Search results for "photocatalysis"

showing 6 items of 606 documents

Synthesis and selected properties of metallo and metal-free 2,3,9,10,16,17,23,24-octacarboxyphthalocyanines

2015

This review article reports methods of synthe sis and selected physicochemical properties of metallo and metal-free 2,3,9,10,16,17,23,24–octacarboxyphthalocyanines. The most frequently used methods of synthesis for this class of co mpounds are described in this article. Moreover, aggregation, catalytic and photocatalytic properties of these complexes are presented. Potential applications of metallo and metal-free 2,3,9,10,16,17,23,24–octacarboxyphthalocyanines are also given.

synthesisabsorption spectraapplicationsChemistry3Organic Chemistryaggregation1724-octacarboxyphthalocyanines16Combinatorial chemistry10Catalysis23catalytic and photocatalytic activitylcsh:QD241-441Metal freelcsh:Organic chemistryPhotocatalysismetallo and metal-free 29ARKIVOC : Archive for Organic Chemistry
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Photocatalytic partial oxidation of propylene in the presence of mesoporous organosilane-modified titanias

2014

titania-silicaepoxidationSettore CHIM/07 - Fondamenti Chimici Delle Tecnologiephotocatalysis
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Combination of Photocatalysis and Ozonation for the treatment of Contaminated Water Containing Bromide Ions

2013

titanium dioxide photocatalysisn ozonationSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie
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Carbon Nitride-Based Catalysts for High Pressure CO2 Photoreduction

2022

In the current research, the productivity of CO2 photoreduction has been boosted by performing the reaction in an innovative photocatalytic reactor, which allows for operation up to 20 bar. A set of photocatalysts were used, including three types of pristine TiO2, i.e., one commercially prepared (Evonik P25), one home-prepared by flame spray pyrolysis (FSP), and one obtained by the hydrolysis of TiCl4 (TiO2exCl), a bare thermo-exfoliated carbon nitride (C3N4-TE), and binary materials composed of TiO2 and C3N4-TE. The photoreduction was carried out in water at pH 14 and in the presence of Na2SO3 as a hole scavenger. Hydrogen and very small amounts of CO were detected in the head space of the…

titanium dioxidesolar fuelsSettore ING-IND/25 - Impianti ChimiciCatalysiscarbon capture and conversionCO<sub>2</sub> photoreduction; carbon capture and conversion; photocatalysis; pressurized photoreactor; titanium dioxide; carbon nitride; solar fuelsCO2 photoreductionCO2 photoreduction; carbon capture and conversion; photocatalysis; pressurized photoreactor; titanium dioxide; carbon nitride; solar fuelsSettore CHIM/07 - Fondamenti Chimici Delle TecnologiePhysical and Theoretical Chemistrypressurized photoreactorcarbon nitridephotocatalysisGeneral Environmental Science
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Multimetallic Oxynitrides Nanoparticles for a New Generation of Photocatalysts

2019

A versatile synthetic strategy for the preparation of multimetallic oxynitrides has been designed and here exemplarily discussed considering the preparation of nanoscaled zinc-gallium oxynitrides and zinc-gallium-indium oxynitrides, two important photocatalysts of new generation, which proved to be active in key energy related processes from pollutant decomposition to overall water splitting. The synthesis presented here allows the preparation of small nanoparticles (less than 20 nm in average diameter), well-defined in size and shape, yet highly crystalline and with the highest surface area reported so far (up to 80 m2  g-1 ). X-ray diffraction studies show that the final material is not a…

urea glass routeDiffractionoxynitride010405 organic chemistryChemistryOrganic ChemistryNanoparticleGeneral Chemistry010402 general chemistrywater splitting01 natural sciencesDecompositionCatalysis0104 chemical sciencesCatalysismultimetallic nitrideReaction rate constantChemical engineeringSettore CHIM/03 - Chimica Generale E InorganicaOrganic dyePhotocatalysisWater splittingdye decompositionSettore CHIM/02 - Chimica FisicaChemistry – A European Journal
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Photocatalytic nano-composite architectural lime mortar for degradation of urban pollutants under solar and visible (interior) light

2017

Abstract Recent advances in nano-technology and nano-additives can give enhanced properties to natural hydraulic lime (NHL), creating a multifunctional material. We have prepared a novel nanocomposite, made of a commercial mortar with 1 wt% and 5 wt% added titania nanoparticles (NPs). These TiO 2 NPs are themselves doped with 1 mol% silver, to give the material enhanced photocatalytic and antimicrobial properties. The Ag-doped TiO 2 NPs were made from a simple, costs effective, aqueous green nanosynthesis process, and the end material only contains 0.01–0.05% Ag. As this mortar is intended to both combat atmospheric pollution, and create more durable/lower maintenance building facades (plas…

xTitaniaMaterials scienceSettore ING-IND/22 - Scienza e Tecnologia dei MaterialiSettore ICAR/10 - Architettura Tecnica02 engineering and technology010501 environmental sciencesengineering.material01 natural sciencesNOCoatingGeneral Materials SciencePhotocatalysisLime mortarComposite materialCuring (chemistry)0105 earth and related environmental sciencesCivil and Structural EngineeringSettore CHIM/03 - Chimica Generale e InorganicaNanocompositeNanocompositeSettore CHIM/07 - Fondamenti Chimici delle TecnologieHydraulic limeBuilding and Construction021001 nanoscience & nanotechnologyMortarengineeringPhotocatalysisMortar Natural hydraulic lime Photocatalysis NOx Titania NanocompositeNatural hydraulic limeMortar0210 nano-technologyMortar; Nanocomposite; Natural hydraulic lime; NO; x; Photocatalysis; TitaniaVisible spectrum
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