Search results for "pic"

Nuclear moments of indium isotopes reveal abrupt change at magic number 82

2022

In spite of the high-density and strongly correlated nature of the atomic nucleus, experimental and theoretical evidence suggests that around particular 'magic' numbers of nucleons, nuclear properties are governed by a single unpaired nucleon1,2. A microscopic understanding of the extent of this behaviour and its evolution in neutron-rich nuclei remains an open question in nuclear physics3-5. The indium isotopes are considered a textbook example of this phenomenon6, in which the constancy of their electromagnetic properties indicated that a single unpaired proton hole can provide the identity of a complex many-nucleon system6,7. Here we present precision laser spectroscopy measurements perf…

Local Structure Studies of Ti for SrTi16O3 and SrTi18O3 by Advanced X-ray Absorption Spectroscopy Data Analysis

2015

Strontium titanate is a model quantum paraelectric in which in the region of dominating quantum statistics the ferroelectric instability is inhibited due to nearly complete compensation of the harmonic contribution into ferroelectric soft mode frequency by the zero-point motion contribution. The enhancement of atomic masses by the substitution of 18O for 16O decreases the zero-point atomic motion and low-T ferroelectricity in SrTi18O3 is realized. In this study we report on the local structure of Ti in SrTi16O3 and SrTi18O3 by Ti K-edge extended x-ray absorption fine structure measurements in temperature range 6 – 300 K.

On the local mode behaviour of the XH2/XD2 and XD/XH fragments with respect to the deuterated species of the near local mode XH3(C3v ) molecule

2009

International audience; Effect of isotopic substitution in the near local mode, XH3(C3v), molecules is considered. On that basis it is shown that the spectroscopic properties of deuterated and/or di-deuterated isotopic species of the XH3(C3v) molecule with the value of interbond angle close to π/2 are analogous to the spectroscopic properties of its separate fragments: of a three-atomic local mode 'molecule' XH2/XD2 and of a diatomic XD/XH 'molecule'. The phosphine molecule is considered as an illustration.

Estimation of isotropic nuclear magnetic shieldings in the CCSD(T) and MP2 complete basis set limit using affordable correlation calculations

2013

A linear correlation between isotropic nuclear magnetic shielding constants for seven model molecules (CH2O, H2O, HF, F2, HCN, SiH4 and H2S) calculated with 37 methods (34 density functionals, RHF, MP2 and CCSD(T)), with affordable pcS-2 basis set and corresponding complete basis set results, estimated from calculations with the family of polarization-consistent pcS-n basis sets is reported. This dependence was also supported by inspection of profiles of deviation between CBS estimated nuclear shieldings and shieldings obtained with the significantly smaller basis sets pcS-2 and aug-cc-pVTZ-J for the selected set of 37 calculation methods. It was possible to formulate a practical approach o…

Guaranteed error bounds for linear algebra problems and a class of Picard-Lindelöf iteration methods

2012

This study focuses on iteration methods based on the Banach fixed point theorem and a posteriori error estimates of Ostrowski. Their application for systems of linear simultaneous equations, bounded linear operators, as well as integral and differential equations is considered. The study presents a new version of the Picard–Lindelöf method for ordinary differential equations (ODEs) supplied with guaranteed and explicitly computable upper bounds of the approximation error. The estimates derived in the thesis take into account interpolation and integration errors and, therefore, provide objective information on the accuracy of computed approximations.

Superconducting spintronic tunnel diode

2022

Diodes are key elements for electronics, optics, and detection. Their evolution towards low dissipation electronics has seen the hybridization with superconductors and the realization of supercurrent diodes with zero resistance in only one direction. Here, we present the quasi-particle counterpart, a superconducting tunnel diode with zero conductance in only one direction. The direction-selective propagation of the charge has been obtained through the broken electron-hole symmetry induced by the spin selection of the ferromagnetic tunnel barrier: a EuS thin film separating a superconducting Al and a normal metal Cu layer. The Cu/EuS/Al tunnel junction achieves a large rectification (up to ∼…

Kaksiosainen juhlateos valottaa myöhäiskeskiaikaista maalariammattilaisuutta Ruotsissa

2014

Commenting on poverty online : A corpus-assisted discourse study of the Suomi24 forum

2020

This paper brings new insight to poverty and social exclusion through an analysis of how poverty-related issues are commented on in the largest online discussion forum in Finland: Suomi24 (‘Finland24’). For data, we use 32,407 posts published in the forum in 2014 that contain the word köyhä (‘poor’) or a predefined semantically similar word. We apply the Corpus-Assisted Discourse Studies (CADS) method, which combines quantitative methods and qualitative discourse analysis. This methodological solution allows us to analyse both large-scale tendencies and detailed expressions and nuances on how poverty is discussed. The quantitative analysis is conducted with topic modelling, an unsupervised …

Männyn (Pinus sylvestris) ja kuusen (Picea abies) kaupallisesti hyödynnettävissä olevat pienimolekyyliset yhdisteet

2005

Fast pyrolysis of hot-water-extracted and delignified Norway spruce (Picea abies) sawdust by Py-GC/MS

2019

The thermochemical behavior of Norway spruce (Picea abies) sawdust as such and after various chemical treatments (hot-water extraction, delignification, and hot-water extraction followed by delignification) was investigated by analytical pyrolysis–gas chromatography–mass spectrometry. In each case, the yields of major GC-amenable condensable products were semi-quantitatively measured, and the individual compounds were classified into several compound groups. The formation of these groups from feedstock samples with varying mass portions of their structural constituents (carbohydrates and lignin) was determined at 500 °C and 700 °C with a residence time of 5 s and 20 s. The formation of pyro…