Search results for "pla"

Oxidation, efflux, and isotopic fractionation of methane during autumnal turnover in a polyhumic, boreal lake

2007

[1] We studied the oxidation and efflux of methane (CH4) in a small, polyhumic lake, Mekkojarvi (southern Finland), during 6 weeks in autumn when the stability of the water mass first weakened, temporarily restabilized, and finally mixed completely. During the summer stratification period, CH4 had accumulated in the anoxic hypolimnion to high concentrations (>150 mmol m−3). Gradual mixing of the water column during the autumn allowed access to both oxygen and CH4 by aerobic methane-oxidizing bacteria (MOB) deeper in the water column. Thus the bulk (∼83–88%) of the CH4 accumulated in the hypolimnion was subsequently consumed by MOB while only 12–17% was lost from the lake to the atmosphere a…

Precambrian crustal evolution and continental drift

1981

One of the major questions of Precambrian research is whether present-day plate tectonic models can be applied to the evolution of the ancient continental crust or whether the tectonic style suggests a unidirectional and therefore non-uniformitarian development in response to gradual changes in the global thermal regime through time.

Erratum: The runaway instability of thick discs around black holes - II. Non-constant angular momentum discs

2004

Thermal photon v3 at LHC from fluctuating initial conditions

2014

Abstract We calculate the triangular flow parameter v 3 of thermal photons for 0–40% central collisions of Pb nuclei at LHC using an event-by-event hydrodynamic model with fluctuating initial conditions. Thermal photon v 3 with respect to the participant plane angle is found to be positive and significant compared to the elliptic flow parameter v 2 of thermal photons. In addition, photon v 3 as a function of p T shows similar qualitative nature to photon v 2 in the region 1 p T 6 GeV / c . We argue that while v 3 originates from ϵ 3 deformations of the initial state density distribution, fast buildup of radial flow due to fluctuations is the main driving mechanism for the observed large val…

Synthesis of hyperbranched poly(tert-butyl acrylate) by self-condensing atom transfer radical polymerization of a macroinimer

2000

Using 2-hydroxyethyl α-bromoisobuty-rate as initiator, atom transfer radical polymerization (ATRP) of tert-butyl acrylate leads to poly(tert-butyl acrylate) (PtBA) with a hydroxyl group at one and a bromine atom at the other end. Esterification of the hydroxyl group of these heterotelechelic polymers with acryloyl chloride yields PtBA (M n = 3060) with a polymerizable double bond at one end and a bromine atom at the other end which can act as an initiator in ATRP (macroinimer). Self-condensing ATRP of such a macroinimer leads to hyperbranched or highly branched PtBA. The polymer was characterized by GPC viscosity measurements. Even at M w = 78800, a rather low polydispersity index of M w M …

Modeling suggests that oblique extension facilitates rifting and continental break-up

2012

[1] In many cases the initial stage of continental break-up was and is associated with oblique rifting. That includes break-up in the Southern and Equatorial Atlantic, separation from eastern and western Gondwana as well as many recent rift systems, like Gulf of California, Ethiopia Rift and Dead Sea fault. Using a simple analytic mechanical model and advanced numerical, thermomechanical modeling techniques we investigate the influence of oblique extension on the required tectonic force in a three-dimensional setting. While magmatic processes have been already suggested to affect rift evolution, we show that additional mechanisms emerge due to the three-dimensionality of an extensional syst…

Mechanism of anionic polymerization of methyl methacrylate in the presence of aluminium alkyls

1995

Methyl methacrylate was polymerized with tert-butyl lithium in the presence of triethylaluminium or triisobutylaluminium at 78°C in toluene. As indicated by GPC and MALDI-TOF mass spectrometry, the polymerization is accompanied by side reactions. The lower oligomers were fractionated by distillation and characterised by NMR, FT-IR, UV and electron impact (EI) mass spectrometry. All these data show that part of the polymer chains are carrying exactly one tert-butyl isoprenyl ketone unit. In order to avoid the formation of tert-butyl isoprenyl ketone a molar ratio of Al/Li>2 is necessary.

Piezoelectric Actuated Nonlinear Energy Sink With Tunable Attenuation Efficiency

2019

Abstract Comparing to linear vibration absorbers, nonlinear energy sinks (NESs) have attracted worldwide attention for their intrinsic characteristics of targeted energy transfer or energy pumping in a relatively wide frequency range. Unfortunately, they are highly dependent on the vibration amplitude to be attenuated and will play its role only if the external load exceeds a specific threshold value. Different from the passive bistable NES, a novel piezoelectric nonlinear energy sink (PNES) is designed by introducing in-phase actuation to compensate or enhance the external vibration loads, thus triggering the NES operating in high attenuation efficiency. The nonlinear mathematic model of t…

Sex-specific interaction between arbuscular mycorrhizal and dark septate fungi in the dioecious plant Antennaria dioica (Asteraceae).

2012

Male and female plants of dioecious species often differ in their resource demands and this has been linked to secondary sexual dimorphism, including sex-specific interactions with other organisms such as herbivores and pollinators. However, little is known about the interaction between dioecious plants and fungal root endophytes. Plants may be simultaneously colonised by arbuscular mycorrhizal (AM) and dark septate (DS) fungi. While it is well established that AM mutualism involves reciprocal transfer of photosynthates and mineral nutrients between roots of host plants and these fungi, the role of DS fungi remains controversial. Here, we report the temporal and spatial variation in AM and …

Synthesis, Anti-Inflammatory Activity, and in Vitro Antitumor Effect of a Novel Class of Cyclooxygenase Inhibitors: 4-(Aryloyl)phenyl Methyl Sulfones

2010

Following our previous research on anti-inflammatory drugs (NSAIDs), we report on the design and synthesis of 4-(aryloyl)phenyl methyl sulfones. These substances were characterized for their capacity to inhibit cyclooxygenase (COX-1 and COX-2) isoenzymes. Molecular modeling studies showed that the methylsulfone group of these compounds was inserted deep in the pocket of the human COX-2 binding site, in an orientation that precludes hydrogen bonding with Arg120, Ser353, and Tyr355 through their oxygen atoms. The N-arylindole 33 was the most potent inhibitor of COX-2 and also the most selective (COX-1/COX-2 IC(50) ratio was 262). The indole derivative 33 was further tested in vivo for its ant…