Search results for "petrology"

Active moss monitoring allows to identify and track distribution of metal(loid)s emitted from fumaroles on Vulcano Island, Italy

2014

Abstract Volatile metal(loid)s are known to be emitted from volcanoes worldwide. We tested the suitability of active moss monitoring for tracking volatile metal(loid)s released from the fumarolic field on Vulcano Island, Italy, and differentiated fumaroles from other sources of gaseous and particulate trace elements such as sea spray and soil. Metal(loid) accumulation on the mosses per day did depend neither on the state of the exposed moss (dead or living) nor exposure time (3, 6, or 9 weeks). After collection, mosses were digested with either HNO3/H2O2 or deionized water and analyzed by ICP-MS. While for most elements both extraction methods yielded similar concentrations, higher concentr…

Late Miocene sea surface salinity variability and paleoclimate conditions in the Eastern Mediterranean inferred from coral aragonite δ18O

2009

Abstract Coral skeletons are archives of chemical proxies which enable paleoenvironmental reconstructions to be made at subannual resolution. Stable oxygen isotope ( δ 18 O) ratios of these archives reflect sea surface temperature (SST) as well as the δ 18 O composition of ambient seawater. The δ 18 O seawater composition is not only controlled by global ice build-up, but river discharge and the hydrological balance of evaporation and precipitation, all influencing sea surface salinity (SSS), also play an important role in marginal seas. New sub-annually resolved coral δ 18 O data were measured and evaluated together with published data from reef coral communities of Late Miocene age from C…

Geothermal energy release at the Solfatara of Pozzuoli (Phlegraean Fields): Phreatic and phreatomagmatic explosion risk implications

1984

The H2O, CO2 and H2S outputs at the Solfatara of Pozzuoli have been measured and a map of the exhaling areas has also been made. The energy released at the surface by the fluids has been estimated to be 1019 ergs/day. The presence of aquifers at Phlegraean Fields increases the phreatic and phreatomagmatic explosion risk. Our results suggest that even if an uprising magma may interact with water at depth, an explosion could occur only at the shallow levels of a few hundred meters. Since the transfer of energy toward the surface is favoured by the presence of fractures, a detailed analysis of the deep fracture network would help to evaluate the risk levels of the various areas of Phlegraean F…

Sweet chestnut (Castanea sativa) leaves as a bio-indicator of volcanic gas, aerosol and ash deposition onto the flanks of Mt Etna in 2005–2007

2009

Sweet chestnut leaves (Castanea sativa) collected from the flanks of Mt Etna volcano in 2005-2007 were analysed by inductively-coupled plasma mass spectrometry to investigate the spatial and temporal variability of element concentrations. The aim of this work was to determine whether these leaves are a bio-indicator for volcanic gas, aerosol and ash deposition and to gain new insights into the environmental effects of quiescent and eruptive volcanic plumes. Results show a positive correlation between sample variability in the concentration of elements in Castanea sativa and enrichment factors of elements in the plume. The spatial and temporal variability of chalcophilic elements (As, Cd, Cu…

Modelling groundwater processes in a carbonate catchment: a case study from the Madonie area (Northern Sicily)

2011

Abstract This study reports on the results of a hydrogeochemical survey carried out in the Madonie area, a carbonate massif located in Palermo Province, Northern Sicily. The large dataset (226 collected sites) is used to highlight the processes controlling the distribution of dissolved chemicals in groundwaters; and, more importantly, to develop a general model (based on reaction-path modelling, and using the EQ3/6 code) of rock–water reactions in a carbonate environment. The investigated groundwater samples have conductivity between 31.7 and 8220 μS/cm; their total dissolved solids (TDS) content is higher near the coast area, where the seawater contribution becomes important. Calcium and H…

First 13C/12C isotopic characterisation of volcanic plume CO2

2010

We describe analytical details and uncertainty evaluation of a simple technique for the measurement of the carbon isotopic composition of CO2 in volcanic plumes. Data collected at Solfatara and Vulcano, where plumes are fed by fumaroles which are accessible for direct sampling, were first used to validate the technique. For both volcanoes, the plume-derived carbon isotopic compositions are in good agreement with the fumarolic compositions, thus providing confidence on the method, and allowing its application at volcanoes where the volcanic component is inaccessible to direct sampling. As a notable example, we applied the same method to Mount Etna where we derived a δ13C of volcanic CO2 betw…

Millennial-scale climate variability during the last 12.5 ka recorded in a Caribbean speleothem

2013

Abstract We present a speleothem stable oxygen isotope record for the last 12.5 ka based on two stalagmites from western Cuba. The δ18O signal is interpreted to represent past precipitation variability. Both stalagmites show a pronounced transition from higher δ18O values (indicating drier conditions) to more negative δ18O values (suggesting wetter conditions) between 10 and 6 ka. This transition is also visible in a planktonic δ18O record off Haiti. On orbital timescales, the δ18O value of Caribbean precipitation, thus, strongly resembles the oxygen isotope composition of Caribbean surface water. On millenial timescales, the speleothem δ18O record shows a high correlation to a North Atlant…

Ice age at the Middle–Late Jurassic transition?

2003

A detailed record of sea surface temperatures in the Northern Hemisphere based on migration of marine invertebrate fauna (ammonites) and isotopic thermometry (δ18O values of shark tooth enamel) indicates a severe cooling at the Middle–Late Jurassic transition (MLJT), about 160 Ma ago. The magnitude of refrigeration (1–3°C for lower middle latitudes) and its coincidence in time with an abrupt global-scale fall of sea level documented through sequence stratigraphy are both suggestive of continental ice formation at this time. Ice sheets may have developed over the high-latitude mountainous regions of Far-East Russia. The drastic cooling just post-dated the Middle–Late Callovian widespread dep…

Preface to the Special Issue on ‘‘Applications and developments of magnetic resonance techniques in geosciences’’

2011

The Coupled Magmatic and Hydrothermal Systems of the Restless Aluto Caldera, Ethiopia

2020

Seismicity can be used to better understand interactions between magma bodies, hydrothermal systems and their host rocks—key factors influencing volcanic unrest. Here, we use earthquake data to image, for the first time, the seismic velocity structure beneath Aluto, a deforming volcano in the Main Ethiopian Rift. Traveltime tomography is used to jointly relocate seismicity and image 3D P- and S-wave velocity structures and the ratio between them (V P/V S). At depths of 4–9 km, the seismicity maps the top of a large low velocity zone with high V P/V S, which we interpret as a more ductile and melt-bearing region. A shallow (<3 km) hydrothermal system exhibits low seismic velocities and ve…