Search results for "petrology"
showing 10 items of 1516 documents
Determination of U-Pb ages of zircons by direct measurement of the 210Pb/206Pb ratio
1993
Abstract Precise measurements of the 210Pb/206Pb ratio in zircons permits, for the first time, the determination of complete U-Pb ages by measurement of Pb isotopes only, without determination of the U-Pb ratio by isotope dilution. The 238U daughter isotope 210Pb is generally in radioactive equilibrium with 238U; however, the very short half-life of 210Pb (22.3a) results in extremely low 210Pb/206Pb ratios of ∼ 10−8, especially for Archaean zircons. These ratios have been determined using a Finnigan MAT 262® mass spectrometer equipped with a high abundance sensitivity lens system (RPQ). The accuracy of the 210Pb method has been tested on nine different zircon samples with 207Pb/206Pb ages f…
Empirical calibration of the clumped isotope paleothermometer using calcites of various origins
2014
We present the first universal calibration of the clumped isotope thermometer for calcites of various mineralizing types. These are an eggshell of an ostrich, a tropical bivalve, a brachiopod shell, cold seep carbonate, and three foraminifera samples that grew between 9 and 38 C. CaCO3 was digested at 90 C using a common acid bath. Considering a difference in phosphoric acid fractionation factors between reaction at 25 and 90 C of 0.069& (Guo et al., 2009), the function between growth temperature T and the excess of 13 C– 18 O bonds in the evolved CO2 is expressed by a linear regression between 1/T 2 and absolute D47 (R 2 = 0.9915):
Zircon M127 - A Homogeneous Reference Material for SIMS U-Pb Geochronology Combined with Hafnium, Oxygen and, Potentially, Lithium Isotope Analysis
2016
Faculty of Geosciences, Geography and Astronomy, University of Vienna; Beijing SHRIMP Centre, Chinese Academy of Geological Sciences; European Commission [MEXC-CT-2005-024878]; FWF Austrian Science Fund [P20028-N10, P24448-N19]; U.S. National Science Foundation [EAR 1524336]
Stable isotope fractionation in speleothems: Laboratory experiments
2010
Abstract In recent years, stalagmites have become important archives for paleoclimate. Several studies applying carbon and oxygen isotopes of stalagmites show a simultaneous increase of δ 13 C and δ 18 O along individual growth layers, which is interpreted as being indicative of isotope fractionation under disequilibrium conditions. In order to obtain robust paleoclimatic information from calcite precipitated under these non-equilibrium conditions it is important to improve the quantitative understanding of the corresponding isotope fractionation processes. Here we present laboratory experiments simulating calcite precipitation under cave-analogue conditions. The major focus was the investi…
Geochemical constraints on volatile sources and subsurface conditions at Mount Martin, Mount Mageik, and Trident Volcanoes, Katmai Volcanic Cluster, …
2017
Abstract We use the chemical and isotopic composition of volcanic gases and steam condensate, in situ measurements of plume composition and remote measurements of SO2 flux to constrain volatile sources and characterize subvolcanic conditions at three persistently degassing and seismically active volcanoes within the Katmai Volcanic Cluster (KVC), Alaska: Mount Martin, Mount Mageik and Trident. In situ plume measurements of gas composition were collected at all three volcanoes using MultiGAS instruments to calculate gas ratios (e.g. CO2/H2S, SO2/H2S and H2O/H2S), and remote measurements of SO2 column density were collected from Mount Martin and Mount Mageik by ultraviolet spectrometer system…
Ordering kinetics in synthetic Mg(Al,Fe3+)2O4 spinels: Quantitative elucidation of the whole Al-Mg-Fe partitioning, rate constants, activation energi…
2014
A novel procedure, based on the application of the kinetics simulator Gepasi, has been successfully applied for modeling the cation ordering process in two synthetic Mg(Al2-yFe3+y)O4 spinels (y~ 0.39 and 0.54, samples F39 and F54, respectively). The kinetic profiles suggested a two-stage mechanism, with rapid inter-site exchange of Fe3+ with Mg followed by slow exchange of Al with Mg. The trial to apply the classical approaches, based on the explicit solutions of the differential equations corresponding to single-cation (Sha-Chappel model) or two-cation (Müller model) exchange reactions, proved not feasible in the whole time range, thus implying a lack of information about the exchange proc…
In situ quantification of the nitrogen content of olivine-hosted melt inclusions from Klyuchevskoy volcano (Kamchatka): Implications for nitrogen rec…
2021
International audience; Assessing the N content of arc magmas and their mantle source remains a challenge because the volatile element composition of melts and gases can be modified during magma ascent, storage, and eruption. Given that melt inclusions (MIs) in Mg-rich olivine represent the best proxies for primary arc melts, we applied, for the first time, an in situ high-resolution secondary ion mass spectrometry (SIMS) method to determine the N concentration in olivine-hosted MIs from Klyuchevskoy volcano in Kamchatka. To reverse the effects of post-entrapment modification processes (i.e., exsolution of volatiles into a fluid bubble), the MIs were partially to completely homogenized at h…
Synthesis, characterization and study of covalently modified triazole LAPONITE® edges
2020
Abstract LAPONITE® (Lap) clay mineral was successful functionalized by triazole groups in a two steps procedure. First, the Lap edges were modified with 3-azidopropyltrimethoxysilane by traditional heating and microwave irradiation. Microwave irradiation allowed us to obtain high loading onto the Lap edges in lower times compared to those obtained through conventional method. Afterwards, the triazole moieties were obtained by reaction between azido functionalized Lap and propargyl alcohol. The successful functionalization of Lap was proved by thermogravimetric analysis, FT-IR spectroscopy, dynamic light scattering and ζ-potential measurements. Finally, the effects of the surface modificatio…
Reply to the “Comment by Delmelle et al. (2013) on ‘Scavenging of sulfur, halogens and trace metals by volcanic ash: The 2010 Eyjafjallajökull erupti…
2014
Abstract With this short communication we address the principal issues raised by Delmelle et al. (2014) in relation to the work of Bagnato et al. (2013) concerning the 2010 eruption of Eyjafjallajokull, Iceland. The principal conclusions of the work of Bagnato et al. (2013) include the observation that protracted gas-aerosol interaction in the plume promotes selective leaching of cation species from ash, with alkalis and Ca (and, among trace elements, Zn and Cu) being more rapidly re-mobilized (and transferred to soluble surface salts) relative to more inert elements (Mg, Ti). They also observed that adsorption onto ash surfaces is a major atmospheric sink of volcanic acidic gases, with 282…
Enhancement of adsorption ability of calcium alginate gel beads towards Pd(II) ion. A kinetic and equilibrium study on hybrid Laponite and Montmorill…
2015
Abstract The adsorption ability of hybrid Montmorillonite and Laponite–calcium alginate gel beads towards Pd 2 + ion was studied in the pH range 2–4, in pure water and in aqueous NaCl solution at I = 0.01 mol L − 1 and T = 25 °C. The pseudo second order kinetic equation and the Langmuir and Freundlich isotherms were used to fit the kinetic and thermodynamic experimental data. A comparison of the results already published on the adsorption capacity of calcium alginate gel beads at the same experimental conditions was made. Enhancement of palladium(II) adsorption by alginate beads with the addition of the two clay minerals was obtained, with increments higher than 50% of Pd(II) ion recovered/…