Late Jurassic (Oxfordian–Early Kimmeridgian) inferred from delta18O of Paris Basin oyster shells.
2008
10 pages; International audience; Oxygen isotope data from biostratigraphically well-dated oyster shells from the Late Jurassic of the eastern Paris Basin are used to reconstruct the thermal evolution of western Tethyan surface waters during the Early Oxfordian–Early Kimmeridgian interval. Seventy eight oyster shells were carefully screened for potential diagenetic alteration using cathodoluminescence microscopy. Isotope analyses were performed on nonluminescent parts of shells (n=264). Intra-shell δ18O variability was estimated by microsampling along a transect perpendicular to the growth lines of the largest oyster shell. The sinusoidal distribution of the δ18O values along this transect …
Weathering evolution in lutites of the K/Pg transition red beds of the Tremp Group (Tremp-Isona Basin, south Pyrenees)
2017
AbstractThe Tremp–Isona basin (south-central Pyrenees, Lleida, Spain) shows maximum development of the Tremp Group (early Maastrichtian to late Paleocene) covering a wide geological record across the Cretaceous–Paleogene (K/Pg) boundary in continental facies. The mineralogy and geochemistry of lutites were used to assess the evolution of weathering from the Maastrichtian to the Eocene, and particularly for the red beds of the Lower Red and Upper Red Units (pre- and post-K/Pg, respectively). Chemical weathering decreased initially in the Maastrichtian (Gray Unit to Lower Red Unit), increasing subsequently from the Paleocene (Upper Red Unit) to Eocene units. ANOVA analysis of mineralogical co…
Intact seismic-scale platforms and ramps in the Lower to Middle Jurassic of Morocco: implications for stratal anatomy and lithofacies partitioning.
2017
9 pages; International audience; The Jurassic carbonate platforms of the central High Atlas in Morocco are well known for several high-quality outcrops. In the central High Atlas, there are two complementary locations that offer critical lessons for our understanding of Jurassic carbonate system evolution in extensional basins: a Lower Jurassic high-relief, carbonate platform with steep slopes that developed on the footwall of a rotating fault block in an active half-graben (Djebel Bou Dahar [DBD]) and an upper Lower to Middle Jurassic low-angle prograding carbonate ramp rich in ooids (Amellago ramp [AR]). The DBD and AR outcrops provide superbly exposed, structurally intact, and fully acce…
Hydrothermalism in the Tyrrhenian Sea: Inorganic and microbial sulfur cycling as revealed by geochemical and multiple sulfur isotope data
2011
15 pages; International audience; The Palinuro volcanic complex and the Panarea hydrothermal field, both located in the Tyrrhenian Sea (Italy), are associated with island arc magmatism and characterized by polymetallic sulfide mineralization. Dissolved sulfide concentrations, pH, and Eh measured in porewaters at both sites reveal a variable hydrothermal influence on porewater chemistry. Multiple sulfur isotopic measurements for disseminated sulfides (CRS: chromium reducible sulfur) extracted from sediments at Palinuro yielded a broad range in δ34S range between −29.8 and +10.2‰ and Δ33S values between+0.015 and+0.134‰. In contrast, sediments at Panarea exhibit a much smaller range in δ34SCR…
Water mass exchange and variations in seawater temperature in the NW Tethys during the Early Jurassic: evidence from neodymium and oxygen isotopes of…
2009
10 pages; International audience; Oxygen and neodymium isotope analyses performed on biostratigraphically well-dated fish remains recovered from the Hettangian to Toarcian of the Paris Basin were used to reconstruct variations of Early Jurassic seawater temperature and to track oceanographic changes in the NW Tethys. Our results indicate a strong correlation between δ18O trends recorded by fish remains and belemnites, confirming the paleoenvironmental origin of oxygen isotope variations. Interestingly, temperatures recorded by pelagic fishes and nektobenthic belemnites and bottom dwelling fishes are comparable during the Late Pliensbachian sea-level lowstand but gradually differ during the …
Revised phosphate-water fractionation equation reassessing paleotemperatures derived from biogenic apatite.
2010
8 pages; International audience; Oxygen isotopes of biogenic apatite have been widely used to reassess anomalous temperatures inferred from oxygen isotope ratios of ancient biogenic calcite, more prone to diagenetic alteration. However, recent studies have highlighted that oxygen isotope ratios of biogenic apatite differ dependent on used analytical techniques. This questions the applicability of the phosphate–water fractionation equations established over 25 years ago using earlier analytical techniques to more recently acquired data. In this work we present a new phosphate–water oxygen isotope fractionation equation based on oxygen isotopes determined on fish raised in aquariums at contro…
Facies variations in response to Holocene sea-level and climate change on Bora Bora, French Polynesia: Unravelling the role of synsedimentary siderit…
2017
International audience; Five mixed carbonate-siliciclastic sedimentary facies were identified in the barrier-reef lagoon of Bora Bora using microfacies and statistical analyses of 70 sediment samples taken at high resolution from two vibrocores. Fades and fades successions were interpreted with respect to Holocene sea-level and climate changes. The windward lagoon core is characterized by sideritic marly wackestones and foraminifera-sideritic wackestones, deposited around 7700 years BP (years before present) during the early-mid Holocene transgression. At that time, extensive weathering and erosion of iron-bearing minerals from the volcanic island, due to a wetter climate, were expressed in…