Search results for "plasmon"
showing 10 items of 614 documents
Chemical Interface Damping Depends on Electrons Reaching the Surface.
2017
Metallic nanoparticles show extraordinary strong light absorption near their plasmon resonance, orders of magnitude larger compared to nonmetallic nanoparticles. This "antenna" effect has recently been exploited to transfer electrons into empty states of an attached material, for example to create electric currents in photovoltaic devices or to induce chemical reactions. It is generally assumed that plasmons decay into hot electrons, which then transfer to the attached material. Ultrafast electron-electron scattering reduces the lifetime of hot electrons drastically in metals and therefore strongly limits the efficiency of plasmon induced hot electron transfer. However, recent work has revi…
Increasing Nanoparticles’ Refractive Index Sensitivity
2012
Since the plasmon resonance of nanoparticles depends on the refractive index of the immediate environment, these particles form the basis of many sensing schemes . The sensitivity of plasmon sensors for the detection of changes in the environment varies greatly and depends on the particle material and its morphology (size and shape). To further increase this sensitivity by chemical modifications was another goal of my work.
Synthesis of Yb nanoparticles by laser ablation of ytterbium target in sodium bis(2-ethylhexyl)sulfosuccinate reverse micellar solution
2010
Abstract Surfactant-coated ytterbium nanoparticles were produced by Nd:YAG laser ablation of a Yb bulk target immersed in sodium bis(2-ethylhexyl)sulfosuccinate (AOT)/ n -heptane micellar solution. In our experimental conditions, as highlighted by IR spectroscopy, AOT molecules are not decomposed by the intense laser pulses but play a pivotal role in the stabilisation of Yb nanoparticles. The formation of Yb nanoparticles in the liquid phase was monitored by UV–Vis spectroscopy whereas the Yb/AOT composites obtained by evaporation of the organic solvent were characterised by XPS and TEM. Data analysis consistently shows the presence of surfactant-coated, nearly spherical and non-interacting…
Analyse locale des sensibilités des lectures angulaires, spectroscopiques et ellipsométriques de la Résonance des Plasmons de Surface en vue de la mi…
2006
The fluorescence labelling, used by the fluorescence biochips, is known to change the charge distribution of the labelled molecules and then modify their biological activity. Among label free biosensors, we choose an optical detection, such as spectroscopic ellipsometry and/or surface plasmon resonance (SPR) of the biolayers.These optical techniques are based on the measurement of both thickness and optical index of the adsorbed biolayer. An AFM statistical measurement of the thickness of functionalized lithographed microstructures has been performed in order to determine the thickness of the biolayers.We have shown that the spectroscopic reading of the SPR phase shift is 100 times more sen…
ELECTRON-FED OPTICAL ANTENNA
2019
Nanoscale electronics and photonics are among the most promising research areas providing functional nanocomponents for data transfer and signal processing. By adopting metal-based optical antennas as a disruptive technological vehicle, we demonstrate that an optical antenna coupled to a tunnel junction can be interfaced to create an electronically driven self-emitting unit. This nanoscale plasmonic transmitter operates by injecting electrons in a contacted tunneling antenna feedgap. Under certain operating conditions, we show that the device radiates a broadband light spectrum which can be related to a thermal like spectrum. We propose a model based upon the spontaneous emission of hot ele…
SNOM signal near plasmonic nanostructures: an analogy with fluorescence decays channels
2008
International audience; Scanning Near-field Optical Microscope (SNOM) is based on local excitations of nanostructures deposited on a substrate (illumination mode). Ideally, the local source behaves like a dipolar emitter so that the SNOM signal is strongly similar to the fluorescence decay rates of an excited molecule that would be located at the SNOM tip position. We present here how the SNOM signal near plasmonic nanostructures can be used to analyze radiative and non-radiative contribution to the fluorescence decay rate.
Far-field imaging of the electromagnetic local density of optical states.
2008
International audience; We introduce a new experimental method to measure the local electromagnetic density of states (LDOS) by integrating the differential scattering cross section. The signal detected essentially reflects the intrinsic scattering response of the photonic structures and renders the partial LDOS dominated by evanescent modes. We give a theoretical understanding of the LDOS image formation and show a qualitative agreement between experimental images and theoretical maps. This approach can be practically applied to the direct measurement of an optical antenna's scattering efficiency and can provide valuable information for designing optimum structures utilized in radiative de…
Surface plasmon polaritons on metal cylinders with dielectric core
2001
International audience; Metal-cladded dielectric cylinders with submicron diameters may serve to model coated tips used in nearfield scanning optical microscopy. The signal measured may be greatly influenced by resonance effects due to eigenmodes of the probe. Especially, using a photon scanning tunneling microscope setup, gold-coated tips have been found to detect a signal proportional to the magnetic field distributions [E. Devaux et al.. Phys. Rev. B 62, 10 504 (2000)]. This effect is attributed to cylindrical surface plasmons. We present here fully retarded calculations of the dispersion and field patterns of the nonradiative plasmon modes in cylindrical geometry. We study the effect of…
Analysis of the angular acceptance of surface plasmon Bragg mirrors
2007
International audience; We analyze an important aspect of the behavior of surface plasmon polariton (SPP) Bragg mirrors: the dependence of the angular acceptance for reflection on the incidence angle. By means of leakage radiation microscopy, both in direct and Fourier space, we observe that the angular acceptance diminishes for increasing incidence angles. This effect, which can considerably affect the design of devices based on these elements, is shown to be the consequence of the decrease of the bandgap width with increasing incidence angle. (c) 2007 Optical Society of America.
Dielectric-loaded plasmonic waveguide-ring resonators
2009
International audience; Using near-field microscopy, the performance of dielectric-loaded plasmonic waveguide-ring resonators (WRRs) operating at telecom wavelengths is investigated for various waveguide-ring separations. It is demonstrated that compact ( footprint similar to 150 mu m(2)) and efficient ( extinction ratio similar to 13 dB) WRR-based filters can be realized using UV-lithography. The WRR wavelength responses measured and calculated using the effective-index method are found in good agreement. (c) 2009 Optical Society of America