Search results for "plastics"
showing 10 items of 2724 documents
Macromonomers on the basis of 2-phenyl-2-oxazoline
1988
By initiation of the ring-opening polymerization of 2-phenyl-2-oxazoline (1) with p-iodomethylstyrene a macromonomer with a styrene end-group (2) is obtained. The degree of polymerization was varied between 10 and 16. The radical copolymerization of 2 with styrene is described. 1 forms with methyl triflate a very stable oxazolinium salt which is a good initiator for the bulk polymerization of 1 at temperatures of 50–70°C. It was conclusively proved that under these conditions the polymerization proceeds by a living mechanism. By termination with N, N-dimethylaminopropylmeth-acrylamide a macromonomer (5) was obtained. 5 can be radically homopolymerized. This comb-like polymer 6 has the typic…
Synthesis of block copolymers with poly(methyl methacrylate): P(B-b-MMA), P(EB-b-MMA), P(S-b-B-b-MMA) and P(S-b-EB-b-MMA)
1993
Well-defined diblock copolymers poly(butadiene-b-methyl methacrylate) (=P(B-b-MMA)) and triblock copolymers poly(styrene-b-butadiene-b-methyl methacrylate) (=P(S-b-B-b-MMA)) have been prepared by sequential anionic polymerization in THF. The synthesis of P(B-b-MMA) and P(S-b-B-b-MMA) was most efficient in the presence of lithium alkoxides. By this method side reactions are suppressed and the polymerization can be performed at higher temperatures. The resulting triblock copolymers have narrow molecular weight distribution. The 1,2-PB midblock was quantitatively hydrogenated with tosylhydrazide to enhance thermal stability. Alternatively the hydrogenation can be performed at elevated pressure…
Acrylic thermoplastic elastomers and comb-shaped poly(methyl methacrylate) via the macromonomer technique
1996
Comb-shaped poly(methyl methacrylate) (PMMA) and poly(butyl acrylate) (PnBuA) grafted with PMMA were prepared by radical copolymerization of ω-methacryloyl-PMMA with MMA and nBuA, respectively. The comb-shaped PMMA is characterized with respect to radius of gyration by using gel permeation chromatography equipped with a multi-angle laser light scattering detector. The radical copolymerization of the macromonomer with nBuA in toluene follows complex kinetics. The dependence of the relative reactivity of the macromonomer on absolute concentration and on the ratio of comonomers may be explained by preferential solvation of comonomers by segments of their own kind (“bootstrap effect”) or even m…
Capillary Nematization of Semiflexible Polymers
2016
emiflexible polymers under good solvent conditions confined by two planar parallel repulsive walls are investigated for a wide range of monomer concentrations and distances between the walls, for a case where persistence length and contour length of the macromolecules are almost equal. Chain conformations and local nematic ordering near the walls are studied by both molecular dynamics methods and density functional theory, putting it in perspective with the recent work where the isotropic phase of semiflexible polymer solutions in the vicinity of a single repulsive wall in semi-infinite geometry is considered. Profiles of the total density of monomers as well as densities of end- and middle…
Flow properties of low density/linear low density polyethylenes
1986
Rheological data have been collected both in shear and non-isothermal elongational flow on three different types of blends, made from one low density polyethylene sample and three linear low density polyethylene samples. In addition to the flow curves, data are presented on the extrudate-swell phenomenon, on the instability arising in capillary flow and on the tensile behavior in the molten state.
The rheological behavior of HDPE/LDPE blends 4. Instability phenomena in capillary flow
1984
Experimental data, relative to instability phenomena in capillary flow, have been collected for HDPE/LDPE blends already characterized from a rheological viewpoint. The data comprise morphological observations as well as the determination of critical parameters as a function of the blend composition and of the processing conditions.
Rheology-morphology relationships in nylon 6/liquid-crystalline polymer blends
1990
Extrusion measurements have been carried out on blends of nylon 6 and a liquid-crystalline copolyesteramide (LCP). The flow curves at low temperature show a behavior similar to that of pure LCP with a rapid rise of the viscosity at low shear rates. At high shear rates the viscosity is lower than that for each of the two components. This minimum has been attributed to the lack of interactions between the two phases and to the formation of fibrils of the LCP phase. The SEM analysis shows, indeed, that fibrils of the LCP phase are produced in the convergent flow at the inlet of the capillary at high shear rates. These fibrils are lost during the flow in the long capillary.
Advanced ultra-high molecular weight polyethylene/antioxidant-functionalized carbon nanotubes nanocomposites with improved thermo-oxidative resistance
2015
Multiwalled carbon nanotubes (CNTs) functionalized with hindered phenol moieties are dispersed in ultra-high molecular weight polyethylene (UHMWPE), and the stabilizing action of the antioxidant (AO) functionalized CNTs (AO-f-CNTs) is studied through a combination of rheological and spectroscopic (FT-IR) analyses. The effectiveness of two alternative compounding methods, namely hot compaction (HC) and melt mixing (MM), is compared. The combination of high temperature and mechanical stress experienced during MM brings about noticeable degradation phenomena of the matrix already in the course of the compounding step. Differently, the milder conditions of the HC process preserve the stability …
Formulation, Characterization and Optimization of the Processing Conditions of Blends of Recycled Polyethylene and Ground Tyre Rubbers: Mechanical an…
2005
Abstract Recycling represents a valid alternative to the disposal of post-consumer plastics in common landfills if it is possible to obtain new materials with good final properties compatible with practical application and, above all, by using cheap methods. In this work the possibility to produce secondary materials by blending recycled polyethylene (RPE) coming from greenhouses and post-consumer ground tyre rubber (GTR) has been studied. In particular, the preparation of these blends has been carried out in a common industrial twin screw extruder. RPE pellets and GTR powder were fed to the extruder without any other additive. Temperature, processing speed, mixing procedure and composition…
Reductive Decationizable Block Copolymers for Stimuli-Responsive mRNA Delivery
2016
Messenger ribonucleic acids (mRNAs) are considered as promising alternatives for transient gene therapy, but to overcome their poor pharmacokinetic properties, smart carriers are required for cellular uptake and stimuli-responsive release. In this work, a synthetic concept toward reductive decationizable cationic block copolymers for mRNA complexation is introduced. By combination of RAFT block copolymerization with postpolymerization modification, cationic block copolymers are generated with disulfide-linked primary amines. They allow effective polyplex formation with negatively charged mRNA and subsequent release under reductive conditions of the cytoplasm. In first in vitro experiments w…